Compatibility of polymers and chemical oxidants for enhanced groundwater remediation

Environmental Science and Technology

Volumn 42, Issue 24, 2008, Pages 9296-9301

  Smith, Megan M ^a   Silva, Jeff A K ^a   Munakata Marr, Junko ^a   Mccray, John E ^a  

^a Department of Geology and Geological Engineering   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

APPLICATIONS.; CHEMICAL COMPATIBILITIES; CHEMICAL OXIDANTS; CHEMICAL OXIDATIONS; COMPETITIVE EFFECTS; GROUNDWATER REMEDIATIONS; GROUNDWATER TREATMENTS; HETEROGENEOUS AQUIFERS; HYDROLYZED POLYACRYLAMIDE; IN SITU CHEMICAL OXIDATIONS; NONTOXIC POLYMERS; ORGANIC CONTAMINANTS; OXIDANT CONSUMPTIONS; OXIDATION RATES; POLYMER FLOODS; POTASSIUM PERMANGANATES; SODIUM PERSULFATES; SOLUTION VISCOSITIES; TETRACHLOROETHENE; VISCOSITY LOSSES;

AQUIFERS; CATALYST ACTIVITY; DISSOLUTION; GROUNDWATER; GROUNDWATER POLLUTION; GROUNDWATER RESOURCES; HYDRODYNAMICS; HYDROGEOLOGY; IMPURITIES; ORGANIC POLYMERS; OXIDATION; PHOTORESISTS; POLLUTION; POLYMERS; POTASSIUM; SODIUM; TURBULENT FLOW; UNDERGROUND RESERVOIRS; VISCOSITY; WATER TREATMENT;

OXIDANTS;

EXPERIMENTAL STUDY; GROUNDWATER POLLUTION; HYDROLYSIS; ORGANIC POLLUTANT; OXIDANT; OXIDATION; POLYMER; POLYSACCHARIDE; REMEDIATION; VISCOSITY;

ENVIRONMENTAL REMEDIATION; MANGANESE COMPOUNDS; OXIDANTS; OXIDATION-REDUCTION; OXIDES; POLYMERS; POTASSIUM PERMANGANATE; SOIL; TIME FACTORS; VISCOSITY; WATER POLLUTANTS; WATER SUPPLY;

EID: 58149174243     PISSN: 0013936X     EISSN: None     Source Type: Journal    
DOI: 10.1021/es800757g     Document Type: Article

References (27)

