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Volumn 130, Issue 49, 2008, Pages 16460-16461

Oxidation-resistant fluorogenic probe for mercury based on alkyne oxymercuration

Author keywords

[No Author keywords available]

Indexed keywords

ALKYNE; CYSTEINE; DENTAL ALLOY; MERCURY;

EID: 57549087917     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja805678r     Document Type: Article
Times cited : (212)

References (20)
  • 5
    • 57549094524 scopus 로고    scopus 로고
    • Method 1631: Measurement of Mercury in Water; U.S. Environmental Protection Agency: Washington, D.C., 2002.
    • Method 1631: Measurement of Mercury in Water; U.S. Environmental Protection Agency: Washington, D.C., 2002.
  • 11
    • 38849171163 scopus 로고    scopus 로고
    • See Supporting Information. For the absorbance and fluorescence spectra of 4, see: Koide, K.; Song, F.; de Groh, E. D.; Garner, A. L.; Mitchell, V. D.; Davidson, L. A.; Hukriede, N. A. ChemBioChem 2008, 9, 214.
    • See Supporting Information. For the absorbance and fluorescence spectra of 4, see: Koide, K.; Song, F.; de Groh, E. D.; Garner, A. L.; Mitchell, V. D.; Davidson, L. A.; Hukriede, N. A. ChemBioChem 2008, 9, 214.
  • 12
    • 57549090688 scopus 로고    scopus 로고
    • We also observed a byproduct that appears to be an alkylmercury species. Because of safety concerns about this unknown but potentially extremely toxic compound, we decided against further characterization
    • We also observed a byproduct that appears to be an alkylmercury species. Because of safety concerns about this unknown but potentially extremely toxic compound, we decided against further characterization.
  • 14
    • 57549100102 scopus 로고    scopus 로고
    • Although the protocol described by the EPA calls for Cl-Br, we find NCS to be easier to handle because of its stability and nonvolatile nature. See Figure S7 for details
    • Although the protocol described by the EPA calls for Cl-Br, we find NCS to be easier to handle because of its stability and nonvolatile nature. See Figure S7 for details.
  • 18
    • 57549093364 scopus 로고    scopus 로고
    • A calibration of the fluorescence intensity with respect to mercury concentrations in fish is necessary; however, this result provides a proof of principle that 2 can be used against fish samples under oxidative conditions
    • A calibration of the fluorescence intensity with respect to mercury concentrations in fish is necessary; however, this result provides a proof of principle that 2 can be used against fish samples under oxidative conditions.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.