Study on curing kinetics and thermal degradation kinetics of hyperbranched Poly(Trimellitic Anhydride Ethylene Glycol) Epoxy (HTME)/Diglycidyl ether of bisphenol-a epoxy hybrid resin

Polymer - Plastics Technology and Engineering

Volumn 47, Issue 12, 2008, Pages 1220-1226

  Zhang, Daohong ^a,b   Jia, Demin ^b  

^a SOUTH CENTRAL UNIVERSITY FOR NATIONALITIES   (China)

^b SOUTH CHINA UNIVERSITY OF TECHNOLOGY   (China)

Author keywords

Curing; Hyperbranched epoxy resin; Kinetics; Thermal degradation

Indexed keywords

ACTIVATION ENERGY; DEGRADATION; DENDRIMERS; DIFFERENTIAL SCANNING CALORIMETRY; EPOXY RESINS; ETHERS; ETHYLENE; ETHYLENE GLYCOL; FUNCTIONAL POLYMERS; GLYCOLS; GRAVIMETRIC ANALYSIS; LASER INTERFEROMETRY; MOLECULAR WEIGHT; ORGANIC COMPOUNDS; PHENOLS; POLYMER BLENDS; RESINS; THERMOGRAVIMETRIC ANALYSIS; THERMOSETS;

BISPHENOL; CURING KINETICS; CURING REACTIONS; CURING TIMES; DIGLYCIDYL ETHER OF BISPHENOL-A; FUNCTIONAL ADDITIVES; HYPERBRANCHED EPOXY RESIN; HYPERBRANCHED POLIES; LOW VISCOSITIES; REACTION ORDERS; THERMAL DEGRADATION; THERMAL DEGRADATION KINETICS; THERMOSETTING RESINS;

CURING;

CURING (FINISHING); DEGRADATION; EPOXY RESIN; KINETICS; THERMOSETTING POLYMER; TOUGHNESS;

EID: 57249105372     PISSN: 03602559     EISSN: 15256111     Source Type: Journal    
DOI: 10.1080/03602550802497149     Document Type: Article

References (26)

1. Ellis, B. (1993) Chemistry and Technology of Epoxy Resins, Blackie Academic Professional, Glasgow, UK
2. Peter, B., Nandika, A. D. and Teresa, D. G. (2001) Epoxy + montmorillonite nanocomposite: Effect of composition on reaction kinetics. Polym. Eng. Sci., 41, p. 1794.
3. Xu, W., He, P. and Chen, D. (2003) Cure behavior of epoxy resin/ montmorillonite/imidazole nanocomposite by dynamic torsional vibration method. Euro. Polym. J., 39, p. 617.
4. Gonis, J., Simon, G. P. and Cook, W. D. (1999) Cure properties of epoxies with varying chain length as studied by DSC. J. Appl. Polym. Sci., 72, p. 1479.
5. Jens, R., Graeme, A. G. and Friedrich, V. (2003) Curing kinetics and thermomechanical behavior of co-anhydride cured aminoglycidyl epoxy resins. Polym. Int., 52, p. 1758.
6. Lin, S. and Huang, S. K. (1996) Study of curing kinetics of siloxane-modified DGEBA epoxy resins. J. Appl. Polym. Sci., 62, p. 1641.
7. Lin, J. F., Ho, C. F. and Huang, S. K. (2000) Studies on curing kinetics and total thermal degradation of the modified epoxy copolymer with penta-coordinated phosphate as a tribranched junction. J. Appl. Polym. Sci., 77, p. 719.
8. Bouer, R. S. (1979) Epoxy Resin Chemistry, American Chemical Society, Washington, DC
9. Hsiue, G. H., Liu, Y. L. and Liao, H. H. (2001) Synthesis and properties of a novel, liquid, trifunctional, cycloaliphatic epoxide. J. Polym. Sci. Part A: Polym.Chem., 39, p. 2799.
10. Park, S. J., Seo, M. K., Lee, J. R. and Lee, D. R. (2001) Studies on epoxy resins cured by cationic latent thermal catalysts: The effect of the catalysts on the thermal, rheological, and mechanical properties. J. Polym. Sci. Part A: Polym. Chem., 39, p. 187.
11. Boogh, L., Pettersson, B. and Jan-Anders, E. (1999) Dentritic hyperbranched polymers as tougheners for epoxy resins. Polymer, 40, p. 2249.
12. Malmstrom, E., Johansson, M. and Hult, A. (1996) The effect of terminal alkyl chains on hyperbranched polyesters based on 2,2-bis(hydroxymethyl)propionic acid. Macromol. Chem. Phys., 197, p. 3199.
13. Ratna, D., Varley, R. J., Raman, R. K. S. and Simon, G. P. (2003) Studies on blends of epoxy-functionalized hyperbranched polymer and epoxy resin. J. Mater. Sci., 38, p. 147.
14. Ratna, D., Varley, R. J. and Simon, G. P. (2004) Processing and chemorheology of epoxy resins and their blends with dendritic hyperbranched polymers. J. Appl. Polym. Sci., 92, p. 1604.
15. Xu, G., Shi, W. F., Gong, M., Yu, F. and Feng, J. P. (2004) Curing behavior and toughening performance of epoxy resins containing hyperbranched polyester. Polym. Adv. Tech., 15, p. 639.
16. Varley, R. J. and Wendy, T. (2004) Toughening of an epoxy anhydride resin system using an epoxidized hyperbranched polymer. Polym. Int., 53, p. 69.
17. Varley, R. J. (2004) Toughening of epoxy resin systems using low-viscosity additives. Polym. Int., 53, p. 78.
18. Zhang, D. H. and Jia, D. M. (2006) Toughness and strength improvement of diglycidyl ether of bisphenol-A by low viscosity liquid hyperbranched epoxy resin. J. Appl. Polym. Sci., 101, p. 2504.
19. Zhang, D. H. and Jia, D. M. (2006) Study on performance of diglycidyl ether of bisphenol-A/hyperbranched aromatic polyester epoxy resin HTME system and their toughness mechanism. Polym-Plast. Tech. Eng., 45, p. 1005.
20. Bouer, R. S. (1979) Epoxy Resin Chemistry, American Chemical Society, Washington, DC
21. (1996) Annual Book of ASTM Standards. p. 14.02.
22. Vergnaud, J. M. and Bouzon, J. (1992) Cure of Thermosetting Resins-Modelling and Experiments, Springer-Verlag, London
23. Flynn, J. H. and Wall, L. A. (1966) A quick direct method for the determination of activation energy from thermogravimetric data. J. Polym. Sci. Part B Polym. Let., 4, p. 323.
24. Coats, A. W. and Redfern, J. P. (1964) Kinetic parameters from thermogravimetric data. Nuture, 201, p. 68.
25. Zhang, D. H. and Jia, D. M. (2006) Synthesis of novel low-viscosity liquid epoxidized aromatic hyperbranched polymers. Europ. Polym. J., 42, p. 711.
26. Guo, B. C., Fu, W. W., Jia, D. M., Wang, L. and Qiu, Q. H. (2002) Kinetics of thermal decomposition of cyanate/epoxy blends. Acta Materiae Compositae Sinica, 19, p. 1.