The colloidal structure of bitumen: Consequences on the rheology and on the mechanisms of bitumen modification

Advances in Colloid and Interface Science

Volumn 145, Issue 1-2, 2009, Pages 42-82

  Lesueur, Didier ^a  

^a Eurovia España ^*  (Spain)

Author keywords

Bitumen; Mineral fillers; Multiphase materials; Polymer modified bitumen; Rheology

Indexed keywords

ABS RESINS; ACIDS; COLLOIDS; COMPOSITE MATERIALS; ELASTICITY; FILLERS; MECHANICAL PROPERTIES; MINERALOGY; MINERALS; MINING; PHOTORESISTS; PLASTICITY; POLYMERS; RHEOLOGY; SILICA; SILICATE MINERALS; STRUCTURAL PROPERTIES; TITRATION; VISCOSITY;

ARTIFICIAL MATERIALS; BITUMEN; COLLOIDAL STRUCTURES; COLLOIDAL SUSPENSIONS; CONSTRUCTION MATERIALS; CONTINUOUS PHASES; DROPLET SHAPES; KEY PARAMETERS; LITERATURE DATUMS; MINERAL FILLERS; MODIFIED BITUMENS; MULTIPHASE MATERIALS; PALIERNE MODELS; PROMISING APPROACHES; RHEOLOGICAL PROPERTIES; SOLVATION PARAMETERS;

BITUMINOUS MATERIALS;

EID: 56949101483     PISSN: 00018686     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.cis.2008.08.011     Document Type: Review

References (332)

1. Connan J. Use and trade of bitumen in antiquity and prehistory: molecular archaelogy reveals secrets of past civilizations. Phil Trans R Soc Lond B 354 (1999) 33-50
2. Abraham H. Asphalt and Allied Substances. 6th Ed. (1960), Van Nostrand, New York
3. Murali Krishnan J., and Rajagopal K.R. Review of uses and modeling of bitumen from ancient to modern times. Appl Mech Rev 56 (2003) 149-214
4. Barakat A.O., Mostafa A., Qian Y., Kim M., and Kennicutt II M.C. Organic geochemistry indicates Gebel El Zeit, Gulf of Suez, is a source of bitumen used in some Egyptian Mummies. Geoarchaelogy 20 (2005) 211-228
5. Lay M.G. Ways of the World (1992), Rutgers Univ. Press, New Brunswick
6. Krchma L.C., and Gagle D.W. A U.S.A. history of asphalt refined from crude oil and its distribution. Proc Assoc Asphalt Paving Techn 43A (1974) 25-88
7. Romagosa H. The market for polymer modified asphalts in the USA - 2003. Volumes and trends, Annual Meeting of the Association of Modified Asphalt Producers, New Orleans (2003)
8. Pfeiffer J.P. Introduction. Definitions, nomenclature and conceptsin. In: Pfeiffer J.P. (Ed). The Properties of Asphaltic Bitumen (1950), Elsevier, Amsterdam 1-12
9. Chambers E. Cyclopaedia or an Universal dictionary of arts and sciences, 2 vol. (1728), J. and J. Knapton, London
10. Speight J.G. The Chemistry and Technology of Petroleum. 3rd. Ed. (1999), Marcel Dekker, New-York
11. European Committee for Standardization. EN 12597: Bitumen and bituminous binders - Terminology (2000), European Committee for Standardization, Brussels
12. European Committee for Standardization. EN 12591: Bitumen and bituminous binders - Specifications for paving grade bitumens (1999), European Committee for Standardization, Brussels
13. Lanier D. Heavy oil - a major energy source for the 21st century. Proc. 7th Unitar Heavy Crude and Tar Sands Int. Conf., Beijing (1998) paper 1998.039
14. Burstyna I., Kromhouta H., and Boffettab P. Literature review of levels and determinants of exposure to potential carcinogens and other agents in the road construction industry. Am Indust Hygiene Assoc J 61 (2000) 715-726
15. Durand B. A history of organic geochemistry. Oil Gas Sci Techn - Rev IFP 58 (2003) 203-231
16. Corbett L.W. Manufacture of petroleum asphalt. In: Hoiberg A.J. (Ed). Bituminous Materials: Asphalts, Tars and Pitches (1965), Interscience Publishers, New York 81-122 Vol. 2, Part 1
17. Read J., and Whiteoak D. The Shell Bitumen Handbook. 5th Ed. (2003), Thomas Telford Publishing, London
18. PIARC (World Road Association), Use of Modified Bituminous Binders, Special Bitumens and Bitumens with Additives in Road Pavements, Routes/Roads 303 also available from LCPC Eds, Paris (France), 1999.
