Synthesis and crystal structure of the singly tucked-in derivative of bis(phenyltetramethylcyclopentadienyl)titanium

Inorganic Chemistry Communications

Volumn 12, Issue 1, 2009, Pages 11-14

  Pinkas, Jiří ^a   Císařová, Ivana ^b   Conde, Ana ^c   Fandos, Rosa ^c   Horáček, Michal ^a   Kubišta, Jiří ^a   Mach, Karel ^a  

^a J HEYROVSKÝ INSTITUTE OF PHYSICAL CHEMISTRY   (Czech Republic)

^b CHARLES UNIVERSITY   (Czech Republic)

^c UNIVERSITY OF CASTILLA LA MANCHA   (Spain)

Author keywords

EPR spectra; NMR spectra; Phenyltetramethylcyclopentadienyl ligand; Thermolysis; Titanium; Titanocene; Tucked in; X ray crystallography

Indexed keywords

EID: 57849099632     PISSN: 13877003     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.inoche.2008.10.022     Document Type: Article

References (27)

1. Bercaw J.E., and Brintzinger H.H. J. Am. Chem. Soc. 93 (1971) 2045
2. Bercaw J.E., Marvich R.H., Bell L.G., and Brintzinger H.H. J. Am. Chem. Soc. 94 (1972) 1219
3. Bercaw J.E. J. Am. Chem. Soc. 96 (1974) 5087
4. Pattiasina J.W., Hissink C.E., de Boer J.L., Meetsma A., Teuben J.H., and Spek A.L. J. Am. Chem. Soc. 107 (1985) 7758
5. Luinstra G.A., ten Cate L.C., Heeres H.J., Pattiasina J.W., Meetsma A., and Teuben J.H. Organometallics 10 (1991) 3227
6. Luinstra G.A., and Teuben J.H. J. Am. Chem. Soc. 114 (1992) 3361
7. Mach K., Varga V., Hanuš V., and Sedmera P. J. Organomet. Chem. 415 (1991) 87
8. Vondrák T., Mach K., Varga V., and Terpstra A. J. Organomet. Chem. 425 (1992) 27
9. R. Gyepes, Unpublished results.
10. Fischer J.M., Piers W.E., and Young Jr. V.G. Organometallics 15 (1996) 2410
11. de Wolf J.M., Blaauw R., Meetsma A., Teuben J.H., Gyepes R., Varga V., Mach K., Veldman N., and Spek A.L. Organometallics 15 (1996) 4977
12. Pinkas J., Lukešová L., Gyepes R., Císařová I., Lönnecke P., Kubišta J., Horáček M., and Mach K. Organometallics 26 (2007) 3100
13. -1): 3083 (w), 3058 (w), 3037 (w), 3012 (w), 2981 (m), 2950 (s), 2917 (vs), 2891 (s), 2854 (m), 2724 (vw), 1599 (s), 1574 (w), 1506 (s), 1481 (m), 1445 (s), 1437 (s), 1395 (w), 1377 (m), 1153 (vw), 1076 (w), 1023 (m), 1003 (w), 983 (w), 916 (w), 843 (vw), 794 (s), 760 (vs), 704 (vs), 638 (w), 618 (vw), 590 (w), 528 (vw), 502 (vw), 466 (w), 454 (w), 406 (s). UV-Vis (hexane, nm): 440 (sh).
14. Horáček M., Polášek M., Kupfer V., Thewalt U., and Mach K. Collect. Czech. Chem. Commun. 64 (1999) 61
15. Schmid G., Thewalt U., Sedmera P., Hanuš V., and Mach K. Collect. Czech. Chem. Commun. 63 (1998) 636
16. McDade C., Green J.C., and Bercaw J.E. Organometallics 1 (1982) 1629
17. Kupfer V., Thewalt U., Tišlerová I., Štěpnička P., Gyepes R., Kubišta J., Horáček M., and Mach K. J. Organomet. Chem. 620 (2001) 39
18. C: 1.14, 1.92 ppm/73.9 ppm [10]). EPR (toluene): negligible signals. UV-Vis (toluene, nm): 610.
19. 33Ti: C, 81.62; H, 7.53. Found: C, 81.58; H, 7.50.
20. 2 (SHELXL-97 [20]). All non-hydrogen atoms were refined anisotropically. Hydrogen atoms were fixed and refined in their theoretical positions.
21. Lukens Jr. W.W., Smith III M.R., and Andersen R.A. J. Am. Chem. Soc. 118 (1996) 1719
22. Pinkas J., Císařová I., Gyepes R., Horáček M., Kubišta J., Čejka J., Gómez-Ruiz S., Hey-Hawkins E., and Mach K. Organometallics 27 (2008) 5532
23. Westcott S.A., Kakkar A.K., Stringer G., Taylor N.J., and Marder T.B. J. Organomet. Chem. 394 (1990) 777
24. Z. Otwinowski, W. Minor, HKL Denzo and Scalepack Program Package by Nonius. For a reference see Z. Otwinowski, W. Minor, Methods Enzymol. 276 (1997) 307.
25. Altomare A., Burla M.C., Camalli M., Cascarano G., Giacovazzo C., Guagliardi A., and Polidori G. J. Appl. Crystallogr. 27 (1994) 435
26. Sheldrick G.M. SHELXL97 Program for Crystal Structure Refinement from Diffraction Data (1997), University of Göttingen, Göttingen
27. Langmaier J., Samec Z., Varga V., Horáček M., and Mach K. J. Organomet. Chem. 579 (1999) 348