1. Baijal, S. K. Flow Behavior of Polymers in Porous Media; PennWell Publishing Co.: Tulsa, OK, 1982.
2. Lake, L. W. Enhanced Oil Recovery; Prentice-Hall: Englewood Cliffs, NJ, 1989.
3. Sandiford, B. B. Flow of polymers through porous media in relation to oil displacement. In Improved Oil Recovery by Surfactant and Polymer Flooding; Shah, D. O., Schechter, R. S., Eds.; Academic Press: New York, 1977.
4. Sorbie, K. S. Polymer-Improved Oil Recovery; CRC Press: Boca Raton, FL, 1991.
5. Martel, K. E.; Martel, R; Lefebvre, R; Gélinas, P. J. Laboratory study of polymer solutions used for mobility control during in situ NAPL recovery. Ground Water Monit. Remediat. 1998, 18, 103-113.
6. Martel, R.; Hébert, A.; Lefebvre, R.; Gélinas, P.; Gabriel, U. Displacement and sweep efficiencies in a DNAPL recovery test using micellar and polymer solutions injected in a five-spot pattern. J. Contam. Hydrol. 2004, 75, 1-29.
7. Robert, T.; Martel, R.; Conrad, S. H.; Lefebvre, R.; Gabriel, U. Visualization of TCE recovery mechanisms using surfactant-polymer in a two-dimensional heterogeneous sand model. J. Contam. Hydrol. 2006, 86, 3-31.
8. Siegrist, R. L.; Urynowicz, M. A.; West, O. A.; Crimi, M. L.; Lowe, K. S. Principles and Practices of In Situ Chemical Oxidation Using Permanganate; Battelle Press; Columbus, OH, 2001.
9. Stroo, H. F.; Unger, M.; Kavanaugh, M. C.; Vogel, C.; Leeson, A; Marqusee, J. A.; Smith, B. P. Remediating chlorinated solvent source zones. Environ. Sci. Technol. 2003, 37, 224A-230A.
10. Green, V. S.; Stott, D. E. Polyacrylamide: a review of the use, effectiveness, and cost of a soil erosion control amendment. In Sustaining the Global Farm - Selected Papers from the 10th International Soil Conservation Organization Meeting, Purdue University, Lafayette, IN, 2001.
11. Huling, S.G.; Pivetz, B. In-situ Chemical Oxidation-Engineering Issue; EPA/600/R-06/072; U.S. Environmental Protection Agency: Washington, DC, 2007.
12. Yan, Y. E.; Schwartz, F. W. Oxidative degradation and kinetics of chlorinated ethylenes by potassium permanganate. J. Contam. Hydrol. 1999, 37, 343-365.
13. Schroth, M. H.; Oostrum, M.; Wietsma, T. W.; Istok, J. D. In-situ oxidation of trichloroethene by permanganate: effects on porous medium hydraulic properties. J. Contam. Hydrol. 2001, 50, 79-98.
14. Watts, R. J.; Teel, A. L. Treatment of contaminated soils and groundwater using ISCO. Pract. Periodical Hazard. Toxic Radioact. Waste Manage. 2006, 10, 2-9.
15. Tunnicliffe, B. S.; Thomson, N. R. Mass removal of chlorinated ethenes from rough-walled fractures using permanganate. J. Contam. Hydrol. 2004, 75, 91-114.
16. Zhai, X.; Hua, I.; Rao, P. S. C.; Lee, L. S. Cosolvent-enhanced chemical oxidation of perchloroethylene by potassium permanganate. J. Contam. Hydrol. 2006, 82, 61-74.
17. Waldemer, R. H.; Tratnyek, P. G. Kinetics of contaminant degradation by permanganate. Environ. Sci. Technol. 2006, 40, 1055-1061.
18. Krembs, F. J. Critical analysis of the field scale application of in situ chemical oxidation for the remediation of groundwater. M.S. Thesis, Environmental Science & Engineering Division, Colorado School of Mines, Golden, CO, 2008.
19. Petri, B. G.; Siegrist, R. L.; Crimi, M. L. Effects of groundwater velocity and permanganate concentration on DNAPL mass depletion rates during in situ oxidation. J. Environ. Eng. 2008, 134, 1-13.
20. Huang, K.; Couttenye, R. A.; Hoag, G. E. Kinetics of heat-assisted persulfate oxidation of methyl tert-butyl ether (MTBE). Chemosphere 2002, 49, 413-420.
21. Liang, C. J.; Bruell, C. J.; Marley, M. C.; Sperry, K. L. Persulfate oxidation for in situ oxidation of TCE. I. Activated by ferrous iron with and without a persulfate-thiosulfate redox couple. Chemosphere 2004, 55, 1213-1223.
22. Khairou, K. S. Kinetics and decomposition of intermediate complex during oxidation of pectate polysaccharide by potassium permanganate in alkaline solutions. Int. J. Chem. Kinet. 2002, 35, 67-72.
23. Ahmed, G. A.; Khairou, K. S.; Hassan, R. M. Kinetics and mechanism of oxidation of chitosan polysaccharide by permanganate ion in aqueous perchlorate solutions. J. Chem. Res. 2003, (S), 182-183.
24. El-Khatib, R. M. Spectrophometric detection of methyl cellulose-manganate(VI) intermediate complex in the oxidation of methyl cellulose by alkaline permanganate. Carbohydr. Polym. 2002, 47, 377-385.
25. Huang, K.; Haog, G. E.; Chheda, P.; Woody, B. A.; Dobs, G. D. Oxidation of chlorinated ethenes by potassium permanganate: a kinetics study. J. Hazard. Mater. 2001, B87, 155-169.
26. Hood, E. D.; Thomson, N. R.; Grossi, D.; Farquhar, G. J. Experimental determination of the kinetic rate law for the oxidation of perchloroethylene by potassium permanganate. Chemosphere 2000, 40, 1383-1388.
27. Poulson, S. R.; Naraoka, H. Carbon isotope fractionation during permanganate oxidation of chlorinated ethylenes (cDCE, TCE, PCE). Environ. Sci. Technol. 2002, 36, 3270-3274.