19. Schmidt R.J., and Santucci L.E. A practical method for determining the glass transition temperature of asphalts and calculation of their low temperature viscosities. Proc Assoc Asphalt Paving Techn 35 (1966) 61-85
20. Claudy P., Létoffé J.M., King G.N., and Planche J.P. Caractérisation des bitumes routiers par analyse calorimétrique différentielle (ACD). Analyse thermo-optique (ATO). Corrélation entre propriétés physiques et résultats ACD. Bull Liaison Lab Ponts Chaussées 177 (1992) 45-51
21. Claudy P., Létoffé J.M., King G.N., and Planche J.P. Characterization of asphalts cements by thermomicroscopy and differential scanning calorimetry: Correlation to classic physical properties. Fuel Sci Technol Int 10 (1992) 735-765
22. Jiménez-Mateos J.M., Quintero L.C., and Rial C. Characterization of petroleum bitumens and their fractions by thermogravimetric analysis and differential scanning calorimetry. Fuel 75 (1996) 1691-1700
23. Turner T.F., and Branthaver J.F. DSC studies of asphalts and asphalts components. In: Usmani A.M. (Ed). Asphalt Science and Technology (1997), Marcel Dekker, New York 59-101
24. Mortazavi M., and Moulthrop J.S. SHRP Materials Reference Library, SHRP report A-646 (1993), National Research Council, Washington D. C.
25. Committee for a study for a future strategic highway research program, stategic highway research. Transportation Research Board Special Report 260 (2001), National Research Council, Washington D. C.
26. Branthaver J.F., Petersen J.C., Robertson R.E., Duvall J.J., Kim S.S., Harnsberger P.M., et al. Binder Characterization and Evaluation - vol. 2 Chemistry, SHRP Report A-368 (1994), National Research Council, Washington D. C.
27. Traxler R.N. Asphalt: Its Composition, Properties and Uses (1961), Reinhold Publishing, New-York
28. Barth E.J. Asphalt - Science and Technology (1962), Gordon and Breach, New-York
29. Domin M., Herod A., Kandiyoti R., Larsen J.W., Lazaro M.J., Li S., et al. A comparative study of bitumen molecular weight distributions. Energy Fuels 13 (1999) 552-557
30. Jennings P.W., Desando M.A., Raub M.F., Moats R., Mendez T.M., Stewart F.F., et al. NMR spectroscopy in the characterization of eight selected asphalts. Fuel Sci Techn Int 10 (1992) 887-907
31. Boussingault J.B. Extrait d'un mémoire sur la composition des bitumes. C R Acad Sci 3 (1836) 375-378
32. Boussingault J.B. Mémoire sur la composition des bitumes. Ann Chim Phys 64 (1837) 141-151
33. Richardson C. The Modern Asphalt Pavement. 2nd Ed. (1910), Wiley, New York
34. Labout J.W.A. Constitution of asphaltic bitumen. In: Pfeiffer J.P. (Ed). The Properties of Asphaltic Bitumen (1950), Elsevier, Amsterdam 13-48
35. Errera J. The sensitiveness to light of asphalt as a function of its degree of dispersion. Trans Faraday Soc 19 (1923) 314-317
36. Rostler F.S. Fractional composition: Analytical and functional significance. In: Hoiberg A.J. (Ed). Bituminous Materials: Asphalts, Tars and Pitches (1965), Interscience Publishers, New York 151-222 Vol. 2, Part 1
37. Corbett L.W. Composition of asphalt based on generic fractionation, using solvent deasphaltening, elution-adsorption chromatography and densimetric characterization. Anal Chem 41 (1969) 576-579
38. American Society for Testing and Materials. ASTM D-4124: Test Methods for Separation of Asphalt Into Four Fractions (2001), ASTM, Philadelphia
39. Ecker A. The application of Iatroscan-technique for analysis of bitumen. Petrol Coal 43 (2001) 51-53
40. Leroy G. Bitumen analysis by thin layer chromatography (IATROSCAN). Proc. 4th Eurobitume Congress, Madrid (1989) 166-170
41. Piéri, N., Etude du Vieillissement Simulé et In-Situ des Bitumes Routiers par IRTF et Fluorescence UV en Excitation-Emission Synchrones, Ph. D. Thesis: Univ. Aix-Marseille St-Joseph (France), 1995
42. Koots J.A., and Speight J.G. Relation of petroleum resins to asphaltenes. Fuel 54 (1975) 179-184
43. Speight J.G. Petroleum asphaltenes. Part 1. Asphaltenes, resins and the structure of petroleum. Oil Gas Sci Technol 59 (2004) 467-477
44. Becker J.R. Crude Oil - Waxes, Emulsiones and Asphaltenes (1997), PennWell, Tulsa
45. Di Primio R., Horsfield B., and Guzman-Vega M.A. Determining the temperature of petroleum formation from the kinetic properties of petroleum asphaltenes. Nature 406 (2000) 173-176
46. Espinat D., Rosenberg E., Scarsella M., Barre L., Fenistein D., and Broseta D. Colloidal structural evolution from stable to flocculated state of asphaltene solutions and heavy crudes. In: Mullins O., and Sheu E.Y. (Eds). Structures and Dynamics of Asphaltenes (1998), Plenum Press, New-York 145-201
47. Lin J.R., Lian H., Sadeghi K.M., and Yen T.F. Asphalt colloidal types differentiated by Korcak distribution. Fuel 70 (1991) 1439-1444
48. Speight J.G. Molecular models for petroleum asphaltenes and implication for asphalt science and technology. Proc. Chemistry of Bitumen 1, Roma (1991) 154-207
49. Thanh N.X., Hsieh M., and Philp R.P. Waxes and asphaltenes in crude oils. Org Geochem 30 (1999) 119-132
50. Lian H., Lin J.R., and Yen T.F. Peptization studies of asphaltene and solubility parameter spectra. Fuel 73 (1994) 423-428
51. Laux H., Rahimian I., and Butz T. Thermodynamics and mechanism of stabilization and precipitation of petroleum colloids. Fuel Process Technol 53 (1997) 69-79
52. Rogel E. Studies on asphaltene aggregation via computational chemistry. Colloids Surf, A 104 (1995) 85-93
