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Volumn 626, Issue 1-2, 2009, Pages 103-110

In situ measurement of the Preyssler polyoxometalate morphology upon electrochemical reduction: A redox system with Born electrostatic ion solvation behavior

Author keywords

Bulk electrolysis; Heteropolyanions; Polyoxometalate; Preyssler anion; Radius of gyration (Rg); Small angle X ray scattering (SAXS)

Indexed keywords

CALCIUM; DISSOLUTION; ELECTROCHEMICAL ELECTRODES; ELECTROCHEMISTRY; ELECTROLYSIS; ELECTROLYTIC REDUCTION; ELECTROSTATICS; ION EXCHANGE; LANTHANUM; NEGATIVE IONS; REDUCTION; SCATTERING; SOLVATION; X RAY SCATTERING;

EID: 58749108803     PISSN: 15726657     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jelechem.2008.11.009     Document Type: Article
Times cited : (16)

References (120)
  • 5
    • 3442886712 scopus 로고    scopus 로고
    • Borrás-Almenar J., Coronado E., Müller A., and Pope M. (Eds), Kluwer, Dordrecht
    • In: Borrás-Almenar J., Coronado E., Müller A., and Pope M. (Eds). Polyoxometalate Molecular Science (2003), Kluwer, Dordrecht
    • (2003) Polyoxometalate Molecular Science
  • 10
    • 72749093976 scopus 로고    scopus 로고
    • Polyoxoanions: Synthesis and structure
    • Ward M. (Ed), Elsevier, Oxford
    • Pope M.T. Polyoxoanions: Synthesis and structure. In: Ward M. (Ed). Applications of Coordination Chemistry (2004), Elsevier, Oxford 635-678
    • (2004) Applications of Coordination Chemistry , pp. 635-678
    • Pope, M.T.1
  • 28
    • 37149049312 scopus 로고    scopus 로고
    • g is the shape-independent, root-mean-square measure of all the mass-weighted distances in a particle from its center of mass, see
    • g is the shape-independent, root-mean-square measure of all the mass-weighted distances in a particle from its center of mass, see. Putnam C.D., Hammel M., Hura G.L., and Tainer J.A. Q. Rev. Biophys. 40 (2007) 191-285
    • (2007) Q. Rev. Biophys. , vol.40 , pp. 191-285
    • Putnam, C.D.1    Hammel, M.2    Hura, G.L.3    Tainer, J.A.4
  • 53
    • 85009089243 scopus 로고    scopus 로고
    • Available from Boyd Technologies, CA, USA, .
    • Available from Boyd Technologies, CA, USA, .
  • 54
    • 85009086906 scopus 로고    scopus 로고
    • note
    • ® and Neoflon™, respectively. We obtained a 12″ × 12″ PCFTE film as stock for the cell windows as well as a 12″ × 12″ × 1″ sheet as stock for the cell bodies from Boedeker Plastics, Inc., parts F036-00010 and S036-01000, respectively.
  • 56
    • 85009071730 scopus 로고    scopus 로고
    • note
    • Organic solvents that effectively wet PCTFE, especially dialkylphosphoric acids and malonamides, including dihexylphosphoric acid and N,N′-dimethyl-N,N′-dioctyl-hexylethoxymalonamide, such as employed in liquid-liquid extraction systems, are not adequately contained with the design described here.
  • 59
    • 85009092713 scopus 로고    scopus 로고
    • note
    • The 1/e attenuation length of 20 keV photons in water is 14.2 mm, which is 8.25× longer than the optical path length of the cell.
  • 60
    • 85009117837 scopus 로고    scopus 로고
    • note
    • 12-[36,37] and, moreover, the SAXS data obtained at this solution concentration, 8.9 mg/mL, are identical with those of more dilute analyte concentrations, indicating the absence of interparticle effects.
  • 66
    • 85009089244 scopus 로고    scopus 로고
    • X. Zuo, A. Goshe, R. Zhang, D.M. Tiede, solX program available upon request, contact tiede@anl.gov, 2008.
    • X. Zuo, A. Goshe, R. Zhang, D.M. Tiede, solX program available upon request, contact tiede@anl.gov, 2008.
  • 76
    • 33845367827 scopus 로고    scopus 로고
    • Electrochemistry of Isopoly and Heteropoly Oxometalates
    • Scholz F., and Pickett C.J. (Eds), Wiley-VCH, Weiheim
    • Keita B., and Nadjo L. Electrochemistry of Isopoly and Heteropoly Oxometalates. In: Scholz F., and Pickett C.J. (Eds). Encyclopedia of Electrochemistry (2006), Wiley-VCH, Weiheim 607-700
    • (2006) Encyclopedia of Electrochemistry , pp. 607-700
    • Keita, B.1    Nadjo, L.2
  • 82
    • 0013585573 scopus 로고    scopus 로고
    • Small-angle techniques
    • Wilson A.J.C., and Prince E. (Eds), Kluwer Academic, Dordrecht
    • Glatter O., and May R. Small-angle techniques. In: Wilson A.J.C., and Prince E. (Eds). International Tables For Crystallography (1999), Kluwer Academic, Dordrecht 89-142
    • (1999) International Tables For Crystallography , pp. 89-142
    • Glatter, O.1    May, R.2
  • 89
    • 34250928962 scopus 로고
    • Born M. Z. Phys. 1 (1920) 45-48
    • (1920) Z. Phys. , vol.1 , pp. 45-48
    • Born, M.1
  • 107
    • 85009086909 scopus 로고    scopus 로고
    • note
    • 5+, the effective charges are 1.66- and 1.95-.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.