One-part geopolymer mixes from geothermal silica and sodium aluminate

Industrial and Engineering Chemistry Research

Volumn 47, Issue 23, 2008, Pages 9396-9405

  Hajimohammadi, Ailar ^a   Provis, John L ^a   Van Deventer, Jannie S J ^a  

^a UNIVERSITY OF MELBOURNE   (Australia)

Author keywords

[No Author keywords available]

Indexed keywords

ALUMINOSILICATES; CEMENT MANUFACTURE; OXIDES; PORTLAND CEMENT; SILICA; SILICATES; SODIUM; WATER CONTENT;

AL CONCENTRATIONS; ALKALI ACTIVATORS; BULK PRODUCTIONS; COMMERCIAL VIABILITIES; CRYSTALLINITY; GEOPOLYMER; GEOPOLYMERIZATION; GEOPOLYMERS; SI CONCENTRATIONS; SODIUM ALUMINATES; SOLID SILICAS; SOLID SOURCES; VISCOUS SOLUTIONS;

INORGANIC POLYMERS;

EID: 57949092591     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie8006825     Document Type: Article

References (44)

1. Davidovits, J. Inorganic Polymer. French Patent 8117545, 1981.
2. Duxson, P.; Fernández-Jiménez, A.; Provis, J. L.; Lukey, G. C.; Palomo, A.; van Deventer, J. S. J. Geopolymer Technology: The Current Slate of the Art. J. Mater. Sci. 2007, 42, 2917.
3. Provis, J. L.; van Deventer, J. S. J. Geopolymerisation Kinetics. 2. Reaction Kinetic Modelling. Chem Eng. Sci. 2007, 62, 2318.
4. Lee, W. K. W.; van Deventer, J. S. J. Structural Reorganisation of Class F Fly Ash in Alkaline Silicate Solutions. Colloids Surf., A 2002, 211, 49.
5. Palomo, A.; Grutzeck, M. W.; Blanco, M. T. Alkali-Activated Fly Ashes: A Cement for the Future. Cem. Concr. Res. 1999, 29, 1323.
6. Fernández-Jiménez, A.; Palomo, A. Characterisation of Fly Ashes. Potential Reactivity as Alkaline Cements. Fuel 2003, 82, 2259.
7. Xu, H.; van Deventer, J. S. J. The Geopolymerisation of Alumino-Silicate Minerals. Int. J. Miner. Proc. 2000, 59, 247.
8. Lee, W. K. W.; van Deventer, J. S. J. Use of Infrared Spectroscopy to Study Geopolymerization of Heterogeneous Amorphous Aluminosilicates. Langmuir 2003, 19, 8726.
9. Duxson, P.; Provis, J. L.; Lukey, G. C.; Mallicoat, S. W.; Kriven, W. M.; van Deventer, J. S. J. Understanding the Relationship Between Geopolymer Composition, Microstructure and Mechanical Properties. Colloids Surf., A 2005, 269, 47.
10. Duxson, P.; Mallicoat, S. W.; Lukey, G. C.; Kriven, W. M.; van Deventer, J. S. J. The Effect of Alkali and Si/Al Ratio on the Development of Mechanical Properties of Metakaolin-Based Geopolymers. Colloids Surf., A 2007, 292, 8.
11. Rees, C. A. Mechanisms and Kinetics of Gel Formation in Geopolymers. Ph.D. Thesis, University of Melbourne, 2007.
12. Rees, C. A.; Lukey, G. C.; van Deventer, J. S. J. Characteristics of Geopolymers Derived from Flyash and Solid-Silicate Wastes. Presented at 32nd Australasian Chemical Engineering Conference, CHEMECA 2004; Sustainable Processes; Sydney, 2004.
13. Yang, K. H.; Song, J. K.; Ashour, A. F.; Lee, E. T. Properties of Cementless Mortars Activated by Sodium Silicate. Constr. Build. Mater. 2008, 22, 1981.
14. Koloušek, D.; Brus, J.; Urbanova, M.; Andertova, J.; Hulinsky, V.; Vorel, J. Preparation, Structure and Hydrothermal Stability of Alternative (Sodium Silicate-Free) Geopolymers. J. Mater. Sci. 2007, 42, 9267.
15. Brew, D. R. M.; MacKenzie, K. J. D. Geopolymer Synthesis Using Silica Fume and Sodium Aluminate. J. Mater. Sci. 2007, 42, 3990.
16. Diaz, C.; Valle-Fuentes, F. J. Use of Silicon Residue in Ceramics and Glass. Am Ceram Soc. Bull. 1999, 78, 112.
17. Rincon, J. M. Thermal Behaviour of Silica Waste from a Geothermal Power Station and Derived Silica Ceramics. J. Therm. Anal. Calorim. 1999, 56, 1261.
18. Sims, J. R.; Bingham, F. T. Retention of Boron by Layer Silicates, Sesquioxides, and Soil Materials: II. Soil Sci. Soc. Am. 1968, 32, 364.
19. Álvarez-Ayuso, E.; Querol, X. Stabilization of FGD Gypsum for its Disposal in Landfills Using Amorphous Aluminium Oxide as a Fluoride Retention Additive. Chemosphere 2007, 69, 295.
20. Provis, J. L.; Lukey, G. C.; van Deventer, J. S. J. Do Geopolymers Actually Contain Nanocrystalline Zeolites? A Re-Examination of Existing Results. Chem. Mater. 2005, 17, 3075.
