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The epoxide cleavage probably involves the formation of a tertiary carbocation as intermediate, then the acetic acid attack being favoured by the β-side of the carbocation, the less steric hindered one, which explains the major formation of product 2.
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The epoxide cleavage probably involves the formation of a tertiary carbocation as intermediate, then the acetic acid attack being favoured by the β-side of the carbocation, the less steric hindered one, which explains the major formation of product 2.
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