53. Dickie J.P., and Yen T.F. Macrostructure of the asphaltic fractions by various instrumental methods. Anal Chem 39 (1967) 1847-1852
54. Mullins O. Optical interrogation of aromatic moieties in crude oils and asphaltenes. In: Mullins O., and Sheu E.Y. (Eds). Structures and Dynamics of Asphaltenes (1998), Plenum Press, New-York 21-77
55. Scotti R., and Montanari L. Molecular structure and intermolecular interaction of asphaltenes by FT-IR, NMR, EPR. In: Mullins O., and Sheu E.Y. (Eds). Structures and Dynamics of Asphaltenes (1998), Plenum Press, New-York 79-113
56. Bergmann U., Mullins O.C., and Cramer S.P. X-Ray Raman spectroscopy of carbon in asphaltene: Light element characterization with bulk sensitivity. Anal Chem 72 (2000) 2609-2612
57. Michon L., Martin D., Planche J.P., and Hanqueta B. Estimation of average structural parameters of bitumens by 13C nuclear magnetic resonance spectroscopy. Fuel 76 (1997) 9-15
58. Sheremata J.M., Gray M.R., Dettman H.D., and McCaffrey W.C. Quantitative molecular representation and sequential optimization of Athabasca asphaltenes. Energy Fuels 18 (2004) 1377-1384
59. Kilpatrick P.K., and Spiecker P.M. Asphaltene emulsions. In: Sjöblom J. (Ed). Encyclopedic of Emulsion Technology (2000), Marcel Dekker, New-York 707-730
60. Kallevik, H., Characterisation of Crude Oil and Model Oil Emulsions by means of Near Infrared Spectroscopy and Multivariate Analysis, doctoral thesis, Department of Chemistry, University of Bergen, 1999, Bergen (Norway) cited in T. E. Havre, Formation of Calcium Naphthenate in Water/Oil Systems, Naphthenic Acid Chemistry and Emulsion Stability, doctoral thesis, Department of Chemistry, Norwegian University of Science and Technology, 2002, Trondheim (Norway).
61. Zhao S., Kotlyar L.S., Sparks B.D., Woods J.R., Gao J., and Chung K.H. Solids contents, properties and molecular structures for various asphaltenes from different oilsands. Fuel 80 (2001) 1907-1914
62. Brandt H.C.A., Hendriks E.M., Michels M.A.J., and Visser F. Thermodynamic modeling of asphaltene stacking. J Phys Chem 99 (1995) 10430-10432
63. Akbarzadeh K., Bressler D.C., Wang J., Gawrys K.L., Gray M.R., Kilpatrick P.K., et al. Association behavior of pyrene compounds as models for asphaltenes. Energy Fuels 19 (2005) 1268-1271
64. Yen T.F., Erdman J.G., and Pollack S.S. Investigation of the structure of petroleum asphaltenes by X-ray diffraction. Anal Chem 33 (1961) 1587-1594
65. Sadeghi M.A., Chilingarian G.V., and Yen T.F. X-ray diffraction of asphaltenes. Energy Sources 8 (1986) 99-123
66. Sheu E.Y., De Tar M.M., and Storm D.A. Surface activity and dynamics of asphaltenes. In: Sharma M.K., and Yen T.F. (Eds). Asphaltene Particles in Fossil Fuel Exploration, Recovery, Refining and Production (1994), Plenum Press 115-121
67. Roux J.N., Broseta D., and Demésans B. Study of asphaltene aggregation: concentration and solvent quality effects. Langmuir 17 (2001) 5085-5092
68. Priyanto S., Mansoori G.A., and Suwono A. Measurement of property relationships of nano-structure micelles and coacervates of asphaltene in a pure solvent. Chem Eng Sci 56 (2001) 6933-6939
69. In: Mullins O., and Sheu E.Y. (Eds). Structures and Dynamics of Asphaltenes (1998), Plenum Press, New-York
70. Taylor S.E. The electrodeposition of asphaltenes and implications for asphaltene structure and stability in crude and residual oils. Fuel 77 (1998) 821-828
71. Fotland P., and Anfindsen H. Conductivity of asphaltenes. In: Mullins O., and Sheu E.Y. (Eds). Structures and Dynamics of Asphaltenes (1998), Plenum Press, New-York 247-266
72. Swanson J.M. A contribution to the physical chemistry of the asphalts. J Phys Chem 46 (1942) 141-150
73. Marruska S., and Rao B.M.L. The role of polar species in the aggregation of asphaltenes. Fuel Sci Technol Int 5 (1987) 119-168
74. Fotland P., Anfindsen H., and Fadnes F.H. Detection of asphaltene precipitation and amounts precipitated by measurement of electrical conductivity. Fluid Phase Equilib 82 (1993) 157-164
75. Fotland P., and Anfindsen H. Electrical conductivity of asphaltenes in organic solvents. Fuel Sci Technol Int 14 (1996) 101-116
76. Pernyeszi T., Patzko A., Berkesi O., and Dekany I. Asphaltene adsorption on clays and crude oil reservoir rocks. Colloids Surf A: Phys Chem Aspects 137 (1998) 373-384
77. Petersen J.C., and Plancher H. Model studies and interpretive review of the competitive adsorption and water displacement of petroleum asphalt chemical functionalities on mineral aggregate surfaces. Pet Sci Techn 16 (1998) 89-131
78. Bauget F., Langevin D., and Lenormand R. Dynamic surface properties of asphaltenes and resins at the oil-air interface. J Colloid Interface Sci 239 (2001) 501-508
79. Boduszynski M.M., Chadha B.R., and Pineles H. Investigations on Romaskino Asphaltic Bitumen. 1. Use of ion-exchange and adsorption chromatograhy for the separation of maltenes. Fuel 56 (1977) 145-148
80. Boduszynski M.M., Chadha B.R., and Pochopien T.S. Investigations on Romaskino Asphaltic Bitumen. 3. fractionation of asphaltenes using ion exchange chromatography. Fuel 56 (1977) 432-436
81. Green J.B., Hoff R.J., Woodward P.W., and Stevens L.L. Separation of liquid fossil fuels into acid, base, and neutral concentrates. 1. An improved nonaqueous ion exchange method. Fuel 63 (1984) 1290-1301
82. Petersen J.C., Robertson R.E., Branthaver J.F., Harnsberger P.M., Duvall J.J., Kim S.S., et al. Binder characterization and evaluation. Vol. 4: Test Methods, SHRP Report A-370 (1994), National Research Council, Washington D. C.
