Synthesis and structural characterization of 3-O-ethylene glycol functionalized cellulose derivatives

Carbohydrate Polymers

Volumn 76, Issue 1, 2009, Pages 60-67

  Bar Nir, Batia Ben Aroya ^a   Kadla, John F ^a  

^a UNIVERSITY OF BRITISH COLUMBIA   (Canada)

Author keywords

2,6 Di O thexyldimethylsilyl cellulose; 3 O ethylene glycol 2,6 di O acetyl cellulose; Regioselectivity; Synthesis; T1 NMR experiments

Indexed keywords

CELLULOSE; CELLULOSE DERIVATIVES; ETHYLENE; EXPERIMENTS; GLYCOLS; NUCLEAR MAGNETIC RESONANCE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PSYCHOPHYSIOLOGY; REGIOSELECTIVITY;

2,6-DI-O-THEXYLDIMETHYLSILYL CELLULOSE; 3-O-ETHYLENE GLYCOL 2,6-DI-O-ACETYL CELLULOSE; CATALYTIC AMOUNTS; DEGREE OF SUBSTITUTIONS; FUNCTIONALIZED; NMR SPECTROSCOPIES; POLYMER CHAINS; PROLONGED REACTIONS; REACTION CONDITIONS; REACTION TIMES; REACTION YIELDS; STRUCTURAL CHARACTERIZATIONS; SYNTHESIS; SYNTHESIS OF; T1 NMR EXPERIMENTS;

ETHYLENE GLYCOL;

CELLULOSE; CELLULOSE DERIVATIVES; DEGRADATION; ETHYLENE; ETHYLENE GLYCOL; EXPERIMENTATION; GLYCOLS; NUCLEAR MAGNETIC RESONANCE; SPECTROSCOPY; SUBSTITUENT DISTRIBUTION; SYNTHESIS;

TETRA;

EID: 58149485174     PISSN: 01448617     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.carbpol.2008.09.026     Document Type: Article

References (17)

1. Buchanan C.M., Edgar K.J., Hyatt J.A., and Wilson A.K. Preparation of cellulose [1-C-13]acetates and determination of monomer composition by NMR-spectroscopy. Macromolecules 24 (1991) 3050-3059
2. Buchanan C.M., Edgar K.J., and Wilson A.K. Preparation and characterization of cellulose monoacetates: The relationship between structure and water solubility. Macromolecules 24 (1991) 3060-3064
3. Heinze T., Talaba P., and Heinze U. Starch derivatives of high degree of functionalization. 1. Effective, homogeneous synthesis of p-toluenesulfonyl (tosyl) starch with a new functionalization pattern. Carbohydrate Polymers 42 (2000) 411-420
4. Hernandez-Guerrero M., Davis T.P., Barner-Kowollik C., and Stenzel M.H. Polystyrene comb polymers built on cellulose or poly(styrene-co-2-hydroxyethylmethacrylate) backbones as substrates for the preparation of structured honeycomb films. European Polymer Journal 41 (2005) 2264-2277
5. Kadla J.F., Asfour F.H., and Bar-Nir B. Micropatterned thin film honeycomb materials from regiospecifically modified cellulose. Biomacromolecules 8 (2007) 161-165
6. Kasai W., and Kondo T. Fabrication of honeycomb-patterned cellulose films. Macromolecular Bioscience 4 (2004) 17-21
7. Klemm D., Heinze T., Philipp B., and Wagenknecht W. New approaches to advanced polymers by selective cellulose functionalization. Acta Polymerica 48 (1997) 277-297
8. Koschella A., Heinze T., and Klemm D. First synthesis of 3-O-functionalized cellulose ethers via 2, 6-di-O-protected silyl cellulose. Macromolecular Bioscience 1 (2001) 49-54
9. Liu C., and Baumann H. Exclusive and complete introduction of amino groups and their N-sulfo and N-carboxymethyl groups into the 6-position of cellulose without the use of protecting groups. Carbohydrate Research 337 (2002) 1297-1307
10. Nemoto J., Uraki Y., Kishimoto T., Sano Y., Funada R., Obata N., et al. Production of mesoscopically patterned cellulose film. Bioresource Technology 96 (2005) 1955-1958
11. Petzold K., Klemm D., Heublein B., Burchard W., and Savin G. Investigations on structure of regioselectively functionalized celluloses in solution exemplified by using 3-O-alkyl ethers and light scattering. Cellulose 11 (2004) 177-193
12. Ramsay G. DNA chips: State-of-the-art. Nature Biotechnology 16 (1998) 40-44
13. Sato K., Hasebe K., Tanaka M., Takebayashi M., Nishikawa K., Shimomura M., et al. Preparation of the honeycomb patterned porous film of biodegradable polymer for tissue engineering scaffolds. International Journal of Nanoscience 1 (2002) 689-693
14. Stenzel M.H. Formation of regular honeycomb-patterned porous film by self-organization. Australian Journal of Chemistry 55 (2002) 239-243
15. Stenzel M.H., Davis T.P., and Fane A.G. Honeycomb structured porous films prepared from carbohydrate based polymers synthesized via the RAFT process. Journal of Materials Chemistry 13 (2003) 2090-2097
16. Wijnhoven J.E.G.J., and Vos W.L. Preparation of photonic crystals made of air spheres in titania. Science 281 (1998) 802-804
17. Yue Z.L., and Cowie J.M.G. Preparation and chiroptical properties of a regioselectively substituted cellulose ether with PEO side chains. Macromolecules 35 (2002) 6572-6577