Direct synthesis and characterization of amine-functionalized mesoporous silica materials and their applications as formaldehyde adsorbents

Environmental Engineering Science

Volumn 25, Issue 10, 2008, Pages 1477-1485

  Sae Ung, Srisuda ^a   Boonamnuayvitaya, Virote ^a  

^a KING MONGKUT'S UNIVERSITY OF TECHNOLOGY THONBURI   (Thailand)

Author keywords

Amine; Characterization; Formaldehyde; Functionalization; Mesoporous materials

Indexed keywords

ADSORPTION DATUMS; ADSORPTIVE CAPACITIES; AMINE FUNCTIONAL GROUPS; AMINE GROUPS; BET SURFACES; CETYL TRIMETHYL AMMONIUM BROMIDES; CHEMICAL STRUCTURES; DIRECT SYNTHESES; EXTRACTION METHODS; FOURIER TRANSFORM INFRARED; FREUNDLICH; FTIR SPECTRUMS; FUNCTIONALIZATION; FUNCTIONALIZED MATERIALS; FUNCTIONALIZED MESOPOROUS; GASEOUS FORMALDEHYDES; HIGH CONCENTRATIONS; LANGMUIR; LANGMUIR ISOTHERMS; MESOPOROUS SILICAS; NITROGEN ADSORPTIONS; PORE SURFACES; PORE VOLUMES; PORE WALLS; SILICA MATRIXES; SOLID-STATE NMR; SURFACE AREAS; SURFACTANT TEMPLATES; TETRAETHOXY SILANES; TEXTURAL PROPERTIES;

ADSORBENTS; ADSORPTION; AMINES; AMMONIUM COMPOUNDS; ATMOSPHERIC TEMPERATURE; CHEMICAL PROPERTIES; FORMALDEHYDE; FOURIER TRANSFORM INFRARED SPECTROSCOPY; FOURIER TRANSFORMS; FUNCTIONAL GROUPS; GAS ADSORPTION; INFRARED SPECTROSCOPY; ISOTHERMS; MAGNETIC RESONANCE; MATERIALS PROPERTIES; MESOPOROUS MATERIALS; NUCLEAR MAGNETIC RESONANCE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; ORGANIC COMPOUNDS; OXIDES; SILICA; SURFACE ACTIVE AGENTS; SYNTHESIS (CHEMICAL); TRANSMISSION ELECTRON MICROSCOPY;

SURFACES;

EID: 58149242767     PISSN: 10928758     EISSN: None     Source Type: Journal    
DOI: 10.1089/ees.2007.0237     Document Type: Conference Paper

References (28)