83. Duvall J.J., Miyake G., Catalfomo M.W., Kim S.S., Colgin D.C., and Branthaver J.F. Size exclusion chromatography and ion exchange chromatography separations of asphalts. SHRP Report A-663 (1993), National Research Council, Washington D. C.
84. Jada A., and Salou M. Effects of the asphaltene and resin contents of the bitumens on the water-bitumen interface properties. J Pet Sci Eng 33 (2002) 185-193
85. Langevin D., Poteau S., Hénaut I., and Argillier J.F. Crude oil emulsion properties and their application to heavy oil transportation. Oil Gas Sci Technol - Rev IFP 59 (2004) 511-521
86. Acevedo S., Gutierrez X., and Rivas H. Bitumen-in-water emulsions stabilized with natural surfactants. J Colloid Interface Sci 242 (2001) 230-238
87. Durrieu F. Influence des produits polaires des bitumes routiers sur leurs propriétés interfaciales. Bull Liaison Lab Ponts Chaussées, Spécial V (1977) 37-43
88. Chaverot P., Cagna A., Glita S., and Rondelez F. Interfacial tension of bitumen-water interfaces. Part 1: influence of endogenous surfactants at acidic pH. Energy Fuels 22 (2008) 790-798
89. Braun C.A., and Hay G.S. Manufacture of stable aqueous emulsion. Br Pat Specif 254 012 (1925)
90. Simaillaud B., Mazé M., Brûlé B., and Potti J.J. Caractérisation de l'interface bitume-eau par la mesure de tension interfaciale. Bull Liaison Lab Ponts Chaussées 234 (2001) 3-15
91. Gu G., Xu Z., Nandakumar K., and Masliyah J.H. Influence of water-soluble and water-insoluble natural surface active components on the stability of water-in-toluene-diluted bitumen emulsion. Fuel 81 (2002) 1859-1869
92. Rosinger A. Beiträge zur Kolloidchemie des Asphalts. Kolloid-Z. 15 (1914) 177-179
93. Nellensteyn, F.J., Bereiding en Constitutie van Asphalt, Ph. D. Thesis: Delft University (Netherland), 1923.
94. Nellensteyn F.J. The constitution of asphalt. J Inst Pet Technol 10 (1924) 311-325
95. Pfeiffer J.P., and Saal R.N.J. Asphaltic bitumen as colloid systems. J Phys Chem 44 (1940) 139-149
96. Saal II R.N.J. Physical properties of asphaltic bitumen. 1. Rheological properties. In: Pfeiffer J.P. (Ed). The Properties of Asphaltic Bitumen (1950), Elsevier, Amsterdam 50-76
97. Saal R.N.J., and Labout J.W.A. Rheological properties of asphaltic bitumens. J Phys Chem 44 (1940) 149-165
98. De Gennes P.G. Scaling Concepts in Polymer Physics (1979), Cornell University Press, Ithaca
99. Ferry J.D. Viscoelastic Properties of Polymers. 3rd Ed. (1980), Wiley & Sons, New York
100. Russel W.B., Savill D.A., and Schowalter W.R. Colloidal Dispersions (1992), Cambridge Univ. Press, London
101. Anderson D.A., Christensen D.W., Bahia H.U., Dongre R., Sharma M.G., Antle C.E., et al. Binder Characterization and Evaluation Volume 3: Physical Characterization, SHRP report A-369 (1994), National Research Council, Washington D. C.
