CO2 and CH4 mole fraction measurements during hydrate growth in a semi-batch stirred tank reactor and its significance to kinetic modeling

Fluid Phase Equilibria

Volumn 276, Issue 2, 2009, Pages 150-155

  Bergeron, Sebastien ^a   Servio, Phillip ^a  

^a MCGILL UNIVERSITY   (Canada)

Author keywords

Crystallization; Gas hydrate; Kinetics; Mole fraction; Rate constant

Indexed keywords

CARBON DIOXIDE; CRYSTALLIZATION; CRYSTALLIZATION KINETICS; GASES; GROWTH (MATERIALS); HYDRATION; LIQUID METHANE; METALLIC GLASS; METHANE; NANOCRYSTALLINE ALLOYS; OXIDES; RANGE FINDING; RATE CONSTANTS; REAL TIME SYSTEMS; TANKS (CONTAINERS); TERNARY SYSTEMS; WATER PIPING SYSTEMS; WATERWORKS;

BULK LIQUIDS; EQUILIBRIUM VALUE; GAS HYDRATE; GROWTH PERIOD; GROWTH STAGES; HYDRATE GROWTH; KINETICS; LIQUID WATER; MOLE FRACTION; RATE CONSTANT; STIRRED TANKS; WATER SYSTEMS;

GAS HYDRATES;

EID: 58549112938     PISSN: 03783812     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.fluid.2008.10.021     Document Type: Article

References (30)

1. Sloan E.D. Clathrate Hydrates of Natural Gases (1998), Marcel Dekker Inc., New York p705
2. Chatti I., et al. Benefits and drawbacks of clathrate hydrates: a review of their areas of interest. Energy Conversion and Management 46 (2005) 1333-1343
3. Giavarini C., Maccioni F., and Santarelli M.L. Formation kinetics of propane hydrates. Ind. Eng. Chem. Res. 42 (2003) 1517-1521
4. Ribeiro C.P., and Lage P.L.C. Modelling of hydrate formation kinetics: state-of-the-art and future directions. Chem. Eng.i Sci. 63 (2008) 2007-2034
5. Englezos P., et al. Kinetics of formation of methane and ethane gas hydrates. Chem. Eng. Sci. 42 (1987) 2647-2658
6. Englezos P., et al. Kinetics of gas hydrate formation from mixtures of methane and ethane. Chem. Eng. Sci. 42 (1987) 2659-2666
7. Skovborg P., and Rasmussen P. A mass transport limited model for the growth of methane and ethane gas hydrates. Chem. Eng. Sci. 49 (1994) 1131-1143
8. Hashemi S., Macchi A., and Servio P. Gas hydrate growth model in a semibatch stirred tank reactor. Ind. Eng. Chem. Res. 46 (2007) 5907-5912
9. Bergeron S., and Servio P. Reaction rate constant of propane hydrate formation. Fluid Phase Equilibr. 265 (2008) 30-36
10. Kluytmans J.H.J., et al. Mass transfer in sparged and sittred reactors: influence of carbon particles and electrolyte. Chem. Eng. Sci. 58 (2003) 4719-4728
11. 2 solubility in pure water and the pressure effect on it in the presence of clathrate hydrate. Int. J. Heat Mass Transfer 48 (2005) 2503-2507
12. Servio P., and Englezos P. Effect of temperature and pressure on the solubility of carbon dioxide in water in the presence of gas hydrate. Fluid Phase Equilibr. 190 (2001) 127-134
13. 2 in hydrate forming conditions. Fluid Phase Equilibr. 175 (2000) 75-89
14. Servio P., and Englezos P. Measurement of dissolved methane in water in equilibrium with its hydrate. J. Chem. Eng. Data 47 (2002) 87-90
15. Kim Y.S., et al. Liquid water-hydrate equilibrium measurements and unified predictions of hydrate containing phase equilibria for methane, ethane, propane, and their mixtures. Ind. Eng. Chem. Res. 42 (2003) 2409-2414
16. Yang S.O., et al. Measurement and prediction of phase equilibria for water + methane in hydrate forming conditions. Fluid Phase Equilibr. 185 (2001) 53-63
17. Lu W., Chou I.M., and Burruss R.C. Determination of methane concentrations in water in equilibrium with sI methane hydrate in the absence of a vapor phase by in situ Raman spectrocospy. Geochimica et Cosmochimica 72 (2008) 412-422
18. 4 hydrate in deep ocan sediments. Geophys. Res. Lett. 29 (2002) 85
19. 2 in synthetic sea water at temperatures from 278 K to 293 K and pressures from 6.44 MPa to 29.49 MPa, and densities of the corresponding aqueous solutions. J. Chem. Eng. Data 43 (1998) 2-5
20. 2 in synthetic sea water at temperatures from 278 K to 293 K and pressures from 6.44 MPa to 29.49 MPa, and densities of the corresponding aqueous solutions. J. Chem. Eng. Data 44 (1999) 1432-1433
21. 2 gas hydrates formation using in situ particle size analysis. Chem. Eng. Sci. 60 (2005) 695-709
22. Trebble M.A., and Bishnoi P.R. Development of a new four-parameter cubic equation of state. Fluid Phase Equilibr. 35 (1987) 1-18
23. Gaudette J., and Servio P. Measurement of dissolved propane in water in the presence of gas hydrate. J. Chem. Eng. Data 52 (2007) 1449-1451
24. Hashemi S., et al. Prediction of methane and carbon dioxide solubility in water in the presence of hydrate. Fluid Phase Equilibr. 246 (2006) 131-136
25. Chirico R.D., et al. ThermoML - an XML-based approach for storage and exchange of experimental and critically evaluated thermophysical and thermochemical property data. 2. Uncertainties. J. Chem. Eng. Data 48 (2003) 1344-1359
26. Chun M.-K., and Lee H. Kinetics of formation of carbon dioxide clathrate hydrates. Korean J. Chem. Eng. 13 (1996) 620-626
27. Chapoy A., et al. Measurement and modeling of gas solubility and literature review of the properties for the carbon dioxide-water system. Ind. Eng. Chem. Res. 43 (2004) 1794-1802
28. Lekvam K., and Bishnoi P.R. Dissolution of methane in water at low temperatures and intermediate pressures. Fluid Phase Equilibr. 131 (1997) 297-309
29. Handa Y.P. Effect of Hydrostatic pressure and salinity on the stability of gas hydrates. J. Phys. Chem. 94 (1990) 2652-2657
30. Bergeron S., Macchi A., and Servio P. Theoretical temperature dependency of gas hydrate former solubility under hydrate-liquid water equilibrium. J. Chem. Thermody. 39 (2007) 737-741