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Volumn , Issue 2, 2009, Pages 318-321

Two-electron oxidation of N,N,N′,N′-tetramethylphenylenediamine with a chromium(v) salen complex

Author keywords

[No Author keywords available]

Indexed keywords

CHROMIUM; OXIDATION; RATE CONSTANTS; VANADIUM COMPOUNDS;

EID: 57849110864     PISSN: 14779226     EISSN: 14779234     Source Type: Journal    
DOI: 10.1039/b811140e     Document Type: Article
Times cited : (6)

References (29)
  • 27
    • 0007287020 scopus 로고
    • The observed difference in the comproportionation kinetics may signal the presence of more than one oxidation products in solutions generated with Ce(iv). The need to use an excess of Ce(iv) to oxidize most of the TMPD until only traces of the blue radical cation remained (to ensure that all of the Ce(iv) was consumed) shows that some overoxidation does take place under such conditions. Attempts to use Ce(iv) directly in the stopped-flow instrument to improve the mixing were abandoned for fear that the observed reaction may have contributions from the direct Ce(iv)-TMPD reaction -448
    • S. Hunig P. Richters Chem. Ber. 1958 91 442 448
    • (1958) Chem. Ber. , vol.91 , pp. 442
    • Hunig, S.1    Richters, P.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.