Synthesis and characterization of sterically hindered diarylsilanes containing 2,4,6-trimethylphenyl and 2,4,6-tris(trifluoromethyl)phenyl substituents. X-ray crystal structure of bis[2,4,6-tris(trifluoromethylphenyl)]fluorosilane

Journal of Organometallic Chemistry

Volumn 499, Issue 1-2, 1995, Pages 89-98

  Braddock Wilking, Janet ^a   Schieser, Matt ^a   Brammer, Lee ^a   Huhmann, Jean ^a   Shaltout, Raef ^a  

^a UNIVERSITY OF MISSOURI ST LOUIS   (United States)

Author keywords

Aryl; Crystal structure; Group 14; Hindered (bulky) ligands; Mesityl; Silicon

Indexed keywords

EID: 58149362806     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/0022-328X(95)00327-M     Document Type: Article

References (41)

1. A Quantitative Scale for the Structural Effect on Reactivity toward Nucleophilic Displacement at Silicon.
2. The 2,4,6-Tris(trifluoromethyl)phenyl Substituent: An Ideal Combination of Steric and Electronic Stabilization
3. A second crystal modification of bis[2,4,6,-tris(trifluoromethyl)phenyl]stannylene: a stannylene (stannanediyl) dimer with weak tin?tin interactions
4. Spectroscopic and structural characterization of 2,4,6-tris(trifluoromethyl)phenyllithium�Et2O: a dimer stabilized by lithium ? fluorine contacts
5. Silicium-verbindungen mit starken intramolekularen sterischen wechselwirkungen
6. Darstellung neuartiger monomerer, oligomerer und polymerer Silyltriflate
7. Asymmetric Hydrosilylation
8. NMR spectra of benzenes containing trifluoromethyl groups.
9. Structure of a (4 + 4)-Coordinate Silicon Compound, a Precursor of Hypercoordinate Silyl Mono- and Dications
10. The Formation of Arylsilylpotassium Compounds