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Iron jarosite is in this sense not a unique case. For 3d transition-metal compounds with more than half-filled shells, the effective moments are in general significantly larger than the spin-only moment.
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Iron jarosite is in this sense not a unique case. For 3d transition-metal compounds with more than half-filled shells, the effective moments are in general significantly larger than the spin-only moment.
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Though all Fe-Oeq bond lengths are the same, the equatorial plane is rectangular rather than square, with the short side pointing into the kagome triangles. Furthermore, the Fe-Oap axis is canted by 4° away from the local c′ axis.
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Though all Fe-Oeq bond lengths are the same, the equatorial plane is rectangular rather than square, with the short side pointing into the kagome triangles. Furthermore, the Fe-Oap axis is canted by 4° away from the local c′ axis.
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