메뉴 건너뛰기




Volumn 80, Issue 10, 2007, Pages 1955-1964

Structure and properties of carbonyl-coordinated ruthenium(II) and osmium(II) porphyrin dimers bridged by aza ligands

Author keywords

[No Author keywords available]

Indexed keywords

BIPYRIDINE; ELECTROCHEMICAL MEASUREMENTS; INTRAMOLECULAR REDOX INTERACTIONS; METAL CENTERS; METAL OXIDATIONS; OXIDATION PROCESSES; OXIDATION WAVES; PORPHYRIN DIMERS; PORPHYRIN RINGS; PYRAZINE; STRUCTURE AND PROPERTIES; X-RAY CRYSTALLOGRAPHIES;

EID: 58149299571     PISSN: 00092673     EISSN: 13480634     Source Type: Journal    
DOI: 10.1246/bcsj.80.1955     Document Type: Article
Times cited : (9)

References (53)
  • 1
  • 4
    • 0001351196 scopus 로고    scopus 로고
    • ed. by K. M. Kadish, K. M. Smith, R. Guilard, Academic Press, New York, Chap. 46, p
    • a) H. Ogoshi, T. Mizutani, T. Hayashi, Y. Kuroda, in The Porphyrin Handbook, ed. by K. M. Kadish, K. M. Smith, R. Guilard, Academic Press, New York, 2000, Vol. 6, Chap. 46, p. 279.
    • (2000) The Porphyrin Handbook , vol.6 , pp. 279
    • Ogoshi, H.1    Mizutani, T.2    Hayashi, T.3    Kuroda, Y.4
  • 6
    • 0000000904 scopus 로고    scopus 로고
    • ed. by K. M. Kadish, K. M. Smith, R. Guilard, Academic Press, New York, Chap. 22, p
    • c) J. K. M. Sanders, in The Porphyrin Handbook, ed. by K. M. Kadish, K. M. Smith, R. Guilard, Academic Press, New York, 2000, Vol. 3, Chap. 22, p. 347.
    • (2000) The Porphyrin Handbook , vol.3 , pp. 347
    • Sanders, J.K.M.1
  • 7
    • 0000085682 scopus 로고    scopus 로고
    • ed. by K. M. Kadish, K. M. Smith, R. Guilard, Academic Press, NewYork, Chap. 57, p
    • a) D. Gust, T. A. Moore, in The Porphyrin Handbook, ed. by K. M. Kadish, K. M. Smith, R. Guilard, Academic Press, NewYork, 2000, Vol. 8, Chap. 57, p. 153.
    • (2000) The Porphyrin Handbook , vol.8 , pp. 153
    • Gust, D.1    Moore, T.A.2
  • 9
    • 84940906688 scopus 로고    scopus 로고
    • ed. by K. M Kadish, K. M. Smith, R. Guilard, Academic Press, New York
    • c) P. D. Harvey, in The Porphyrin Handbook, ed. by K. M Kadish, K. M. Smith, R. Guilard, Academic Press, New York, 2003, Vol. 18, p. 63.
    • (2003) The Porphyrin Handbook , vol.18 , pp. 63
    • Harvey, P.D.1
  • 14
    • 0001110345 scopus 로고    scopus 로고
    • ed. by K. M. Kadish, K. M. Smith, R. Guilard, Academic Press, New York, Chap. 40, p
    • J.-L. Chambron, V. Heitz, J.-P. Sauvage, in The Porphyrin Handbook, ed. by K. M. Kadish, K. M. Smith, R. Guilard, Academic Press, New York, 2000, Vol. 6, Chap. 40, p. 1.
    • (2000) The Porphyrin Handbook , vol.6 , pp. 1
    • Chambron, J.-L.1    Heitz, V.2    Sauvage, J.-P.3
  • 27
    • 58149316934 scopus 로고    scopus 로고
    • Abbreviations: ttp, 5,10,15,20-tetra-p-tolylporphyrinato dianion; oep, 2,3,7,8,12,13,17,18-octaethylporphyrinato dianion; py, pyridine; mpy, 4-methylpyridine; pz, pyrazine; bpy, 4,4′-bipyridine; dabco, l,4-diazabicyclo[2,2,2]octane; TBAP, tetrabutylammonium perchlorate; TBAPF6, tetra-butylammonium hexafluorophosphate; DDQ, 2,3-dichloro-5,6-dicyano-l,4-benzoquinone; CV, Cyclic Voltammetry; DPV, Differential Pulse Voltammetry
    • 6) = tetra-butylammonium hexafluorophosphate; DDQ = 2,3-dichloro-5,6-dicyano-l,4-benzoquinone; CV = Cyclic Voltammetry; DPV = Differential Pulse Voltammetry.
  • 28
    • 58149283226 scopus 로고    scopus 로고
    • 2(BL)J showed two oxidation processes. Each of these two oxidation processes involved two-electron transfers. However, the splits in each oxidation process have not been reported, because they are very small, though stepwise one-electron transfers at the first oxidation process have been suggested.
    • 2(BL)J showed two oxidation processes. Each of these two oxidation processes involved two-electron transfers. However, the splits in each oxidation process have not been reported, because they are very small, though stepwise one-electron transfers at the first oxidation process have been suggested.
  • 31
    • 58149296889 scopus 로고    scopus 로고
    • CrystalClear
    • CrystalClear, Rigaku Co., 1999.
    • (1999) Rigaku Co
  • 32
    • 58149286919 scopus 로고    scopus 로고
    • CrystalStructure 3.6.0: Crystal Structure Analysis Package, Rigaku and Rigaku/MSC, 9009 New Trails Dr., The Woodlands TX 77381, U.S.A., 2000-2004.
    • CrystalStructure 3.6.0: Crystal Structure Analysis Package, Rigaku and Rigaku/MSC, 9009 New Trails Dr., The Woodlands TX 77381, U.S.A., 2000-2004.
  • 39
    • 58149303615 scopus 로고    scopus 로고
    • The hydrogen atoms were located at the calculated position. An acceptable R value and the normal shape of tolyl groups allowed the evaluation of H⋯H distance.
    • The hydrogen atoms were located at the calculated position. An acceptable R value and the normal shape of tolyl groups allowed the evaluation of H⋯H distance.
  • 40
    • 58149286918 scopus 로고    scopus 로고
    • Because ethyl groups showed disorder and because the terminal methyl groups can rotate around the C-C bonds, not the H⋯H distance but the C⋯C distance was used for discussion of the oep complexes
    • Because ethyl groups showed disorder and because the terminal methyl groups can rotate around the C-C bonds, not the H⋯H distance but the C⋯C distance was used for discussion of the oep complexes.
  • 41
    • 58149288955 scopus 로고    scopus 로고
    • In this setting, the minimum H⋯H separation becomes 2.20 Å if mirror symmetry is supposed. However, the ethyl group is flexible and the small rotation of terminal methyl group can evade such close contact.
    • In this setting, the minimum H⋯H separation becomes 2.20 Å if mirror symmetry is supposed. However, the ethyl group is flexible and the small rotation of terminal methyl group can evade such close contact.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.