Ruthenium promotion of Co/SBA-15 catalysts with high cobalt loading for Fischer-Tropsch synthesis

Fuel Processing Technology

Volumn 90, Issue 2, 2009, Pages 237-246

  Xiong, Haifeng ^a   Zhang, Yuhua ^a   Liew, Kongyong ^b   Li, Jinlin ^a,b  

^a SUZHOU UNIVERSITY   (China)

^b BEIJING UNIVERSITY OF POSTS AND TELECOMMUNICATIONS   (China)

Author keywords

Cobalt catalysts; Fischer Tropsch synthesis; Ruthenium promoter; SBA 15

Indexed keywords

ADSORPTION; ATOMIC PHYSICS; ATOMS; CARBON MONOXIDE; CATALYSIS; CATALYST ACTIVITY; CATALYSTS; COBALT; COBALT COMPOUNDS; DESORPTION; FOURIER TRANSFORM INFRARED SPECTROSCOPY; FOURIER TRANSFORMS; GAS ADSORPTION; HYDROGEN; INFRARED SPECTROSCOPY; OXYGEN; PHOTOELECTRON SPECTROSCOPY; RUTHENIUM; SPECTRUM ANALYSIS; TEMPERATURE PROGRAMMED DESORPTION; TRANSITION METALS; VOLUMETRIC ANALYSIS; X RAY PHOTOELECTRON SPECTROSCOPY;

BRIDGE TYPES; CATALYST REDUCIBILITIES; CATALYTIC ACTIVITIES; COBALT ATOMS; COBALT CATALYSTS; COBALT CLUSTERS; COBALT LOADINGS; COBALT OXIDES; DIFFRACTOMETRY; DIFFUSE REFLECTANCE INFRARED FOURIER TRANSFORM SPECTROSCOPIES; ELECTRONIC INTERACTIONS; HYDROGEN SPILLOVERS; INCIPIENT WETNESSES; OXYGEN TITRATIONS; PEAK INTENSITIES; REDUCTION TEMPERATURES; RUTHENIUM PROMOTER; SBA-15; X-RAY PHOTOELECTRON SPECTROSCOPIES;

FISCHER-TROPSCH SYNTHESIS;

EID: 58249144192     PISSN: 03783820     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.fuproc.2008.08.014     Document Type: Article

References (37)

