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Since in general, RTIL has higher viscosity (by one-two orders of magnitude) than that of conventional solvents, as can be readily seen from the comparison of the viscosities of EMIBF4 and H2O 27 and 1.0 mPa s, the value of the resistance component for an electro-mechanical impedance of the quartz crystal electrode in RTIL is increased, and consequently compensation in oscillation circuit for the resulting resistance becomes increasingly difficult. Thus, the oscillation is apt to be unsteadied or stopped by overload and/or coupling with the impedance of the electrical circuits for measurement composed of potentiostat/galvanostat and laptop computer. Even if stable oscillation is gained, we need to confirm whether frequency changes are interpreted in terms of rigid mass changes or not. The most appropriate experiment to prove the hypothesis of rigid mass change is the electro-deposition of metal ion. Previously, we have reported that by means of ex situ quartz cr
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