Structure and photophysical properties of new trinuclear lanthanide complexes (Ln = Eu and Tb) with 1,10-phenanthroline

Inorganic Chemistry Communications

Volumn 12, Issue 1, 2009, Pages 52-54

  Wong, Ka Leung ^a   Zhu, Yi Min ^b   Yang, Yang Yi ^b   Law, Ga Lai ^c   Fan, Hai Hua ^a,c   Tanner, Peter A ^a   Wong, Wing Tak ^c  

^a CITY UNIVERSITY OF HONG KONG   (Hong Kong)

^b SUN YAT SEN UNIVERSITY   (China)

^c UNIVERSITY OF HONG KONG   (Hong Kong)

Author keywords

Europium; Lanthanide complexes; Luminescence; Terbium; Trinuclear

Indexed keywords

EID: 58149105276     PISSN: 13877003     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.inoche.2008.11.002     Document Type: Article

References (19)

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16. Synthesis: The respective lanthanide sulphate salt (Ln = Eu, Tb, ∼0.078 g, 0.1 mol) was dissolved in methanol (10 ml) with 1,10-phenanthroline (∼0.018 g, 0.1 mmol). The mixture was then stirred at room temperature for 3 h. Colorless powders were obtained upon slow evaporation of solvent at room temperature. Colorless crystals were obtained after re-crystallization from DMF.
17. 4: C: 33.34, H: 3.21, N: 8.10. FAB MS: m/z 1711.
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