Interfacial properties of poly(N-vinyl-2pyrrolidone) at the air/water interface

Journal of Macromolecular Science - Physics

Volumn 43 B, Issue 5, 2004, Pages 913-924

  Gargallo L ^a   Leiva, A ^a   Alegria L ^a   Miranda, B ^a   Gonzalez A ^a   Radie, D ^a  

^a PONTIFICIA UNIVERSIDAD CATÓLICA DE CHILE   (Chile)

Author keywords

Adsorption layers; Air water interface; Poly(N vinyl 2 pyrrolidone); Spread films; Surface excess layer

Indexed keywords

ADSORPTION; GIBBS FREE ENERGY; GRAFT COPOLYMERS; HYDRODYNAMICS; INTERFACES (MATERIALS); LIGHT SCATTERING; MONOLAYERS; THERMODYNAMIC PROPERTIES;

ADSORPTION LAYERS; AIR/WATER INTERFACES; SPREAD FILMS; SURFACE EXCESS LAYERS;

VINYL RESINS;

EID: 5744235059     PISSN: 00222348     EISSN: None     Source Type: Journal    
DOI: 10.1081/MB-200033255     Document Type: Article

References (32)

1. Ho, P.S. Chemistry and adhesion of metal-polymer interfaces. Appl. Surf. Sci. 1989, 41-42, 559-556.
2. Fleer, G.J.; Scheutjcus, J.M.H.M.; Cohen-Stuart, MA; Cosgrove, T.; Vincent, B. Polymers at Interfaces; Chapman and Hall: London, 1993; 502.
3. Patel, S.S.; Tirrel, M. Measurement of forces between surface in polymer fluids. Annu. Rev. Phys. Chem. 1989, 40, 597-635.
4. Asnacios, A.; Langevin, D.; Argillier, F.J. Complexation of cationic surfactant and anionic polymer at the air-water interface. Macromolecules 1996, 29 (23), 7412-7417.
5. Sadrzadeh, N.; Yu, O.; Zografi, G. Surface phase behavior of poly(terf-butyl methacrylate)-fatty acid glyceride binary mixtures at the air-water interface. Langmuir 1988, 14 (1), 151-156.
6. Gargallo, L.; Radic, D. Poly(Af-vinyl-2-pyrrolidone) interactions. In Polymeric Materials Encyclopedia; Salamone, J.C., Eds.; CRC Press; 1996.
7. Molyneux, P.J. Water Solube Synthetic Polymers: Properties and Behavior, 5th Ed.; 1980; Vol. 1, Chapters 1 and 4 and Vol. II, Chapter 2.
8. Gargallo, L.; Radic, D. Interaction of poly(vinylpyrrolidone) with small cosolutes in aqueous and nonaqueous media. Polymer 1983, 24 (1), 91-94.
9. Molyneux, P.; Cornarakis-Lentzos, M. The interaction of poly(vinylpyrrolidone) with aromatic compounds in aqueous solutions. Part IV. Evaluation of the cooperativity parameter, and the methylene-group contribution to the binding strength, for the alkyl parahydroxybenzoates. Colloid Polym. Sci. 1979, 257 (8), 855-873.
10. Inoue, M.; Otsu, T. Interaction .of several polymers with p-substituted phenols in aqueous solution. J. Polym. Sci. Poly. Chem. Ed. 1976, 14 (8), 1939-1944.
11. Bandyapaadhyay, P.; Rodriguez, P. Interaction of poly(vinylpyrrolfidone) with phenolic cosolutes. Polymer 1972, 13 (3), 119-123.
12. Gargallo, L.; Radic, D. Polymer consolvent system. V. Influence of the binary solvent on the preferential adsorption behavior of poly(vinylpyrrolidone). Polym. Commun. 1985, 26 (5), 149-152.
13. Gargallo, L.; Pérez-Cotapos, J.; Santos, J.; Radic, D. Poly(N-vinyl-2-pyrrolidone)monoalkyl xanthates. L. Adsorption and chemical reaction. Langmuir 1993, 9 (3), 681-684.
