Investigations on the cure chemistry and polymer properties of benzoxazine-cyanate ester blends

European Polymer Journal

Volumn 45, Issue 2, 2009, Pages 494-502

  Santhosh Kumar, K S ^a   Reghunadhan Nair, C P ^a   Ninan, K N ^a  

^a INDIAN SPACE RESEARCH ORGANISATION   (India)

Author keywords

Co curing; Cyanate ester; Polybenzoxazine; Thermal properties

Indexed keywords

COBALT; COMPUTER NETWORKS; CURING; CYCLOADDITION; ESTERIFICATION; ESTERS; NITROGEN COMPOUNDS; ORGANIC COMPOUNDS; PHENOLIC RESINS; PHENOLS; POLYMERS; RESINS; THERMODYNAMIC PROPERTIES; THERMOSETS;

ANALYTICAL DATUMS; BENZOXAZINE; BISPHENOL; CO-CURING; CURE CHEMISTRIES; CURED BLENDS; CYANATE ESTER; CYCLOADDITION REACTIONS; HEAT OF REACTIONS; HIGH TEMPERATURES; POLYBENZOXAZINE; POLYCYANURATE; POLYMER PROPERTIES; REACTION TEMPERATURES; SINGLE BONDS; THERMAL PROPERTIES;

POLYMER BLENDS;

EID: 58149470360     PISSN: 00143057     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.eurpolymj.2008.11.001     Document Type: Article

References (25)

1. Ning X., and Ishida H. Phenolic materials via ring-opening polymerization: synthesis and characterization of bisphenol-A based benzoxazines and their polymers. J Polym Sci A Polym Chem 32 (1994) 1121-1129
2. Rimdusit S., and Ishida H. Development of new class of electronic packaging materials based on ternary systems of benzoxazine, epoxy, and phenolic resins. Polymer 41 (2000) 7941-7949
3. Liu Y.-L., and Chou C.-I. High performance benzoxazine monomers and polymers containing furan groups. J Polym Sci A Polym Chem 43 (2005) 5267-5282
4. Takeichi T., Agag T., and Zeidam R. Preparation and properties of polybenzoxazine/poly(imide-siloxane) alloys: in situ ring-opening polymerization of benzoxazine in the presence of soluble poly(imide-siloxane)s. J Polym Sci A Polym Chem 39 (2001) 2633-2641
5. Kiskan B., and Yagci Y. Synthesis and characterization of naphthoxazine functional poly(ε-caprolactone). Polymer 46 (2005) 11690-11697
6. Chen Q., Xu R., Zhang J., and Yu D. Polyhedral oligomeric silsesquioxane (POSS) nanoscale reinforcement of thermosetting resin from benzoxazine and bisoxazoline. Macromol Rapid Commun 26 (2005) 1878-1882
7. Cui Y., Chen Y., Wang X., Tian G., and Tang X. Synthesis and characterization of polyurethane/polybenzoxazine-based interpenetrating polymer networks (IPNs). Polym Inter 52 (2003) 1246-1248
8. Ishida H., and Allen D. Mechanical characterization of copolymers based on benzoxazine and epoxy. Polymer 37 (1996) 4487-4495
9. Santhosh Kumar K.S., Nair C.P.R., and Ninan K.N. Benzoxazine-bismaleimide blends: curing and thermal properties. Eur Polym J 43 (2007) 2504-2514
10. Santhosh Kumar K.S., Nair C.P.R., Sadhana R., and Ninan K.N. Bis allyl benzoxazine: synthesis, polymerisation and polymer properties. Eur Polym J 43 (2007) 5084-5096
11. Fang T., and Shimp D.A. Polycyanate esters: science and applications. Prog Polym Sci 20 (1995) 61-118
12. Fan J., Hu X., and Yue C.Y. Dielectric properties of self-catalytic interpenetrating polymer network based on modified bismaleimide and cyanate ester resins. J Polym Sci B Polym Phys 41 (2003) 1123-1134
13. Lakshmi M., and Reddy B.S.R. Synthesis and characterization of new epoxy and cyanate ester resins. Eur Polym J 38 (2002) 795-801
14. Nair C.P.R., Dona M., and Ninan K.N. Imido-phenolic-triazine network polymers derived from maleimide-functional novolac. Eur Polym J 37 (2001) 315-321
15. Hamerton I., and Hay J.N. Recent developments in the chemistry of cyanate esters. Polym Inter 47 (1998) 465-473
16. Hamerton I., and Hay J.N. Recent technological developments in cyanate ester resins. High Perform Polym 10 (1998) 163-174
17. Nair C.P.R., Mathew D., and Ninan K.N. Cyanate ester resins, recent developments. Adv Polym Sci 155 (2001) 1-99
18. Hamerton I. Chemistry and technology of ester resins (1994), Blackie Academic and Professional, Glasgow
19. Bartolomeo P., Chailan J.F., and Vernet J.L. Curing of cyanate ester resin: a novel approach based on FTIR spectroscopy and comparison with other techniques. Eur Polym J 37 (2001) 659-670
20. Mathew D., Nair C.P.R., and Ninan K.N. Catalysis of the cure reaction of bisphenol A dicyanate: a DSC study. J Polym Sci A Polym Chem 37 (1999) 1103-1114
21. Liang G., and Zhang M. Enhancement of processability of cyanate ester resin via copolymerization with epoxy resin. J Appl Polym Sci 85 (2002) 2377-2381
22. Laskoski M., Dominguez D.D., and Keller T.M. Development of an oligomeric cyanate ester resin with enhanced processability. J Mater Chem 15 (2005) 1611-1613
23. Ishida H., and Sanders D.P. Regioselectivity and network structure of difunctional alkyl-substituted aromatic amine-based polybenzoxazines. Macromolecules 33 (2000) 8149-8157
24. Bauer M., Bauer J., and Kuhn G. Analytik von prepolymeren und polymeren aromatischer cyansäureester. 2. Hochdruckflüssigchromatographie. Acta Polym 37 (1986) 218-220
25. Ward I.M., and Hadley D.W. An introduction to the mechanical properties of solid polymers (1993), Wiley, New York p. 93