102. Lee A.R., Warren J.B., and Waters D.B. The flow properties of bituminous materials. J Inst Pet Technol 26 (1940) 101-128
103. Lesueur D., Gérard J.F., Claudy P., Létoffé J.M., Planche J.P., and Martin D. A structure-related model to describe asphalt linear viscoelasticity. J Rheol 40 (1996) 813-836
104. Gaestel C., Smadja R., and Lamminan K.A. Contribution à la connaissance des propriétés des bitumes routiers. Revue Générale des Routes et Aérodrômes 466 (1971) 85-97
105. Petersen J.C., Robertson R.E., Branthaver J.F., Harnsberger P.M., Duvall J.J., Kim S.S., et al. Binder Characterization and Evaluation Volume 1, SHRP report A-367 (1994), National Research Council, Washington D. C.
106. Christensen D.W., and Anderson D.A. Rheological evidence concerning the molecular architecture of asphalt cements. Proc. Chemistry of Bitumen 2, Rome (1991) 568-595
107. Redelius, P., The structure of asphaltenes in bitumen, Road Mater. Pavement Des., special issue EATA 2006 (2006) 143-162
108. Porte G. In: Daoud M., and Williams C.E. (Eds). From giant micelles to fluid membranes: Polymorphism in dilute solutions of surfactant molecules in Soft Matter Physics (1999), Springer-Verlag, Berlin 155-186
109. Francken, L. Ed., Bituminous Binders and Mixes, RILEM report 17, London: E & FN Spon, 1998.
110. Prausnitz J.M., Lichtenthaler R.N., and Gomes de Azevedo E. Molecular Thermodynamics of Fluid-Phase Equilibria. 3rd Ed. (2000), Prentice Hall, Englewoods Cliff
111. Israelachvili J.N. Intermolecular and Surface Forces. 2nd Ed. (1992), Academic Press, London
112. Bodan A.N. Polyquasispherical structure of petroleum asphalts. Chem Technol Fuels Oils 18 (1982) 614-618
113. Storm D.A., Sheu E.Y., and De Tar M.M. Macrostructure of asphaltenes in vaccuum residue by small-angle X-Ray scattering. Fuel 72 (1993) 977-981
114. Storm D.A., Barresi R.J., and Sheu E.Y. Rheological study of Ratawi vacuum residue in the 298-673 K temperature range. Energy Fuels 9 (1995) 168-176
115. Dwiggins Jr. C.W. A small angle X-Ray scattering study of the colloidal nature of petroleum. J Phys Chem 69 (1965) 3500-3506
116. Ravey J.C., Ducouret G., and Espinat D. Asphaltene macrostructure by small angle neutron scattering. Fuel 67 (1988) 1560-1567
117. Overfield R.E., Sheu E.Y., Sinha S.K., and Laing K.S. SANS study of asphaltene aggregation. Fuel Sci Technol Int 7 (1989) 611-624
118. Bardon C., Barré L., Espinat D., Guille V., Li M.H., Lambard J., et al. The colloidal structure of crude oils and suspensions of asphaltenes and resins. Fuel Sci Technol Int 14 (1996) 203-242
119. Hénaut I., Barré L., Argillier J.F., Brucy F., and Bouchard R. Rheological and structural properties of heavy crude oils in relation with their asphaltene content. Proc. Soc. Petrol. Eng. Int. Symposium on Oilfield Chem., Houston (Feb. 2001) Paper SPE 65020
120. Mason T.G., and Lin M.Y. Asphaltene nanoparticle aggregation in mixtures of incompatible crude oils. Phys Rev E 67 (2003) 1-4 050401
121. Yen T.F. The colloidal aspect of a macrostructure of petroleum asphalt. Fuel Sci Technol Int 10 (1992) 723-733
122. Lesueur D., Gérard J.F., Claudy P., Létoffé J.M., Planche J.P., and Martin D. Relationships between the structure and the mechanical properties of paving grade asphalt cements. J Assoc Asphalt Paving Techn 66 (1997) 486-507
123. Saal III R.N.J. Physical properties of asphaltic bitumen. 2. Surface phenomena, thermal and electrical properties, etc. In: Pfeiffer J.P. (Ed). The Properties of Asphaltic Bitumen (1950), Elsevier, Amsterdam 77-108
124. Lesueur D. On the thermorheological complexity and relaxation modes of asphalt cements. J Rheol 43 (1999) 1701-1704
125. Gawrys K.L., and Kilpatrick P.K. Asphaltene aggregation: techniques for analysis. J Instr Sci Techn 32 (2004) 247-253
126. Gawrys K.L., and Kilpatrick P.K. Asphaltenic aggregates are polydisperse oblate cylinders. J Colloid Interface Sci 288 (2005) 325-334
127. Murgich J., Rodriguez J.M., and Aray Y. Molecular recognition and molecular mechanics of micelles of some model asphaltenes and resins. Energy Fuels 10 (1996) 68-76
128. Brûlé B., and Migliori F. Application de la chromatographie sur gel perméable à la caractérisation de bitumes routiers et de leur susceptibilité au vieillissement artificiel. Bull Liaison Lab Ponts Chaussées 128 (1983) 107-120
129. Fenistein D., Barré L., Broseta D., Espinat D., Livet A., Roux J.N., et al. Viscosimetric and neutron scattering study of asphaltene aggregates in mixed toluene/heptane solvents. Langmuir 14 (1998) 1013-1020
130. Sirota E. Physical structure of asphaltenes. Energy Fuels 19 (2005) 1290-1296
131. Meakin P. Fractal aggregates. Adv Colloid Interface Sci 28 (1988) 249-331
132. Weitz D.A., Huang J.S., Lin M.Y., and Sung J. Limits of the fractal dimension for irreversible kinetic aggregation of gold colloids. Phys Rev Lett 54 (1985) 1416-1419
