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(b) Special issue for organocatalysis: Chem. Rev. 2007, 107, 12.
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33845554384
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For epoxidation: a
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For epoxidation: (a) Davis, F. A.; Jenkins, R. H.; Awad, S. B.; Stringer, O. D.; Watson, H. W.; Galloy, J. J. Am. Chem. Soc. 1982, 104, 5412.
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For selective oxidation of sulfides: a
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For selective oxidation of sulfides: (a) Davis, F. A.; Billmers, J. M. J. Org. Chem. 1983, 48, 2672.
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Davis, F.A.1
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Towson, J.C.4
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9
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0000343128
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(d) Davis, F. A.; McCauley, J. P.; Chattopadhyay, S.; Harkal, M. E.; Towson, J. C.; Watson, W. H.; Tavanaiepour, I. J. Am. Chem. Soc. 1987, 109, 3370.
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Chattopadhyay, S.3
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(f) Davis, F. A.; ThimmaReddy, R.; Weismiller, M. C. J. Am. Chem. Soc. 1989, 111, 5964.
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(g) Davis, F. A.; Reddy, T.; Han, W.; Carroll, P. J. J. Am. Chem. Soc. 1992, 114, 1428.
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Davis, F.A.1
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0001276584
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(h) Davis, F. A.; Weismiller, K. M.; Reddy, R. T.; Chen, B.-C. J. Org. Chem. 1992, 57, 7274.
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Davis, F.A.1
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(i) Schoumacker, S.; Hamelin, O.; Téti, S.; Pécaut, J.; Fontecave, M. J. Org. Chem. 2005, 70, 301.
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0000043848
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For oxidation of enolate anions: a
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For oxidation of enolate anions: (a) Davis, F. A.; Chen, B.-C. Chem. Rev. 1992, 92, 919.
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Davis, F.A.1
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0027756956
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(b) Davis, F. A.; Kumar, A.; Reddy, R.; Chen, B.-C.; Wade, P. A.; Shah, S. W. J. Org. Chem. 1993, 58, 7591.
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Davis, F.A.1
Kumar, A.2
Reddy, R.3
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Shah, S.W.6
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17
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(c) Davis, F. A.; Reddy, R. E.; Kasu, P. V. N.; Portonovo, S. P.; Carroll, P. J. J. Org. Chem. 1997, 62, 3625.
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Davis, F.A.1
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(a) Page, P. C. B.; Heer, J. P.; Bethell, D.; Collington, E. W.; Andrews, D. M. Tetrahedron: Asymmetry 1995, 6, 2911.
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(c) Vidal, J.; Hannachi, J.-C.; Hourdin, G.; Mulatier, J.-C.; Collet, A. Tetrahedron Lett. 1998, 39, 8845.
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(e) Bonnet, D.; Rommes, C.; Gras-Masse, H.; Melnyk, O. Tetrahedron 1999, 40, 7315.
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0034671043
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(g) Messina, F.; Botta, M.; Corelli, F.; Paladino, A. Tetrahedron: Asymmetry 2000, 11, 4895.
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Tetrahedron: Asymmetry
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Messina, F.1
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Corelli, F.3
Paladino, A.4
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0034671043
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(h) Messina, F.; Botta, M.; Corelli, F.; Paladino, A. Tetrahedron: Asymmetry 2000, 11, 4895.
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Tetrahedron: Asymmetry
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Messina, F.1
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0037670061
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(i) Armstrong, A.; Edmods, I. D.; Swarbric, M. E. Tetrahedron Lett. 2003, 44, 5335.
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Armstrong, A.1
Edmods, I.D.2
Swarbric, M.E.3
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1842557232
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(k) Hannachi, J.-C.; Vidal, J.; Mulatier, J.-C.; Collet, A. J. Org. Chem. 2004, 69, 2367.
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Armstrong, A.1
Jones, L.H.2
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Kelsey, R.D.4
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30
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59849117111
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Although the highly electrophilic perfluorooxaziridines show the exceptionally strong oxidizing power, any catalytic oxidation reaction using corresponding imines have been reported: Petrov, V. A, Resnati, G. Chem. Rev. 1996, 96, 1
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Although the highly electrophilic perfluorooxaziridines show the exceptionally strong oxidizing power, any catalytic oxidation reaction using corresponding imines have been reported: Petrov, V. A.; Resnati, G. Chem. Rev. 1996, 96, 1.
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31
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0030865569
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Vidal, J.; Damestoy, S.; Guy, L.; Hanachi, J.; Aubry, A.; Collet, A. Chem. - Eur. J. 1997, 3, 1691.
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Chem. - Eur. J
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Vidal, J.1
Damestoy, S.2
Guy, L.3
Hanachi, J.4
Aubry, A.5
Collet, A.6
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33
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0037243598
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(a) Jennings, W. B.; Schweppe, A. W. B.; Testa, L. M.; Zaballos-Garcia, J.; Sepulveda-Arques, E. Synlett 2003, 121.
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Synlett
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Jennings, W.B.1
Schweppe, A.W.B.2
Testa, L.M.3
Zaballos-Garcia, J.4
Sepulveda-Arques, E.5
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34
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0035180602
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(b) Jennings, W. B.; O'Shea, J. H.; Schweppe, A. Tetrahedron Lett. 2001, 42, 101.
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Tetrahedron Lett
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Jennings, W.B.1
O'Shea, J.H.2
Schweppe, A.3
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35
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0001001432
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Hart, D. J.; Kanai, K.; Thomas, D. G.; Kuei. Yang, T. J. Org. Chem. 1983, 48, 289.
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J. Org. Chem
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Hart, D.J.1
Kanai, K.2
Thomas, D.G.3
Kuei4
Yang, T.5
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36
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59849125293
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A similar reactivity of N-trimethylsilylimine with sulfonylchlorides is already known: Georg, G. I.; Harriman, G. C. B.; Peterson, S. A. J. Org. Chem. 1992, 57, 1224.
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A similar reactivity of N-trimethylsilylimine with sulfonylchlorides is already known: Georg, G. I.; Harriman, G. C. B.; Peterson, S. A. J. Org. Chem. 1992, 57, 1224.
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37
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59849125860
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3CN, compound 4a was obtained as a yellow powder (50%).
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3CN, compound 4a was obtained as a yellow powder (50%).
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38
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59849114653
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2O at -30°C (74%).
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2O at -30°C (74%).
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39
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59849098790
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2 (1 mL) was added, at rt, a solution of m-chloroperbenzoic acid (129.5 mg, 0.75 mmol). After 3 h, the solution was filtrated, and the evaporation of the solvent gave the corresponding oxaziridine 6a (41%).
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2 (1 mL) was added, at rt, a solution of m-chloroperbenzoic acid (129.5 mg, 0.75 mmol). After 3 h, the solution was filtrated, and the evaporation of the solvent gave the corresponding oxaziridine 6a (41%).
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40
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59849106529
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1H NMR to determine the conversion of the olefin into the corresponding epoxide.
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1H NMR to determine the conversion of the olefin into the corresponding epoxide.
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41
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59849122642
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Probably due to the slow decompositon of oxone at rt, the epoxidation reaction is more efficient at 0°C.
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Probably due to the slow decompositon of oxone at rt, the epoxidation reaction is more efficient at 0°C.
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