Reactivity ratios and monomer partitioning in the microemulsion copolymerization of vinyl acetate and butyl acrylate

Journal of Applied Polymer Science

Volumn 111, Issue 1, 2009, Pages 329-337

  Ovando Medina, Víctor M ^a   Martínez Gutiérrez, Hugo ^a   Mendizábal, Eduardo ^b   Corona, Miguel A ^b   Peralta, René D ^a,c  

^a CENTRO DE INVESTIGACIÓN EN QUÍMICA APLICADA   (Mexico)

^b UNIVERSITY OF GUADALAJARA   (Mexico)

^c UNIVERSIDAD AUTÓNOMA DE SAN LUIS POTOSÍ   (Mexico)

Author keywords

Copolymerization; Kinetics (polym.); Microstructure; Modeling; Radical polymerization

Indexed keywords

ATOM TRANSFER RADICAL POLYMERIZATION; CATALYST ACTIVITY; CHEMICAL REACTIONS; ETHERS; ETHYLENE; FREE RADICAL POLYMERIZATION; MICROEMULSIONS; MICROSTRUCTURE; MONOMERS; POLYETHYLENE OXIDES; POLYMERIZATION; POLYMERS; POLYVINYL ACETATES; POTASSIUM; SODIUM; SODIUM SULFATE;

ACRYLATE SYSTEMS; BULK COPOLYMERIZATIONS; BUTYL ACRYLATES; COPOLYMER COMPOSITIONS; DODECYL ETHERS; EXPERIMENTAL DATUMS; HETEROGENEOUS POLYMERIZATIONS; MICROEMULSION COPOLYMERIZATIONS; MICROEMULSION DROPLETS; MODELING; MONOMER PARTITIONING; MONOMER REACTIVITY RATIOS; POLY(ETHYLENE OXIDE); POLYMER PARTICLES; POTASSIUM PERSULFATES; RADICAL POLYMERIZATION; REACTIVITY RATIOS; SODIUM DODECYL SULFATES; TRUE VALUES; VINYL ACETATES;

COPOLYMERIZATION;

COPOLYMER; COPOLYMERIZATION; EMULSION; MONOMER; POLYETHYLENE OXIDE; STABILIZING AGENT;

EID: 58149233853     PISSN: 00218995     EISSN: 10974628     Source Type: Journal    
DOI: 10.1002/app.29041     Document Type: Article

References (32)

1. Shi, Y.; Wu, Y.; Hao, J.; Li, G. J Polym Sci Part A: Polym Chem 2005, 43, 203.
2. Herrera, J. R.; Peralta, R. D.; López, R. G.; Cesteros, L. C.; Mendizábal, E.; Puig, J. E. Polymer 2003, 44, 1795.
3. Puig, J. E. Investigación Tecnológica (Academia de Ingeniería, México) 2005. http://www.ai.org.mx/anterior/revista/ numeros-anteriores.htm (accessed July 2008).
4. O'Donnell, J.; Kaler, E. Macromol Rapid Commun 2007, 28, 1445.
5. Kim, N.; Sudol, E. D.; Dimonie, V. L.; El-Aasser, M. S. Macro-molecules 2004, 37, 2427.
6. Sanghvi, P. G.; Pokhriyal, N. K.; Devi, S. J Appl Polym Sci 2002, 84, 1832.
7. Polic, A. L.; Duever, T. A.; Penlidis, A. J Polym Sci Part A: Polym Chem 1998, 36, 813.
8. Klumperman, B.; Aerdts, A. Macromolecules 1996, 29, 6679.
9. Bhawal, S.; Sanghvi, P. G.; Devi, S. Eur Polym J 2003, 39, 389.
10. Emelie, B.; Pichot, C.; Guillot, J. Makromol Chem 1991, 192, 1629.
11. Bevington, J. C.; Harris, D. O. J Polym Sci Polym Lett Ed 1967, 5, 799.
12. Tidwell, P. W.; Mortimer, G. A. J Polym Sci Part A: Gen Pap 1965, 3, 369.
13. Van der Meer, R.; Linssen, H. N.; German, A. L. J Polym Sci Polym Chem Ed 1978, 16, 2915.
14. Patiño-Leal, H.; Reilly, P. M.; O'Driscoll, K. F. J Polym Sci Polym Lett Ed 1980, 18, 219.
15. Hagiopol, C. Copolymerization: Toward a Systematic Approach; Kluwer Academic/Plenum: New York, 1999.
16. Mayo, F. R.; Lewis, F. M. J Am Chem. Soc 1944, 66, 1594.
17. Araujo, O.; Giudici, R.; Saldívar, E.; Ray, W. H. J Appl Polym Sci 2001, 79, 2360.
18. De la Cal, J. C.; Leiza, J. R.; Asua, J. M. J Polym Sci Part A: Polym Chem 1991, 29, 155.
19. Ugelstad, J.; Mork, P. C.; Mfutakamba, H. R.; Soleimany, E.; Nordhuus, I.; Nustad, K.; Schmid, R.; Berge, A.; Ellingsen, T.; Aune, O. In Science and Technology of Polymer Colloids; Poehlein, G. W.; Ottewill, R. H.; Goodwins, J. W., Eds.; NATO ASI Series; Kluwer Academic Publishers B.V.: Dordrecht, The Netherlands, 1983; Vol. 1, p 51.
20. Stewart, W.; Caracotsios, M.; Serensen, J. GREG; University of Wisconsin: Madison, WI, 1990.
21. Pichot, C.; Llauro, M. F.; Pham, Q. T. J Polym Sci Polym Chem Ed 1981, 19, 2619.
22. Dubé, M. A.; Penlidis, A. Polymer 1995, 36, 587.
23. Bataille, P.; Bourassa, H. J Polym Sci Part A: Polym Chem 1989, 27, 357.
24. Polymer Handbook, 3rd ed.; Brandaip, J.; Immergut, H., Eds.; Wiley: New York, 1989.
25. Guo, J. S.; Sudol, E. D.; Vanderhoff, J. W.; El-Aasser, M. S. J Polym Sci Part A: Polym Chem 1992, 30, 691.
26. Delgado, J. Ph.D. Thesis, Lehigh University, 1986.
27. Kong, X. Z.; Pichot, C.; Guillot, J. Eur Polym J 1988, 24, 485.
28. Gugliotta, L. M.; Arzamendi, G.; Asua, J. M. J Appl. Polym Sci 1995, 55, 1017.
29. Gao, J.; Penlidis, A. Prog Polym Sci 2002, 27, 403.
30. Montgomery, D. R.; Fry, C. E. J Polym Sci Part C: Polym Symp 1968, 25, 59.
31. Noel, L. F. J.; Maxwell, I. A.; German, A. L. Macromolecules 1993, 26, 2911.
32. Odian, G. Principles of Polymerization, 4th ed.; Wiley: Hoboken, NJ, 2004.