Synthesis of p-aminophenol from the hydrogenation of nitrobenzene over metal-solid acid bifunctional catalyst

Journal of Chemical Technology and Biotechnology

Volumn 83, Issue 11, 2008, Pages 1466-1471

  Wang, Shufang ^a   Ma, Yuanhui ^a   Wang, Yanji ^a   Xue, Wei ^a   Zhao, Xinqiang ^a  

^a HEBEI UNIVERSITY OF TECHNOLOGY   (China)

Author keywords

Bifunctional catalysts; Hydrogenation; Nitrobenzene; P aminophenol; Rearrangement; Solid acid

Indexed keywords

ACIDS; CALCINATION; CATALYSIS; CATALYSTS; HYDROGENATION; NITROBENZENE; PLATINUM; PLATINUM METALS; ZIRCONIUM ALLOYS;

ACID MEDIUMS; ACID SITES; ACTIVE SITES; AMINO-PHENOLS; BIFUNCTIONAL CATALYSTS; CALCINATION TEMPERATURES; CATALYTIC ACTIVITIES; CATALYTIC HYDROGENATIONS; HIGH ACTIVITIES; HYDROGENATION ACTIVITIES; P-AMINOPHENOL; PHENYLHYDROXYLAMINE; PT LOADINGS; REARRANGEMENT; SHORT-COMINGS; SOLID ACID; SOLID ACIDS; STRONGER ACID SITES; SYNTHESIS OF; SYNTHESIS ROUTES;

SULFURIC ACID;

4 AMINOPHENOL; ALCOHOL; CARBONIC ACID DERIVATIVE; HYDROXYLAMINE; METAL; NITROBENZENE; PHENYLHYDROXYLAMINE; PLATINUM DERIVATIVE; SULFATED ZIRCONIUM; UNCLASSIFIED DRUG; WATER; ZIRCONIUM DERIVATIVE; ZIRCONIUM OXIDE;

ACIDITY; ARTICLE; CATALYSIS; CATALYST; CHEMICAL REACTION; CHEMICAL STRUCTURE; HYDROGENATION; INHIBITION KINETICS; REACTION ANALYSIS; SOLVENT EFFECT; TEMPERATURE;

EID: 57149108276     PISSN: 02682575     EISSN: 10974660     Source Type: Journal    
DOI: 10.1002/jctb.1929     Document Type: Article

References (24)

1. Komatsu T and Hirose T, Gas phase synthesis of para-aminophenol from nitrobenzene on Pt/zeolite catalysts. Appl Catal A 276:95-102 (2004).
2. Rylander PN, Karpenko IM and Pond GR, Process for preparing para-aminophenol. US Patent 3715397 (1973).
3. Gao Y, Wang FD, Liao SJ and Yu DR, Selective hydrogenation of nitrobenzene to p-aminophenol by the polymer-supported palladium-based mono- and bimetallic catalyst. React Kinet Catal Lett 64:351-357 (1998).
4. Rode CV, Vaidya MJ and Chaudhari RV, Synthesis of p-aminophenol by catalytic hydrogenation of nitrobenzene. Org Process Res Dev 3:465-470 (1999).
5. Rode CV, Vaidya M, Jaganathan JR and Chaudhari RV, Hydrogenation of nitrobenzene to p-aminophenol in a four-phase reactor: reaction kinetics and mass transfer effects. Chem Eng Sci 56:1299-1304 (2001).
6. Chandrashekha VR, Manisha JV and Raghunath VC, Single step hydrogenation of nitrobenzene to p-aminophenol. US Patent 6403833 (2002).
7. Wang YJ, Zhang HT, Zhao Q, Wang SF and Li F, Preparation and application of the supported catalyst for p-aminophenol synthesis. CN Patent 1562467 (2004).
8. Chaudhari RV, Diveher SS, Vaidya MJ and Rode CV, Single step process for the preparation of p-aminophenol. US Patent 6028227 (2000).
9. Chu W, Wu XT and Cui MQ, The catalyst for selective hydrogenation of nitrobenzene to p-aminophenol. CN Patent 1562465 (2004).
10. Jin T, Yamaguchi T and Tanabe K, Mechanism of acidity generation on sulfur-promoted metal oxides. J Phys Chem 90:4794-4796 (1986).
11. Yamaguchi T and Tanabe K, Structural identification of acid sites of sulfur-promoted solid super acid and construction of its structure on silica support. Mater Chem Phys 17:3-19 (1987).
12. Arata K, Preparation of superacids by metal oxides for reactions of butanes and pentanes. Appl Catal A 146:3-32 (1996).
13. Risch M and Wolf EE, n-Butane and n-pentane isomerization over mesoporous and conventional sulfated zirconia catalysts. Catal Today 62:255-268 (2000).
14. Yadav GD and Nair JJ, Sulfated zirconia and its modified versions as promising catalysts for industrial processes. Micropor Mesopor Mater 33:1-48 (1999).
15. Zhang L, Wang L and Chen JM, Studies of peroxodisulfated zirconia solid acid. Chem J Chin Univ 21:116-119 (2000).
16. Fu SY, Li J, Zhang HS and Yu HS, Synthesis of N-hydroxybenzenamine and its spectroscopy. Guangzhou Chem 21:4-13 (1999).
17. Jin JC, Rearrangement Reaction. Higher Education Publishing Co., Beijing, p. 278 (1990).
18. Arata K, Preparation of superacids by metal oxides and their catalytic action. Adv Catal 37:165-171 (1990).
19. 2. J Catal 151:96-101 (1995).
20. Tran MT, Gnep NS, Szabo G and Guisnet M, Influence of the calcination temperature on the acidic and catalytic properties of sulphated zirconia. Appl Catal A 171:207-217 (1998).
21. Hahn A, Ressler T, Jentoft RE and Jentoft FC, The role of the 'glow phenomenon' in the preparation of sulfated zirconia catalysts. Chem Commun 537-538 (2001).
22. Wan KT, Khouw CB and Davis ME, Studies on the catalytic activity of zirconia promoted with sulfate, iron, and manganese. J Catal 158:311-326 (1996).
23. Song X and Sayari A, Sulfated zirconia-based strong solid-acid catalysts: recent progress. Catal Rev Sci Eng 38:329-412 (1996).
24. March J, Advanced Organic Chemistry. McGraw-Hill, New York, p. 616 (1977).