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Volumn 112, Issue 47, 2008, Pages 14692-14697

Structural ordering and phase behavior of charged microgels

Author keywords

[No Author keywords available]

Indexed keywords

AMIDES; CARBOXYLIC ACIDS; CRYSTALLINE MATERIALS; DYNAMIC LIGHT SCATTERING; EXPERIMENTS; FORECASTING; IONIZATION OF LIQUIDS; LIGHT SCATTERING; MOLECULAR INTERACTIONS; MONOMERS; ORGANIC ACIDS; PHASE BEHAVIOR; PHASE DIAGRAMS; REFRACTION; SCATTERING; TITRATION;

EID: 57449120922     PISSN: 15206106     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp808203d     Document Type: Article
Times cited : (93)

References (41)
  • 21
    • 4243973802 scopus 로고    scopus 로고
    • Wu, J.; Zhou, B.; Hu, Zu. Phys. Rev. Lett. 2003, 90, 0483041.
    • Wu, J.; Zhou, B.; Hu, Zu. Phys. Rev. Lett. 2003, 90, 0483041.
  • 33
    • 84906393766 scopus 로고    scopus 로고
    • St. John, Ashlee N.; Breedveld, Victor; Lyon, L. Andrew J. Phys. Chem. B 2007, 111, 7796.
    • St. John, Ashlee N.; Breedveld, Victor; Lyon, L. Andrew J. Phys. Chem. B 2007, 111, 7796.
  • 34
    • 84906393767 scopus 로고    scopus 로고
    • NIPAm (1.4 g) and 0.03 g of cross-linker (BIS) were dissolved in 100 mL of water. The mixture was transferred into a 250 mL round-bottom flask and was heated at 70°C under a gentle nitrogen stream for 45 min. AAc (0.08 g in 10gm of water) was added to the above mixtures. Finally, the initiator, potassium perox-disulfate (KPS) (0.05 g dissolved in 10 g of water) was added to initiate the polymerization. The reaction mixture was kept at 70°C under nitrogen at least for 6 h to complete the reaction. Finally, the suspensions were purified by dialysed followed by centrifugation under high rate to remove the unreacted monomers, linear chains and ionic impurities.
    • NIPAm (1.4 g) and 0.03 g of cross-linker (BIS) were dissolved in 100 mL of water. The mixture was transferred into a 250 mL round-bottom flask and was heated at 70°C under a gentle nitrogen stream for 45 min. AAc (0.08 g in 10gm of water) was added to the above mixtures. Finally, the initiator, potassium perox-disulfate (KPS) (0.05 g dissolved in 10 g of water) was added to initiate the polymerization. The reaction mixture was kept at 70°C under nitrogen at least for 6 h to complete the reaction. Finally, the suspensions were purified by dialysed followed by centrifugation under high rate to remove the unreacted monomers, linear chains and ionic impurities.
  • 38
    • 84906379860 scopus 로고    scopus 로고
    • h,45 is the hydrodynamic radius at 45°C at pH = 3.2. It was taken into account that in the collapsed state, the microgel particle contains 50% water.
    • h,45 is the hydrodynamic radius at 45°C at pH = 3.2. It was taken into account that in the collapsed state, the microgel particle contains 50% water.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.