Direct measurement of molecular mobility in actively deformed polymer glasses

Science

Volumn 323, Issue 5911, 2009, Pages 231-234

  Lee, Hau Nan ^a   Paeng, Keewook ^a   Swallen, Stephen F ^a   Ediger, M D ^a  

^a UNIVERSITY OF WISCONSIN MADISON   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

GLASS; POLY(METHYL METHACRYLATE); POLYMER;

ELEMENT MOBILITY; FORCE; GLASS; MEASUREMENT METHOD; MOLECULAR ANALYSIS; POLYMER;

ANISOTROPY; ARTICLE; BLEACHING; CORRELATION ANALYSIS; CROSS LINKING; ENVIRONMENT; FLUORESCENCE; MEASUREMENT; MOLECULAR MODEL; NUCLEAR MAGNETIC RESONANCE; PRIORITY JOURNAL; RELAXATION TIME; SPECTRUM; STRESS;

EID: 58149383775     PISSN: 00368075     EISSN: 10959203     Source Type: Journal    
DOI: 10.1126/science.1165995     Document Type: Article

References (31)

1. H. E. H. Meijer, L. E. Govaert, Prog. Polym. Sci. 30, 915 (2005).
2. H. Eyring, J. Chem. Phys. 4, 283 (1936).
3. R. E. Robertson, J. Chem. Phys. 44, 3950 (1966).
4. M. C. Boyce, D. M. Parks, A. S. Argon, Mech. Mater. 7, 15 (1988).
5. C. P. Buckley, D. C. Jones, Polymer 36, 3301 (1995).
6. J. M. Caruthers, D. B. Adolf, R. S. Chambers, P. Shrikhande, Polymer 45, 4577 (2004).
7. K. Chen, K. S. Schweizer, Europhys. Lett. 79, 26006 (2007).
8. A. J. Liu, S. R. Nagel, Nature 396, 21 (1998).
9. A. F. Yee, R. J. Bankert, K. L. Ngai, R. W. Rendell, J. Polym. Sci. Part Polym. Phys. 26, 2463 (1988).
10. J. J. Martinez-Vega, H. Trumel, J. L. Gacougnolle, Polymer 43, 4979 (2002).
11. L. C. E. Struik, Physical Aging in Amorphous Polymers and Other Materials (Elsevier, New York, 1978).
12. G. B. McKenna, J. Phys. Condens. Matter 15, S737 (2003).
13. L. S. Loo, R. E. Cohen, K. K. Gleason, Science 288, 116 (2000).
14. H.-N. Lee, K. Paeng, S. F. Swallen, M. D. Ediger, J. Chem. Phys. 128, 134902 (2008).
15. F. M. Capaldi, M. C. Boyce, G. C. Rutledge, Phys. Rev. Lett. 89, 175505 (2002).
16. A. V. Lyulin, B. Vorselaars, M. A. Mazo, N. K. Balabaev, M. A. J. Michels, Europhys. Lett. 71, 618 (2005).
17. R. A. Riggleman, H.-N. Lee, M. D. Ediger, J. J. de Pablo, Phys. Rev. Lett. 99, 215501 (2007).
18. R. A. Riggleman, K. S. Schweizer, J. J. de Pablo, Macromolecules 41, 4969 (2008).
19. Materials and methods are available as supporting material on Science Online.
20. M. D. Ediger, Annu. Rev. Phys. Chem. 51, 99 (2000).
21. R. Bergman, F. Alvarez, A. Alegria, J. Colmenero, J. Non-Cryst. Solids 235, 580 (1998).
22. H. G. H. van Melick, L. E. Govaert, H. E. H. Meijer, Polymer 44, 2493 (2003).
23. E. J. Kramer, J. Polym. Sci. Part B Polym. Phys. 43, 3369 (2005).
24. M. L. Falk, J. S. Langer, Phys. Rev. E 57, 7192 (1998).
25. P. Schall, D. A.Weitz, F. Spaepen, Science 318, 1895 (2007).
26. E. R. Weeks, J. C. Crocker, A. C. Levitt, A. Schofield, D. A. Weitz, Science 287, 627 (2000).
27. F. Casas, C. Alba-Simionesco, H. Montes, F. Lequeux, Macromolecules 41, 860 (2008).
28. K. Chen, K. S. Schweizer, Macromolecules 41, 5908 (2008).
29. C. T. Thurau, M. D. Ediger, J. Chem. Phys. 116, 9089 (2002).
30. T. K. Haxton, A. J. Liu, Phys. Rev. Lett. 99, 195701 (2007).
31. This work was supported by NSF through grant NIRT-0506840. We thank K. Schweizer, J. Caruthers, G. Medvedev, J. de Pablo, and R. Riggleman for helpful discussions.