133. Loeber L., Sutton O., Morel J., Valleton J.M., and Muller G. New direct observations of asphalts and asphalt binders by scanning electron microscopy and atomic force microscopy. J Microsc 182 (1996) 32-39
134. Jäger A., Lackner R., Eisenmenger-Sittner C., and Blab R. Identification of microstructural components of bitumen by means of atomic force microscopy (AFM). Proc Appl Math Mech 4 (2004) 400-401
135. Masson J.F., Leblond V., and Margeson J. Bitumen morphologies by phase-detection atomic force microscopy. J Microsc 221 (2006) 17-29
136. Masson J.F., Leblond V., Margeson J., and Bundalo-Perc S. Low-temperature bitumen stiffness and viscous paraffinic nano- and micro-domains by cryogenic AFM and PDM. J Microsc 227 (2007) 191-202
137. Baginska K., and Gawel I. Effect of origin and technology on the chemical composition and colloidal stability of bitumens. Fuel Proces Technol 85 (2004) 1453-1462
138. Bearsley S., Forbes A., and Haverkamp R.G. Direct observation of the asphaltene structure in paving-grade bitumen using confocal laser-scanning microscopy. J Microsc 215 (2004) 149-155
139. Lu X., Langton M., Olofsson P., and Redelius P. Wax morphology in bitumen. J Mater Sci 40 (2005) 1893-1900
140. Mack C. Colloid chemistry of asphalts. J Phys Chem 36 (1932) 2901-2914
141. Leontaritis K.J., and Mansoori G.A. Asphaltene deposition: a survey of field experiences and research approaches. J Pet Sci Eng 1 (1988) 229-239
142. Taylor S.E. The electrodeposition of asphaltenes and implications for asphaltene structure and stability in crude and residual oils. Fuel 77 (1998) 821-828
143. Gawrys K.L., Spiecker P.M., and Kilpatrick P.K. The role of asphaltene solubility and chemical composition on asphaltene aggregation. Pet Sci Technol 21 (2003) 461-489
144. Lesueur, D., Propriétés Mécaniques des Liants Routiers, Ph. D. Thesis: INSA Lyon (France), 1996.
145. Gawel I., Czechowski F., and Baginska K. Study of wax isolated from bitumen. Proc. 1st Eurasphalt and Eurobitume Congress, Strasbourg (1996) 1-14 paper E&E 5.139
146. Claudy P.M., Létoffé J.M., Martin D., and Planche J.P. Thermal behavior of asphalt cements. Thermochim Acta 324 (1998) 203-213
147. Masson J.F., and Polomark G.M. Bitumen microstructure by modulated differential scanning calorimetry, Thermochim. Acta 374 (2001) 105-114 (see also Masson J.-F. and G. M. Polomark, Erratum to Bitumen microstructure by modulated differential scanning calorimetry [Thermochim. Acta 374 (2001) 105-114]. Thermochim Acta 413 (2004) 273
148. Masson J.F., Polomark G.M., and Collins P. Time-dependent microstructure of bitumen and its fractions by modulated differential scanning calorimetry. Energy Fuels 16 (2002) 470-476
149. Masson J.F., Collins P., and Polomark G.M. Steric hardening and the ordering of bitumen asphaltenes in bitumen. Energy Fuels 19 (2005) 120-122
150. Nyburg S.C., and Potworowski J.A. Prediction of unit cells and atomic coordinates for the n-alkanes. Acta Crystallogr B29 (1973) 347-352
151. Heukelom W. A bitumen test data chart for showing the effect of temperature on the mechanical behaviour of asphaltic bitumens. J Inst Pet 55 (1969) 404-417
152. Bahia H., Anderson D.A., and Christensen D.W. The bending beam rheometer : a simple device for measuring the low temperature rheology of asphalt binders. J Assoc Asphalt Paving Techn 61 (1992) 172-198
153. Claudy P., Létoffé J.M., Rondelez F., Germanaud L., King G.N., Planche J.P., et al. A new interpretation of time dependent physical hardening in asphalt based on DSC and optical thermoanalysis. ACS Symposium on Chemistry and Characterization of Asphalts, Washington, D.C. (1992)
154. Champion L., Gérard J.F., Planche J.P., Martin D., and Anderson D.A. Asphaltenic-waxy bitumens: limitations to the time-temperature superposition principle. Proc. Eurobitume Workshop, Luxembourg (1999) paper 48
155. Brosseaud Y. Etat du développement des enrobés tièdes en France. Revue Générale des Routes et Aérodrômes 857 (2007) 45-53
156. Edwards Y., Tasdemir Y., and Isacsson U. Influence of commercial waxes and polyphosphoric acid on bitumen and asphalt concrete performance at low and medium temperatures. Mat Struct 39 (2006) 725-737
157. Edwards Y., Tasdemir Y., and Isacsson U. Effects of commercial waxes on asphalt concrete mixtures performance at low and medium temperatures. Cold Reg Sci Technol 45 (2006) 31-41
158. Edwards Y., and Redelius P. Rheological effects of waxes in bitumen. Energy Fuels 17 (2003) 511-520
159. Traxler R.N. Relation between asphalt composition and hardening by volatilization and oxidation. Proc Assoc Asphalt Paving Techn 30 (1961) 359-372
160. Bell C. Summary Report on Aging of Asphalt-Aggregate Systems, SHRP Report A-305 (1989), National Research Council, Washington D. C.
