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The horseshoe-like structure for the 12-mer was configured by starting with a symmetric 15 transition dipole ring and three adjacent dipoles were removed to form a gap that had an angle equivalent to approximately 2π/5. Molecular modeling of an isotactic 12-mer macrocycle (where the 9,9-dimethylfluorene groups are configured anti with respect to each adjacent unit) predicted that the gap region covered approximately this angle. The anisotropy simulation result in a biexponential decay with two approximately equal amplitude components and time constants differing by a factor of 10.
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