Matrix acidizing of carbonate reservoirs using organic acids and mixture of HCl and organic acids

Proceedings - SPE Annual Technical Conference and Exhibition

Volumn 6, Issue , 2008, Pages 4212-4220

  Chang, F F ^a   Nasr El Din, H A ^b   Lindvig, T ^a   Qiu, X W ^a  

^a SCHLUMBERGER   (United States)

^b TEXAS A AND M UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACID RATIOS; ACID TREATMENTS; ACIDIZING TREATMENTS; CARBONATE ACIDIZING; CARBONATE FORMATIONS; CARBONATE RESERVOIRS; CARBONATE ROCKS; CORROSIVITY; DEEP WELLS; FIELD TREATMENTS; HCL SOLUTIONS; LABORATORY EVALUATIONS; LOW COSTS; MATRIX ACIDIZING; ORGANIC LIGANDS; ORGANIC SALTS; PRODUCTIVITY ENHANCEMENTS; REACTION PRODUCTS; RESERVOIR TEMPERATURES; THERMODYNAMIC EQUILIBRIUM; WELL TUBULARS;

ACIDIZATION; ASSOCIATION REACTIONS; CALCIUM; CARBONATES; CARBONATION; CHEMICAL SENSORS; DISSOLUTION; FREE RADICAL POLYMERIZATION; HYDROCHLORIC ACID; MAGNESIUM; ORGANIC ACIDS; PETROLEUM RESERVOIR EVALUATION; REACTION KINETICS; REACTION RATES; ROCKS; SOLAR RADIATION; TELECOMMUNICATION NETWORKS;

ORGANIC COMPOUNDS;

EID: 58849147131     PISSN: None     EISSN: None     Source Type: Conference Proceeding    
DOI: None     Document Type: Conference Paper

References (25)

1. Nasr-El-Din H.A., Al-Mohammad, A.M., Al-Aamri, A.M., and Al-Fuwaires, O.: "Reaction Kinetics of Gelled Acids with Calcite," paper SPE 103979, accepted for publication in SPEPO, 2008.
2. Navarrete, R.C., Holms, B.A., McConnell, S.B. and Linton, D.E.: "Emulsified Acid Enhances Well Production in High-Temperature Carbonate Formations," paper SPE 50612 presented at the 1998 SPE European Petroleum Conference, The Hague, The Netherlands, October 20-22.
3. Al-Mohammad, A.M., Nasr-El-Din H.A., Al-Aamri, A.M., and Al-Fuwaires, O.: "Reaction of Calcite with Surfactant-Based Acids," paper SPE 102838 presented at the 2006 SPE Annual Technical Conference and Exhibition, San Antonio, TX, 24-27 September.
4. Harris, F.N.: "Applications of Acetic Acid to Well Completions, Stimulations and Reconditioning," JPT 13(7) (1961) 637-639.
5. rd Edition, John Wiley & Sons Inc. (2000) 17-11.
6. Chatelain, J.C. Silberberg, I.H., and Schechter, R.S.: "Thermodynamic Limitations in Organic-Acid/Carbonate Systems," SPEJ 16(4) (1976) 189-195.
7. Williams, B.B., Gidley, J.L., and Schechter, R.S.: "Acidizing Fundamentals," SPE Monograph Volume 6, 1979.
8. Dill, W.R. and Keeney, B.R.: "Optimizing HCl-Formic Acid Mixtures for High Temperature Stimulation," paper SPE 7567 presented at the 1978 Annual Fall Technical Conference and Exhibition of the SPE-AIME, Houston, TX, Oct. 1-3.
9. Taylor, K.C., Al-Katheeri, M.I., and Nasr-El-Din, H.A.: "Development and Field Application of a New Measurement Technique for Organic Acid Additives in Stimulation Fluids," SPEJ 10(2) (2005) 152-160.
10. Katheeri, M.I., Nasr-El-Din, H.A., Taylor, K.C., and Grainees, A.H.: "Determination and Fate of Formic Acid in High Temperature Acid Stimulation Fluids," paper SPE 73749 presented at the 2002 SPE International Symposium on Formation Damage Control, Lafayette, LA, Feb. 20-21.
11. Buijse, M., deBoer, P., Breukel, B., Klos, M., and Burgos, G.: "Organic Acids in Carbonate Acidizing," SPEPF 19(3) (2004) 128-134.
12. Fredd, C.N. and Fogler, H.S.: "The Kinetics of Calcite Dissolution in Acetic Acid Solution," Chem. Eng. Sci. 53(22) (1998) 3863-3874.
13. de Rozieres, J., Chang, F.F. and Sullivan, R.B.: "Measuring Diffusion Coefficients in Acid Fracturing Fluids and Their Application to Gelled and Emulsified Acids," paper SPE 28552 presented at the 1994 Annual SPE Conference, New Orleans, LA, Sep. 25-28.
14. Nierode, D.E. and Williams, B.B.: "Characteristics of Acid Reaction in Limestone Formations," SPEJ 11 (1971) 406-418.
15. Roberts, L.D. and Guin, J.A.: "The Effect of Surface Kinetics in Fracture Acidizing," SPEJ 14 (1974) 385-395.
16. Nasr-El-Din, H.A., Al-Mohammad, A.M., Al-Aamri, A.D., Al-Fahad, M.A. and Chang, F.F.: "Quantitative Analysis of Reaction Rate Retardation in Surfactant-Based Acids," paper SPE 107451, accepted for publication in SPEPO, 2008.
17. nd edition, 1975, McGraw-Hill Book Company.
18. Shock, E.L., Helgeson, H.C., and Sverjensky, D.A.: "Calculation of the Thermodynamic Properties of Aqueous Species at High Pressures and Temperatures: Standard Partial Molal Properties of Inorganic Neutral Species," Geochim. Cosmochim. Acta 53 (1989) 2157-2183.
19. Pitzer, K.S.: "Thermodynamics of Electrolytes. I. Theoretical Basis and General Equation," J. Phys. Chem. 77 (1973) 268-277.
20. Loos, D., Pasel, C., Luckas, M., Schmidt, K.G., and Herbell, J.D.: "Experimental Investigation and Modelling of the Solubility of Calcite and Gypsum in Aqueous Systems at Higher Ionic Strength," Fluid Phase Equilibrium 219 (2004) 219-229.
21. Nancollas, G.H.: "Thermodynamics of Ion Association, Part II - Alkaline-Earth Acetates and Formates," J. Chem. Soc. (1956) 744.
22. Bombardieri, C.C. and Martin, T.H.: "Acid Treating Process," US Patent 3,251,415, May 17, 1966.
23. Dill, W.R.: "Reaction Time of Hydrochloric-Acetic Acid Solutions on Limestone," paper SPE 00211 presented at the 16th Southwest Regional Meeting of the American Chemical Society, Oklahoma City, OK, December 1-3, 1960.
24. Mumallah, N.A.: "Factors Influencing the Reaction Rate of Hydrochloric Acid and Carbonate Rock," paper SPE 21036 presented at the 1991 SPE International Symposium on Oilfield Chemistry, Anaheim, CA, Feb. 20-22.
25. Crowe, C.W., McGowan, G.R., and Baranet, S.E.: "Investigation of Retarded Acids Provides Better Understanding of Their Effectiveness and Potential Benefits," SPEPE 5(2) (1990) 166-170.