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57849159490
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For other examples of ligand exchange at a Pt-acetylide center, see refs 3a and 7a.
-
For other examples of ligand exchange at a Pt-acetylide center, see refs 3a and 7a.
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-
-
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41
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57849105604
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See Supporting Information for details
-
See Supporting Information for details.
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42
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10444239452
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43
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57849139868
-
-
c-Pt = 1105 Hz. See Supporting Information (Figures S45-47).
-
c-Pt = 1105 Hz. See Supporting Information (Figures S45-47).
-
-
-
-
44
-
-
57849138590
-
-
C-P = 3.0 and 2.7 Hz (cis).
-
C-P = 3.0 and 2.7 Hz (cis).
-
-
-
-
45
-
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57849140741
-
-
For a discussion of the significance of P-Pt-P bite angles, see for example: (a) Freixa, Z.; van Leeuwen, P. W. N. M. Dalton Trans. 2003, 1890-1901.
-
For a discussion of the significance of P-Pt-P bite angles, see for example: (a) Freixa, Z.; van Leeuwen, P. W. N. M. Dalton Trans. 2003, 1890-1901.
-
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46
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0034249672
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48
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57849124247
-
-
The UV-vis spectra were recorded for pure ligands 2b-f, and all show a high-energy absorption between 254 and 263 nm corresponding to the π-π* transition for the phenyl chromophores with < 16 000 M -1 cm-1. These absorptions are also present in all of the cis-Pt-acetylide complexes that contain these ligands. The circular dichroism (CD) spectral analysis of the pure ligands R-PROPHOS (2c) and S, S-BDPP (2d) show weak signals at 228 and 243 nm, respectively, while the CD spectra of S,S-CHIRAPHOS (2b, R,R-Me-DUPHOS (2e, and R,R-NORPHOS (2f) contain stronger signals at 229, 317, and 233 nm, respectively. The CD spectra of all five ligands show at least one cross-over point in the range 236-275 nm. In all cases the absolute signal intensity of the pure ligand is Δε < 10 M-1 cm-1 for absorptions ≥225 nm; see Supporting Information for spe
-
-1 for absorptions ≥225 nm; see Supporting Information for spectra (Figures S1 and S2).
-
-
-
-
49
-
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57849160370
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For discussion of MLCT in Pt-acetylides, see: (a)Ref 2e. (b) Saha, R.; Qaium, M. A.; Debnath, D.; Younus, M.; Chawdhury, N.; Sultana, N.; Kociok-Köhn, G.; Ooi, L.-L.; Raithby, P. R.; Kijima, M. Dalton Trans. 2005, 2760, 2765.
-
For discussion of MLCT in Pt-acetylides, see: (a)Ref 2e. (b) Saha, R.; Qaium, M. A.; Debnath, D.; Younus, M.; Chawdhury, N.; Sultana, N.; Kociok-Köhn, G.; Ooi, L.-L.; Raithby, P. R.; Kijima, M. Dalton Trans. 2005, 2760, 2765.
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0002234956
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57849127321
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For a detailed description of the procedure used for the UV-vis and CD spectroscopic studies, see the Supporting Information
-
For a detailed description of the procedure used for the UV-vis and CD spectroscopic studies, see the Supporting Information.
-
-
-
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