A facile synthesis of C-24 and C-25 oxysterols by in situ generated ethyl(trifluoromethyl)dioxirane

Steroids

Volumn 74, Issue 1, 2009, Pages 81-87

  Ogawa, Shoujiro ^a   Kakiyama, Genta ^a   Muto, Akina ^a   Hosoda, Atsuko ^a   Mitamura, Kuniko ^b   Ikegawa, Shigeo ^b   Hofmann, Alan F ^c   Iida, Takashi ^a  

^a NIHON UNIVERSITY   (Japan)

^b KINKI UNIVERSITY   (Japan)

^c UNIVERSITY OF CALIFORNIA SAN DIEGO   (United States)

Author keywords

24 Oxocholesterol; 25 Hydroxycholesterol 3 sulfate; Ethyl(trifluoromethyl)dioxirane; Hydroxylation; Remote oxyfunctionalization

Indexed keywords

24 OXOCHOLEST 5 EN 3BETA OL; 24 OXOCHOLESTEROL; 24XI HYDROXYCHOLEST 5 EN 3BETA YL ACETATE; 25 HYDROXYCHOLESTEROL; 3BETA SULFOOXY 25 HYDROXYCHOLEST 5 ENE; 3BETA,25 DIHYDROXYCHOLEST 5 ENE; 5ALPHA CHOLESTAN 3 BETA YL ACETATE; 5ALPHA,6BETA DIBROMO 25 HYDROXYCHOLESTAN 3 BETA YL ACETATE; 5ALPHA,6BETA DIBROMOCHOLEST 24 EN 3BETA YL ACETATE; 5ALPHA,6BETA DIBROMOCHOLESTAN 3 BETA YL ACETATE; ACETIC ACID; CHOLESTEROL; DIMETHYLDIOXIRANE; ETHYL(TRIFLUOROMETHYL)DIOXIRANE; ETHYLENE OXIDE DERIVATIVE; HEXAFLUORO(DIMETHYL)DIOXIRANE; KETONE; METHYL(TRIFLUOROMETHYL)DIOXIRANE; OXYSTEROL; SULFATE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL BOND; CHEMICAL STRUCTURE; CONTROLLED STUDY; FLUORINATION; HYDROXYLATION; OXIDATION; STEROL SYNTHESIS;

CHOLESTEROL ESTERS; ETHYLENE OXIDE; HYDROCARBONS, FLUORINATED; HYDROXYCHOLESTEROLS; KETOCHOLESTEROLS;

EID: 57249113718     PISSN: 0039128X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.steroids.2008.09.015     Document Type: Article

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