21. Jacobs, P. A.; Derouane, E. G.; Weitkamp, J. Evidence for X-ray-Amorphous Zeolites. J. Chem. Soc., Chem. Commun. 1981, 591.
22. Osswald, J.; Fehr, K. T. FTIR Spectroscopic Study on Liquid Silica Solutions and Nanoscale Particle Size Determination. J. Mater. Sci. 2006, 41, 1335.
23. Bell, R. J.; Dean, P. Atomic Vibrations in Vitreous Silica. Discuss. Faraday Soc. 1970, 50, 55.
24. Moolenaar, R. J.; Evans, J. C.; McKeever, L. D. The Structure of the Aluminate Ion in Solutions at High pH. J. Phys. Chem. 1970, 74, 3629.
25. Handke, M.; Mozgawa, W. Vibrational Spectroscopy of the Amorphous Silicates. Vibr. Spectr. 1993, 5, 75.
26. Fernández-Jiménez, A.; Palomo, A.; Sobrados, I.; Sanz, J. The Role Played by the Reactive Alumina Content in the Alkaline Activation of Fly Ashes. Microporous Mesoporous Mater. 2006, 91, 111.
27. Rees, C. A.; Provis, J. L.; Lukey, G C.; van Deventer, J. S. J. Attenuated Total Reflectance Fourier Transform Infrared Analysis of Fly Ash Geopolymer Gel Aging. Langmuir 2007, 23, 8170.
28. Rees, C. A.; Provis, J. L.; Lukey, G C.; van Deventer, J. S. J. In Situ ATR-FTIR Study of the Early Stages of Fly Ash Geopolymer Gel Formation. Langmuir 2007, 23, 9076.
29. Sweet, J. R.; White, W. B. Study of Sodium Silicate Glasses and Liquids by Infrared Reflectance Spectroscopy. Phys. Chem. Glasses 1969, 10, 246.
30. Roy, B. N. Infrared Spectroscopy of Lead and Alkaline-Earth Aluminosilicate Glasses. J. Am. Ceram. Soc. 1990, 73, 846.
31. Fernández-Jiménez, A.; de la Torre, A. G.; Palomo, A.; López-Olmo, G.; Alonso, M. M.; Aranda, M. A. G. Quantitative Determination of Phases in the Alkali Activation of Fly Ash. Part I. Potential Ash Reactivity. Fuel 2006, 85, 625.
32. Fernández-Jiménez, A.; de la Torre, A. G.; Palomo, A.; López-Olmo, G.; Alonso, M. M.; Aranda, M. A. G. Quantitative Determination of Phases in the Alkali Activation of Fly Ash. Part II: Degree of reaction. Fuel 2006, 85, 1960.
33. 2. Cem. Concr. Res. 2007, 37, 512.
34. Fernández-Jiménez, A.; Palomo, A.; Sobrados, I.; Sanz, J. The Role Played by the Reactive Alumina Content in the Alkaline Activation of Fly Ashes. Microporous Mesoporous Mater. 2006, 91, 111.
35. Swaddle, T. W. Silicate Complexes of Aluminum(III) in Aqueous Systems. Coord. Chem. Rev. 2001, 219-221, 665.
36. Weng, L.; Sagoe-Crentsil, K.; Brown, T. Speciation and Hydrolysis Kinetics of Aluminates in Inorganic Polymer Systems. Proceedings of the Geopolymer 2002 International Conference, Melbourne, Australia; Siloxo Pty. Ltd.: Melbourne, Australia, 2002 (CD-ROM Proceedings).
37. Anseau, M. R.; Leung, J. P.; Sahai, N.; Swaddle, T. W. Interactions of Silicate Ions with Zinc (II) and Aluminium (III) in Alkali Aqueous Solution. Inorg. Chem. 2005, 44, 8023.
38. North, M. R.; Swaddle, T. W. Kinetics of Silicate Exchange in Alkaline Aluminosilicate Solutions. Inorg. Chem. 2000, 39, 2661.
39. Abraitis, P. K.; McGrail, B. P.; Trivedi, D. P. The Effects of Silicic Acid, Aluminate Ion Activity and Hydrosilicate Gel Development on the Dissolution Rate of a Simulated British Magnox Waste Glass. Mater. Res. Soc. Symp. Proc. 1999, 556, 401.
40. Iler, R. K. Effect of Adsorbed Alumina on the Solubility of Amorphous Silica in Water. J. Colloid Interface Sci. 1973, 43, 399.
41. Rees, C. A.; Provis, J. L.; Lukey, G. C.; van Deventer, J. S. J. The Mechanism of Geopolymer Gel Formation Investigated Through Seeded Nucleation. Colloids Surf., A 2008, 318, 97.
42. Chindaprasirt, P.; Jaturapitakkul, C.; Sinsiri, T. Effect of Fly Ash Fineness on Compressive Strength and Pore Size of Blended Cement Paste. Cem. Concr. Compos. 2005, 27, 425.
43. Chindaprasirt, P.; Homwuttiwong, S.; Sirivivatnanon, V. Influence of Fly Ash Fineness on Strength, Drying Shrinkage and Sulfate Resistance of Blended Cement Mortar. Cem. Concr. Res. 2004, 34, 1087.
44. Chindaprasirt, P.; Rukzon, S.; Sirivivatnanon, V. Resistance to Chloride Penetration of Blended Portland Cement Mortar Containing Palm Oil Fuel Ash, Rice Husk Ash and Fly Ash. Constr. Build. Mater. 2008, 22, 932.