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Volumn 81, Issue 6, 2008, Pages 726-732

In situ electrochemical quartz crystal microbalance measurement of Au deposition and dissolution in room-temperature ionic liquid containing chloride ion

Author keywords

[No Author keywords available]

Indexed keywords

ANODIC DISSOLUTIONS; AU ELECTRODES; AU SURFACES; CATHODIC DEPOSITIONS; CHLORIDE IONS; CHRONOCOULOMETRY; ELECTROCHEMICAL QUARTZ CRYSTAL MICROBALANCES; ELECTRON REDUCTIONS; FREQUENCY CHANGES; IN-SITU; MASS CHANGES; METHYLIMIDAZOLIUM CHLORIDES; POLYCRYSTALLINE GOLDS; POTENTIAL RANGES; QUARTZ CRYSTALS; REDOX COUPLES; REFERENCE ELECTRODES; SAUERBREY EQUATIONS; TETRAFLUOROBORATE; VOLTAMMETRIC RESPONSES;

EID: 58149312564     PISSN: 00092673     EISSN: 13480634     Source Type: Journal    
DOI: 10.1246/bcsj.81.726     Document Type: Article
Times cited : (10)

References (45)
  • 4
    • 84951279351 scopus 로고    scopus 로고
    • G. Sauerbrey, Z. Phys. 1959, 155, 206.
    • G. Sauerbrey, Z. Phys. 1959, 155, 206.
  • 22
    • 0346469229 scopus 로고
    • ed. by D. Inman, D. G. Lovering, Plenum Press, New York
    • H. I. Chum, R. A. Osteryoung, in Ionic Liquids, ed. by D. Inman, D. G. Lovering, Plenum Press, New York, 1981, pp. 407-423.
    • (1981) Ionic Liquids , pp. 407-423
    • Chum, H.I.1    Osteryoung, R.A.2
  • 38
    • 58149278451 scopus 로고    scopus 로고
    • Since in general, RTIL has higher viscosity (by one-two orders of magnitude) than that of conventional solvents, as can be readily seen from the comparison of the viscosities of EMIBF4 and H2O 27 and 1.0 mPa s, the value of the resistance component for an electro-mechanical impedance of the quartz crystal electrode in RTIL is increased, and consequently compensation in oscillation circuit for the resulting resistance becomes increasingly difficult. Thus, the oscillation is apt to be unsteadied or stopped by overload and/or coupling with the impedance of the electrical circuits for measurement composed of potentiostat/galvanostat and laptop computer. Even if stable oscillation is gained, we need to confirm whether frequency changes are interpreted in terms of rigid mass changes or not. The most appropriate experiment to prove the hypothesis of rigid mass change is the electro-deposition of metal ion. Previously, we have reported that by means of ex situ quartz cr
    • 16b


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.