Complete mechanism of σ* intramolecular aromatic hydroxylation through O2 activation by a macrocyclic dicopper(I) complex

Journal of the American Chemical Society

Volumn 130, Issue 52, 2008, Pages 17710-17717

  Poater, Albert ^a   Ribas, Xavi ^b   Llobet, Antoni ^c,d   Cavallo, Luigi ^a   Solà, Miquel ^b  

^a UNIVERSITY OF SALERNO   (Italy)

^b Institut de Quimica Computacional   (Spain)

^c UNIVERSITAT AUTÒNOMA DE BARCELONA   (Spain)

^d INSTITUTE OF CHEMICAL RESEARCH OF CATALONIA ICIQ   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

AROMATIC COMPOUNDS; AROMATIZATION; CHEMICAL ACTIVATION; HYDROXYLATION; ISOMERS;

AROMATIC HYDROXYLATION; B3LYP CALCULATIONS; C-O BOND FORMATION; HIGH-ENERGY BARRIERS; INTERMEDIATE SPECIE; METHOD OF CALCULATION; REACTION MECHANISM; RELATIVE STABILITIES;

REACTION INTERMEDIATES;

CARBON; COPPER COMPLEX; HEXAAZAMACROCYCLIC DICOPPPER(I)COMPLEX; MACROCYCLIC COMPOUND; OXYGEN; PEROXIDE; UNCLASSIFIED DRUG; BENZENE DERIVATIVE; BIOMIMETIC MATERIAL; COPPER; HETEROCYCLIC COMPOUND; ORGANOMETALLIC COMPOUND;

ARTICLE; CHEMICAL BOND; CHEMICAL STRUCTURE; CONTROLLED STUDY; HYDROXYLATION; PROTON TRANSPORT; CHEMISTRY; THERMODYNAMICS; X RAY CRYSTALLOGRAPHY;

AZA COMPOUNDS; BENZENE DERIVATIVES; BIOMIMETIC MATERIALS; COPPER; CRYSTALLOGRAPHY, X-RAY; HYDROXYLATION; MACROCYCLIC COMPOUNDS; MODELS, MOLECULAR; ORGANOMETALLIC COMPOUNDS; OXYGEN; PEROXIDES; THERMODYNAMICS;

EID: 58849124274     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja801913b     Document Type: Article

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