1. Aguado, J., Arsuaga, J.M., and Arencibia, A. (2005). Adsorption of aqueous mercury (II) on propylthiol-functionalized mesoporous silica obtained by cocondensation. Ind. Eng. Chem. Res. 44, 3665.
2. Barrett, E.P., Joyner, L.G., and Halenda, P.P. (1951). The determination of pore volume and area distributions in porous substances. I. Computations from nitrogen isotherms. J. Am. Chem. Soc. 73, 373.
3. Beck, J.S., Vartuli, J.C., Roth, W.J., Leonowicz, M.E., Kresge, C.T., Schmitt, K.D., Chu, C.T.W., Olson, D.H., Sheppard, E.W., Mc Ullen, S.B., Higgins, J.B., and Schlenker, J.L. (1992). A new family of mesoporous molecular sieves prepared with liquid crystal templates. J. Am. Chem. Soc. 114, 10834.
4. Boonamnuayvitaya, V., Sae-ung, S., and Tanthapanichakoont, W. (2005). Preparation of activated carbons from coffee residue for the adsorption of formaldehyde. Separation and Purification Technol. 42, 159.
5. Brunauer, S., Emmett, P.H., and Teller, E. (1938). Adsorption of gases in multimolecular layers. J. Am. Chem. Soc. 60, 309.
6. Chong, A.S.M. and Zhao, X.S. (2004) Functionalized nanoporous silicas for the immobilization of penicillin acylase. Appl. Surf. Sci. 237, 398.
7. Chong, A.S.M., Zhao, X.S., Kustedjok, A.T., and Qiao, S.Z. (2004). Functionalization of large-pore mesoporous silicas with organosilanes by direct synthesis. Micropor. Mesopor. Mater. 72, 33.
8. Freundlich, H.M.F. (1906). öber die adsorption in lösungen. Z. Phys. Chem. 57, 385.
9. Hall, K.R., Eagleton, L.C., Acrivos, A., and Vermeulen, T. (1996). Pore and solid diffusion kinetics in fixed-bed adsorption under constant pattern conditions. Ind. Eng. Chem. Fundam. 5, 212-223.
10. Halsey, G. (1948). Physical adsorption on non-uniform surfaces. J. of Chem. Phys. 16, 931.
11. Kresge, C.T., Leonowicz, M.E., Roth, W.J., Vartuli, T.C., and Beck, J.S. (1992). Ordered mesoporous molecular sieves synthesized by a liquid crystal template mechanism. Nature 359, 710.
12. Langmuir, I. (1918). The adsorption of gases on plane surfaces of glass, mica and platinum. J. Am. Chem. Soc. 40, 1361.
13. László, K. (2005). Characterization and adsorption properties of polymer-based microporous carbons with different surface chemistry. Microporous and Mesoporous Mater. 80, 205.
14. Lee, B., Kim, Y., Lee, H., and Yi, J. (2001). Synthesis of functionalized porous silicas via templating method as heavy metal ion adsorbents: The introduction of surface hydrophilicity onto the surface of adsorbents. Micropor. Mesopor. Mater. 50, 77.
15. Lesaint, C., Lebeau, B., Marichal, C., and Patarin, J. (2005). Synthesis of mesoporous silica materials functionalized with n-propyl groups. Micropor. Mesopor. Mater. 83, 76.
16. Luechinger, M., Prins, R., and Pirngruber, G.D. (2005). Functionalization of silica surfaces with mixtures of 3-aminopropyl and methyl groups. Micropor. Mesopor. Mater. 85, 111.
17. Margolese, D., Melero, J.A., Christianaen, S.C., Chnelka, B.F., and Stuvky, G.D. (2000). Direct syntheses of ordered SBA-15 Mesoporous silica containing sulfonic acid groups. Chem. Mater. 12, 2448.
18. Pérez-Quintanilla, D., Hierro, I.d., Fajardo, M., and Sierra, I. (2006a). 2-mercaptothiazoline modified mesoporous silica for mercury removal from aqueous media. J. Hazard. Mater. 134, 245.
19. Pérez-Quintanilla, D., Hierro, I.d., Fajardo, M., and Sierra, I. (2006b). Mesoporous silica functionalized with 2-mercaptopyridine: Synthesis, characterization and employment for Hg (II) adsorption. Micropor. Mesopor. Mater. 89, 58.
20. Rong, H., Ryu, Z., Zheng, J., and Zhang, Y. (2003). Influence of heat treatment of rayon-based activated carbon fibers on the adsorption of formaldehyde. J. Colloid and Interface Sci. 261, 207.
21. Sae-ung, S., and Boonamnuayvitaya, V. (2008). One-pot synthesis of organic-inorganic hybrid mesoporous materials for the adsorption of formaldehyde vapor. Environ. Eng. Sci. In Press.
22. Sing, K.S.W., Everett, D.H., Haul, R.A.W., Moscou, L., Pierotti, R.A., Rouquerol, J., and Siemieniewska, E. (1985). Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity. Pure & Appl. Chem. 57, 603.
23. Socrates, G. (2001). Infrared and Raman Characteristic Group Frequencies: Tables and Charts, 3rd ed. West Sussex: John Wiley & Sons.
24. Suzuki, T. (2001). Development and application of formaldehyde adsorbent. R&D Review of Toyota CRDL. 36 (4).
25. Temkin, M.I., and Pyzhev, V. (1940). Kinetics of ammonia synthesis on promoted iron catalyst. Acta Physiochim. URSS. 12, 327.
26. Wang, J., Yu, N., Zheng, A., Yang, J., Wu, D., Sun, Y., Ye, C., and Deng, F. (2006). Mesoporous MSU materials functionalized with sulfonic group: A multinuclear NMR and theoretical calculation study. Micropor. Mesopor. Mater. 89, 219.
27. Wang, L., Qi, T., and Zhang, Y. (2006). Novel organic-inorganic hybrid mesoporous materials for boron adsorption. Colloids. Surface. A. 275, 73.
28. Wang, X., Tseng, Y.-H., Chan, J.C.C., and Cheng, S. (2005). Direct synthesis of highly ordered large-pore functionalized mesoporous SBA-15 silica with methylaminopropyl groups and its catalytic reactivity in flavanone synthesis. Micropor. Mesopor. Mater. 85, 241.