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Volumn 112, Issue 46, 2008, Pages 18104-18109

Interaction of carbon dioxide and hydroxide ion at the surface of ice films

Author keywords

[No Author keywords available]

Indexed keywords

ADSORPTION; AMORPHOUS FILMS; CARBON DIOXIDE; CARBON FILMS; CESIUM; CESIUM COMPOUNDS; DESORPTION; ELECTROLYSIS; FLOW INTERACTIONS; GAS ADSORPTION; HYDROGEN; HYDROGEN BONDS; HYDROLYSIS; ICE; IONS; MOLECULES; TEMPERATURE PROGRAMMED DESORPTION; THEOREM PROVING;

EID: 57249097932     PISSN: 19327447     EISSN: 19327455     Source Type: Journal    
DOI: 10.1021/jp806643e     Document Type: Article
Times cited : (9)

References (49)
  • 16
    • 57249117172 scopus 로고    scopus 로고
    • The reason why the activation energies are zero when the hydration number is small is that in this case the rates are dominated by the long-range ion-dipole interaction and water molecules participating in hydration cannot impede the reactions. See ref 15 for details
    • The reason why the activation energies are zero when the hydration number is small is that in this case the rates are dominated by the long-range ion-dipole interaction and water molecules participating in hydration cannot impede the reactions. See ref 15 for details.
  • 29
    • 1142300287 scopus 로고    scopus 로고
    • (a) Souda, R. Surf. Sci. 2004, 551, 171.
    • (2004) Surf. Sci , vol.551 , pp. 171
    • Souda, R.1
  • 39
    • 57249117169 scopus 로고    scopus 로고
    • Ph.D. Thesis, Seoul National University
    • Kim, J.-H. Ph.D. Thesis, Seoul National University, 2008.
    • (2008)
    • Kim, J.-H.1
  • 44
    • 57249084422 scopus 로고    scopus 로고
    • The reaction quotient Q is defined by the equation Q, HCO3, 3/[CO2]s[OH, s, where [X]s denotes the molar concentration of each species X in the top bilayer of the ice film, which is the probing depth of our RIS and LES measurements. The surface concentrations [CO 2]s and [OH-]s were measured by the RIS and LES techniques in combination with TPD measurements. The upper limit of the reaction quotient was approximated by assuming that the detection limit for HCO3- is the same as that for OH
    • -.
  • 47
    • 57249084424 scopus 로고    scopus 로고
    • - and the L-defect (ref 43).
    • - and the L-defect (ref 43).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.