161. Wright J.R. Weathering: theoretical and practical aspects of asphalt durability. In: Hoiberg A.J. (Ed). Bituminous Materials: Asphalts, Tars and Pitches (1965), Interscience Publishers, New York 249-306 Vol. 2, Part 1
162. Isaccson, and Zeng H. Cracking of asphalt at low temperature as related to bitumen rheology. J Mater Sci 33 (2003) 2165-2170
163. Christensen D.W., and Anderson D.A. Interpretation of dynamic mechanical test data for paving grade asphalt cements. J Assoc Asphalt Paving Techn 61 (1992) 67-98
164. Moschopedis S.E., and Speight J.G. Influence of metal salts on bitumen oxidation. Fuel 57 (1978) 235-240
165. Siddiqui M.N., and Ali M.F. Studies on the ageing behavior of the Arabian asphalts. Fuel 78 (1999) 1005-1015
166. Farcas, F., Étude d'une méthode de simulation du vieillissement des bitumes sur route, LCPC Research report CR21, Paris (France): LCPC Ed., 1998
167. Corbett L.W., and Swarbrick R.E. Composition analysis used to explore asphalt hardening. Proc Assoc Asphalt Paving Techn 29 (1960) 104-112
168. Kats B.I., Glotova N.A., and Kudryashova A.I. Study of aging of asphalts from Romashkino and Ust'-Balyk under natural conditions. Chem Technol Fuels Oils 12 (1976) 121-124
169. Moschopedis S.E., and Speight J.G. The effect of air blowing on the porperties and constitution of a natural bitumen. J Mater Sci 12 (1977) 990-998
170. Groupe National Bitume, Susceptibilité au vieillissement des bitumes - Expérimentation A08, LCPC Research report CR19, Paris (France): LCPC Ed., 1997.
171. Petersen J.C. Asphalt oxidation - an overview including a new model for oxidation proposing that physicochemical factors dominate the oxidation kinetics. Fuel Sci Technol Int 11 (1993) 57-87
172. Lamontagne J., Dumas P., Mouillet V., and Kister J. Comparison by Fourier transform infrared (FTIR) spectroscopy of different ageing techniques: application to road bitumens. Fuel 80 (2001) 483-488
173. Petersen J.C., Barbour F.A., and Dorrence S.M. Catalysis of asphalt oxidation by mineral aggregate surfaces and asphalt components. Proc Assoc Asphalt Paving Techn 43 (1974) 162-177
174. Wurstner R.G., Higgins W.A., and Craig W.G. Laboratory evaluation of factors influencing the performance of paving asphalts - the effect of antioxidants, polymers and methods of processing. Proc Assoc Asphalt Paving Techn 29 (1960) 253-269
175. Petersen J.C., Plancher H., and Harnsberger P.M. Lime treatment of asphalt to reduce age-hardening and improve the flow properties. Proc Assoc Asphalt Paving Technol 56 (1987) 632-653
176. James A., and Stewart D. The use of fatty amine derivatives to slow down the age hardening process in bitumen. Proc. Chemistry of Bitumen 1, Roma (1991) 671-684
177. Ouyang C., Wang S., Zhang Y., and Zhang Y. Improving the aging resistance of asphalt by addition of Zinc dialkyldithiophosphate. Fuel 85 (2006) 1060-1066
178. Marignier J.L. Niepce : L'Invention de la Photographie (1999), Belin, Paris
179. Huang J. In: Usmani A.M. (Ed). Oxidation of asphalt fractions in Asphalt Science and Technology (1997), Marcel Dekker, New York 119-134
180. Martin G., and Tilley R.I. Effect of radiation intensity on photo-oxidation of an air-blown bitumen. J Appl Chem 19 (1969) 235-240
181. Campbell P.G., Wright J.R., and Bowman P.B. The effect of temperature and humidity on the oxidation of air-blown asphalts. Mater Res Stand 2 (1962) 988-995
182. Traxler R.N. A review of the rheology of bituminous materials. J Colloid Sci 2 (1947) 49-68
183. Traxler R.N. Rheology and rheological modifiers others than elastomers: Structure and time. In: Hoiberg A.J. (Ed). Bituminous Materials: Asphalts, Tars and Pitches (1964), Interscience Publishers, New York 143-211 Vol. 1
184. Traxler R.N., and Schweyer H.E. Increase in viscosity of asphalts with time. Proc Am Soc Testing Mat 36 (1936) 544-551
185. Pechenyi B.G., and Kuznetsov O.I. Formation of equilibrium structures in bitumens. Chem Technol Fuels Oils 26 (1991) 372-375
186. Halstead W.J., and Welborn J.Y. History of the development of asphalt testing apparatus and asphalt specifications. Proc Assoc Asphalt Paving Techn 43A (1974) 89-120
187. Saal R.N.J., and Koens G. Investigation into the plastic properties of asphaltic bitumens. J Inst Pet 19 (1933) 176-212
188. Duriez M., and Arrambide J. Nouveau Traité de Matériaux de Construction, Tome 3. 2nd Ed. (1962), Dunod, Paris