1. Khodakov A.Y., Chu W., and Fongarland P. Advances in the development of novel cobalt Fischer-Tropsch catalysts for synthesis of long-chain hydrocarbons and clean fuels. Chem. Rev. 107 (2007) 1692-1744
2. E. Iglesia, S.L. Soled, R.A. Fiato, US Patent No. 4794099, 1988.
3. Panpranot J., Goodwin Jr. J.G., and Sayari A. CO hydrogenation on Ru-promoted Co/MCM-41 catalysts. J. Catal. 211 (2002) 530-539
4. 3 Fischer-Tropsch catalysts. J. Catal. 160 (1996) 125-133
5. Tsubaki N., Sun S., and Fujimoto K. Different functions of the noble metals added to cobalt catalysts for Fischer-Tropsch synthesis. J. Catal. 199 (2001) 236-246
6. 3 catalysts by in situ EXAFS/XANES of Co K and Re LIII edges and XPS. Appl. Catal., A Gen. 264 (2004) 203-212
7. Chu W., Chernavskii P.A., Gengembre L., Pankina G.A., Fongarland P., and Khodakov A.Y. Cobalt species in promoted cobalt alumina-supported Fischer-Tropsch catalysts. J. Catal. 252 (2007) 215-230
8. Zhao D.Y., Feng J., Huo Q., Melosh M., Fredrickson G.H., Chmelka B.F., and Stucky G.D. Triblock copolymer syntheses of mesoporous silica with periodic 50 to 300 A pores. Science. 279 (1998) 548-552
9. Jacobs G., Das T., Zhang Y.Q., Li J.L., Racoillet G., and Davis B.H. Fischer-Tropsch synthesis: support, loading, and promoter effects on the reducibility of cobalt catalysts. Appl. Catal., A Gen. 233 (2002) 263-281
10. Wang Y., Noguchi M., Takahashi Y., and Ohtsuka Y. Synthesis of SBA-15 with different pore sizes and the utilization as supports of high loading of cobalt catalysts. Catal. Today 68 (2001) 3-9
11. Khodakov A.Y., Griboval-Constant A., Bechara R., and Zholobenko V.L. Pore size effects in Fischer-Tropsch synthesis over cobalt-supported mesoporous silicas. J. Catal. 206 (2002) 230-241
12. Cai Q., and Li J.L. Catalytic properties of the Ru promoted Co/SBA-15 catalysts for Fischer-Tropsch synthesis. Catal. Commu. 9 (2008) 2003-2006
13. Martínez A., López C., Márquez F., and Díaz I. Fischer-Tropsch synthesis of hydrocarbons over mesoporous Co/SBA-15 catalysts: the influence of metal loading, cobalt precursor, and promoters. J. Catal. 220 (2003) 486-499
14. H.F. Xiong, Y.H. Zhang, K.Y. Liew, J.L. Li, Fischer-Tropsch synthesis: the role of pore size for Co/SBA-15 catalysts, J. Mol. Catal. A Chem. (in press). doi:10.1016/j.molcata.2008.08.017.
15. Borg Ø., Eri S., Blekkan E.A., Storsæter S., Wigum H., Rytter E., and Holmen A. Fischer-Tropsch synthesis over γ-alumina-supported cobalt catalysts: effect of support variables. J. Catal. 248 (2007) 89-100
16. 3 Fischer-Tropsch catalyst. J. Cent. S. Univ. Technol. 11 (2004) 414-418
17. Baird T., Campbell K.C., Holliman P.J., Hoyle R.W., Stirling D., Williams B.P., and Morris M. Characterisation of cobalt-zinc hydroxycarbonates and their products of decomposition. J. Mater. Chem. 7 (1997) 319-330
18. Schofield J.H. Hartree-Slater subshell photoionization cross-sections at 1254 and 1487 eV. J. Electron. Spectrosc. Relat. Phenom. 8 (1976) 129-137
19. Khodakov A.Y., Zholobenko V.L., Bechara R., and Durand D. Impact of aqueous impregantion on the long-range ordering and mesoporous structure of cobalt MCM-41 and SBA-15 materials. Micropor. Mesopor. Mater. 79 (2005) 29-39
20. 2 catalysts for Fischer-Tropsch synthesis. Fuel Process Technol. 89 (2008) 455-459
21. 2. Appl. Catal., A Gen. 196 (2000) 111-123
22. 3 for Fischer-Tropsch synthesis. J. Mol. Catal., A Chem. 231 (2005) 145-151
23. 3 catalysts: a comparative study on reactivity of support. J. Phys. Chem., B. 104 (2000) 1783-1790
24. 2 catalysts: reduction characteristics and interaction with a methane-oxygen mixture. J. Phys. Chem., B. 103 (1999) 5227-5239
25. Shannon M.D., Lok C.M., and Casci J.L. Imaging promoter atoms in Fischer-Tropsch cobalt catalysts by aberration-corrected scanning transmission electron microscopy. J. Catal. 249 (2007) 41-51
26. 3 Fischer-Tropsch catalysts. Appl. Catal. A Gen. 307 (2006) 212-221
27. 2 Fischer-Tropsch catalysts as investigated by XPS and STEM-EELS. J. Catal. 230 (2005) 301-308
28. 2. Appl. Catal., A Gen. 196 (2000) 111-123
29. Heal M.J., Leisegang E.C., and Torington R.G. Infrared studies of carbon monoxide and hydrogen adsorbed on silica-supported iron and cobalt catalysts. J. Catal. 51 (1978) 314-325
30. 2 Fischer-Tropsch catalysts. Appl. Catal., A Gen. 181 (1999) 201-208
31. 3-based Fischer-Tropsch catalyst. J. Catal. 194 (2000) 401-409
32. Song D.C., Li J.L., and Cai Q. In situ diffuse reflectance FTIR study of CO adsorbed on a cobalt catalyst supported by silica with different pore sizes. J. Phys. Chem. C. 111 (2007) 18970-18979
33. 2 catalysts. J. Catal. 176 (1998) 415-425
34. Lei G.-D., and Kevan L. Characterization of ruthenium species generated in H-X zeolite: interaction with carbon monoxide, nitric oxide, oxygen, and water. J. Phys. Chem. 95 (1991) 4506-4514
35. Pfnur H., Menzel D., Hoffmann F.M., Ortega A., and Bradshaw A.M. High resolution vibrational spectroscopy of CO on Ru(0 0 1): the importance of lateral interactions. Surf. Sci. 93 (1980) 431-452
36. Zubkov T., Morgan Jr. G.A., Yates Jr. J.T., Kühlert O., Lisowski M., Schillinger R., Fick D., and Jänsch H.J. The effect of atomic steps on adsorption and desorption of CO on Ru(1 0 9). Surf. Sci. 526 (2003) 57-71
37. van Steen E., Claeys M., Dry M.E., van de Loosdrecht J., Viljoen E.L., and Visagie J.L. Stability of nanocrystals: thermodynamic analysis of oxidation and Re-reduction of cobalt in water/hydrogen mixtures. J. Phys. Chem., B. 109 (2005) 3575-3577