14. Zatz, J.L. Comparison of adsorbed films of a polyvinylpyrrolidone copolymer with spread monolayers. J. Pharm. Sci. 1978, 67 (10), 1464-1466.
15. Glass, J.E. Adsorption characteristics of water-soluble polymers. II. Poly(ethylene oxide) at the aqueous-air interface. J. Phys. Chem. 1968, 72 (13), 4459-4467.
16. Henderson, J.A.; Richards, R.K. Neutron reflectometry using the kinematic approximation and surface quasi-elastic light scattering from spread films of poly(methylmethacrylate). Macromolecules 1993, 26 (1), 65-75.
17. Henderson, J.A.; Richards, R.W.; Penfold, J.; Thomas, R.K.; Lu, J.R. Organization of poly(ethylene oxide) monolayers at the air-water interface. Macromolecules 1993, 26 (17), 4591-4600.
18. Henderson, J.A.; Richards, R.W.; Penfold, J.; Thomas, R.K. Partial structure factor analysis of neutron reflectometry from spread monolayers of isotactic poly (methylmethacrylate). Acta Polym. 1993, 44 (4), 184-191.
19. Meza, R.; Gargallo, L. Upperturbed dimensions of polyvinylpyrrolidone in pure solvents and in binary mixtures. Eur. Polym. J. 1977, 3 (3), 235-239.
20. Heskins, M.; Guillet, J.E. Solution properties of poly(N-isopropylacrylamide). J. Macromol. Sci. Chem. 1968, 2 (8), 1441-1455.
21. Sauer, B.B.; Kawaguchi, M.; Yu, H. A surface light scattering study of poly(ethylene oxide) and poly(vinyl acetate) at the air/water and heptane/water interface. Macromolecules 1987, 20 (11), 2732-2739.
22. Richards, R.W.; Taylor, M.R. Long-wavelength dynamics of spread films of poly (methyl methacrylate) and poly(ethylene oxide) at the air-water interface. J. Chem. Soc. Faraday Trans. II 1996, 92 (4), 601-610.
23. Kawaguchi, M.; Sauer, B.B.; Yu, I.L. Polymeric monolayers dynamic at the air/water interface by surface light scattering. Macromolecules 1989, 22 (4), 601-610.
24. Assarsson, P.O. Polytechnic Institute of Brooklyn 1966. 1967; Dissertation Abstr., Vol. 28B641, Ph.D. Thesis.
25. Goldfarb, J.; Rodrigues, S. Aqueous solutions of poly(vinylpyrrolidone). Makromol. Chem. 1968, 116, 96-106.
26. Glass, J.L. Adsorption characteristics of water-soluble polymers. I. Poly(vinyl alcohol) and poly(vinyl pirrolidone) at the aqueous-air interface. J. Phys. Chem. 1968, 72 (13), 4450-4458.
27. Okubo, T. Surface tension of synthetic polyelectrolyle solutions at the air-water interface. J. Colloid Interface Sci. 1988, 725 (2), 386-398.
28. Lankveld, J.M.G.; Lykloma, J. Adsorption of poly(vinyl alcohol) on the paraffinwater interface. I. Interfacial tension as a function of time and concentration. J. Colloid Interface Sci. 1972, 41 (3), 454-465.
29. Szyszkowski, B. Experimental studies of the capillary properties of aqueous solutions of fatty acids. Z. Physik. Chem. 1909, 64, 385-414.
30. Langmuir, I. Constitution and fundamental properties of solids and liquids. II. Liquids. J. Am. Chem. Soc. 1917, 39, 1848-1906.
31. Rosen, M.J. Surfactants and Interfacial Phenomena, 2nd Ed.; Wiley-Interscience: New York, 1989.
32. Spitzer, J.J. Adsorption of sodium cyclododecylmethanoate and cycloundecylmethanoate at the air/water interface. Can. J. Chem. 1984, 62 (11), 2359-2363.