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58149316934
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Abbreviations: ttp, 5,10,15,20-tetra-p-tolylporphyrinato dianion; oep, 2,3,7,8,12,13,17,18-octaethylporphyrinato dianion; py, pyridine; mpy, 4-methylpyridine; pz, pyrazine; bpy, 4,4′-bipyridine; dabco, l,4-diazabicyclo[2,2,2]octane; TBAP, tetrabutylammonium perchlorate; TBAPF6, tetra-butylammonium hexafluorophosphate; DDQ, 2,3-dichloro-5,6-dicyano-l,4-benzoquinone; CV, Cyclic Voltammetry; DPV, Differential Pulse Voltammetry
-
6) = tetra-butylammonium hexafluorophosphate; DDQ = 2,3-dichloro-5,6-dicyano-l,4-benzoquinone; CV = Cyclic Voltammetry; DPV = Differential Pulse Voltammetry.
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28
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58149283226
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2(BL)J showed two oxidation processes. Each of these two oxidation processes involved two-electron transfers. However, the splits in each oxidation process have not been reported, because they are very small, though stepwise one-electron transfers at the first oxidation process have been suggested.
-
2(BL)J showed two oxidation processes. Each of these two oxidation processes involved two-electron transfers. However, the splits in each oxidation process have not been reported, because they are very small, though stepwise one-electron transfers at the first oxidation process have been suggested.
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58149303615
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The hydrogen atoms were located at the calculated position. An acceptable R value and the normal shape of tolyl groups allowed the evaluation of H⋯H distance.
-
The hydrogen atoms were located at the calculated position. An acceptable R value and the normal shape of tolyl groups allowed the evaluation of H⋯H distance.
-
-
-
-
40
-
-
58149286918
-
-
Because ethyl groups showed disorder and because the terminal methyl groups can rotate around the C-C bonds, not the H⋯H distance but the C⋯C distance was used for discussion of the oep complexes
-
Because ethyl groups showed disorder and because the terminal methyl groups can rotate around the C-C bonds, not the H⋯H distance but the C⋯C distance was used for discussion of the oep complexes.
-
-
-
-
41
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58149288955
-
-
In this setting, the minimum H⋯H separation becomes 2.20 Å if mirror symmetry is supposed. However, the ethyl group is flexible and the small rotation of terminal methyl group can evade such close contact.
-
In this setting, the minimum H⋯H separation becomes 2.20 Å if mirror symmetry is supposed. However, the ethyl group is flexible and the small rotation of terminal methyl group can evade such close contact.
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42
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