Catalytic dehydration of lactic acid to acrylic acid over sulfate catalysts

Canadian Journal of Chemical Engineering

Volumn 86, Issue 6, 2008, Pages 1047-1053

  Zhang, Jinfeng ^a   Lin, Jianping ^a   Cen, Peilin ^a  

^a ZHEJIANG UNIVERSITY   (China)

Author keywords

Acrylic acid; Calcination temperature; Contact time; Cupric sulfate

Indexed keywords

BIOMASS; BODY FLUIDS; CALCINATION; CALCIUM; CALCIUM PHOSPHATE; CARBON DIOXIDE; CARBOXYLIC ACIDS; CARRIER CONCENTRATION; CATALYSIS; CIVIL AVIATION; DEHYDRATION; DEWATERING; ELECTRON HOLOGRAPHY; LACTIC ACID; ORGANIC ACIDS; RENEWABLE ENERGY RESOURCES; SODIUM;

ACRYLIC ACID; CALCINATION TEMPERATURE; CALCIUM SULFATES; CARRIER GAS; CATALYTIC DEHYDRATIONS; CONCENTRATION OF; CONTACT TIME; CUPRIC SULFATE; MASS RATIOS;

ACIDS;

EID: 58649120530     PISSN: 00084034     EISSN: None     Source Type: Journal    
DOI: 10.1002/cjce.20115     Document Type: Article

References (23)

1. Bachman, G. B. and H. A. Tanner, "Decomposition of Esters," U.S. Patent. 2304872 (1942).
2. Bai, D. M., Q. Wei and Z. H. Yan, "Fedbatch Fermentation of Lactobacillus lactis for Hyper-Production of 1-Lactic Acid," Biotechnol. Lett. 25, 1833-1835 (2003).
3. Barnes, C. E., "Method of Distilling Monomeric Polymeriazation Substance," U.S. Patent. 2241175," (1941).
4. Brockinton, L., P. Savage and D. Hunter, "Acrylic Acid Capacity Expands Worldwide," Chemical Week, October 15," (1986).
5. Fisher, C. H., W. P. Ratchford and L. T. Smith, "Methyl Acrylate Production by Pyrolysis of Methyl Acetoxypropionate," Ind. Eng. Chem. 36(3), 229-233 (1944).
6. Gao, M. H., M. Hiratu and E. Toorisaka, "Acid-Hydrolysis of Fish Wastes for Lactic Acid Fermentation," Bioresour. Technol. 97, 2414-2420 (2006).
7. Goto, M., R. Obuchi and T. Hirose, "Hydrothermal Conversion of Municipal Organic Waste Into Resources," Bioresour. Technol. 93, 279-284 (2004).
8. Gunter, G. C, D. J. Miller and E. J. Jackson, "Formation of 2,3-Pentanedione From Lactic Acid Over Supported Phosphate Catalysts," J. Catal. 148, 252-260 (1994).
9. Gunter, G. C., R. H. Langford and E. J. Jackson, "Catalysts and Supports for Conversion of Lactic Acid to Acrylic Acid and 2,3-Pentaedione, " Ind. Eng. Chem. Res. 34, 974-980 (1995).
10. Holmen, R. E., "Production of Acrylates by Catalytic Dehydration of Lactic Acid and Alkyl Lactates," U.S. Patent. 2859240," (1958).
11. McCrackin P. J. and C. T. Lira, "Conversion of Lactic Acid to Acrylic Acid in Supercritical Water," Ind. Eng. Chem. Res. 32, 2608-2613 (1993).
12. Odell, B., G. Earlam and D. J. Cole-Hamilton, "Hydrothermal Reaction of Lactic Acid Catalyzed by Group VIII Metal Complexes," J. Organomet. Chem. 290, 241-248 (1985).
13. Oh, H., Y. J. Wee and J. S. Yun, "Lactic Acid Production From Agricultural Resources as Cheap Raw Materials," Bioresour. Technol. 96, 1492-1498 (2005).
14. Paparizos, C., S. Dolhyj and W. G. Shaw, "Catalytic Conversion of Lactic Acid and Ammonium Lactate to Acrylic Acid," U.S. Patent. 4786756," (1988).
15. Sawicki, R. A., "Catalyst for Dehydration of Lactic Acid Acrylic Acid," U.S. Patent. 4729978," (1988).
16. Smith, L. T., C. H. Fisher and W. P. Ratchford, "Pyrolysis of Lactic Acid Derivatives: Conversion of Methyl a-Acetoxypropionate to Methyl Acrylate," Ind. Eng. Chem. 34(4), 473-479 (1942).
17. Simons, W. W., "The Infrared Spectra Handbook of Inorganic Compounds". Sadtler Research Laboratories, Philadelphia, PA (1984).
18. Takeshita, T., R. Ohnishi and T. Matsui, "Acid Property and Structure of a Solid Metal Sulfate Catalyst: Change in Structure of Nickel Sulfates With Heating," J. Phys. Chem 69, 4077-4083 (1965).
19. Takeshita, T., R. Ohnishi and K. Tanabe, "Recent Survey of Catalysis by Solid Metal Sulfates," Catal. Rev. 8(1), 29-63 (1973).
20. Varadarajan S., and D. J. Miller, "Catalytic Upgrading of Fermentation-Derived Organic Acids," Biotechnol. Progr. 15, 845-854 (1999).
21. Waldley, D. C., M. S. Tam and P. B. Kokitkar, "Lactic Acid Conversion to 2,3-Pentanedione and Acrylic Acid Over Silica-Supported Sodium Nitrate: Reaction Optimization and Identification of Sodium Lactate as the Active Catalyst," J. Catal. 165, 162-171 (1997).
22. Walkup, P. C., C. A. Rormann and R. T. Hallen, "Production of Esters of Lactic Acid, Esters of Acrylic Acid, Lactic Acid, and Acrylic Acid," U.S. Patent. 5071754," (1991).
23. Zhang, J. F., J. P. Lin, X. B. Xu and P. L. Cen, "Evaluation of Catalysts and Optimization of Reaction Conditions for the Dehydration of Methyl Lactate to Acrylates," Chin. J. Chem. Eng. 16(2), 263-269, (2008).