189. Siegmann M.C. Methods of routine investigation. In: Pfeiffer J.P. (Ed). The Properties of Asphaltic Bitumen (1950), Elsevier, Amsterdam 155-188
190. Gaskins F.H., Brodnyan J.G., Philippoff W., and Thelen E. The rheology of asphalt. II. Flow characteristics of asphalt. Trans Soc Rheol IV (1960) 265-278
191. Pfeiffer J.P., and Van Doormaal P.M. The rheological properties of asphaltic bitumens. J Inst Pet 22 (1936) 414-440
192. Von Obermayer A. Ein Beitrag zur Kenntniss der zähflüssigen Körper. Sitzunsberichte Akad Wissenschaften Wien 75 (1877) 665-678
193. Trouton F.T. On the coefficient of viscous traction and its relation to that of viscosity. Proc R Soc (London) 77 (1906) 426-440
194. Schweyer H.E. A pictorial review of asphalt (bitumen) rheology. Proc Assoc Asphalt Paving Techn 43A (1974) 121-157
195. Van Der Poel C. A general system describing the visco-elastic properties of bitumens and its relation to routine test data. J Appl Chem 4 (1954) 221-236
196. Williams M.L., Landel R.F., and Ferry J.D. The temperature dependence of relaxation mechanisms in amorphous polymers and other glass-forming liquids. J Am Chem Soc 77 (1955) 3701-3707
197. Jongepier R., and Kuilman B. The dynamic shear modulus of bitumens as a function of frequency and temperature. Rheol Acta 9 (1970) 102-111
198. Dobson G.R. The dynamic mechanical properties of bitumen. Proc Assoc Asphalt Paving Techn 38 (1969) 123-135
199. Ramond G., and Such C. Bitumes et bitumes-modifiés - Relations structures, propriétés, composition. Bull Liaison Lab Ponts Chaussées 168 (1990) 65-87
200. Edgeworth R., Dalton B.J., and Parnell T. The pitch drop experiment. Eur J Phys 5 (1984) 198-200
201. AASHTO M320. Standard Specification for Performance Graded Asphalt Binder (2004), American Association of State Highway and Transportation Officials, Washington (D.C.)
202. Bouldin M.G., Dongré R.N., Rowe G.M., and Zanzotto L. The future of performance-related binder specifications. Pet Coal 43 (2001) 7-12
203. AASHTO T315. Determining the Rheological Properties of Asphalt Binder Using a Dynamic Shear Rheometer (DSR) (2004), American Association of State Highway and Transportation Officials, Washington (D.C.)
204. AASHTO T313. Determining the Flexural Creep Stiffness of Asphalt Binder Using the Bending Beam Rheometer (BBR) (2004), American Association of State Highway and Transportation Officials, Washington (D.C.)
205. Christensen R.M. Theory of Viscoelasticity. 2nd Ed. (2003) Dover, Mineola (N.Y.)
206. Doï M., and Edwards S.F. The Theory of Polymer Dynamics (1986), Clarendon Press, Oxford
207. Tschoegl N. The Phenomenological Theory of Linear Viscoelastic Behavior (1989), Springer-Verlag, Berlin
208. Stastna J., and Zanzotto L. Linear response of regular asphalts to external harmonic fields. J Rheol 43 (1999) 719-734
209. Buisine J.M., Joly G., Eladlani A., Such C., Farcas F., Ramond G., et al. Thermodynamic behavior and physicochemical analysis of eight SHRP bitumens. Transp Res Rec 1386 (1993) 1-9
210. Garin, D., Propriétés Viscoélastiques des Bitumes, Rapport de DEA (Master Thesis), Institut National des Sciences Appliquées, Lyon (France), 1989.
211. Fritz G., Pechhold W., Willenbacher N., and Wagner N.J. Characterizing complex fluids with high frequency rheology using torsional resonators at multiple frequencies. J Rheol 47 (2003) 303-319
212. Sayir M.B., Hochuli A., and Partl M.N. Measuring the complex viscosity of bitumen in the kHz range with a new resonance rheometer. Proc. Eurobitume Workshop on Performance Related Properties for Bituminous Binders, Luxembourg (1999) paper 106
213. Krieger I.M. Rheology of monodisperse latices. Adv Colloid Interface Sci 3 (1972) 111-136
214. Metzner A.B. Rheology of Suspensions in Polymeric Liquids. J Rheol 29 (1985) 739-775
215. Lethersich W. The mechanical behaviour of bitumen. J Soc Chem Ind 61 (1942) 101-108
216. Huet, C., Etude par une Méthode d'Impédance du Comportement Viscoélastique des Matériaux Hydrocarbonés, Ph. D. Thesis, Univ. Paris (France), 1963.
217. Sayegh, G., Contribution à l'Etude des Propriétés Viscoélastique des Bitumes Purs et des Bétons Bitumineux, Ph. D. Thesis, Univ. Paris (France), 1965.
218. Verney V., Michel A., Planche J.P., and Brûlé B. Influence de la température sur la viscosité complexe d'un bitume routier. Cahiers Rhéol 41 (1990) 811-819
219. Dickinson E.J., and Witt H.P. The dynamic shear modulus of paving asphalts as a function of frequency. Trans Soc Rheol 18 (1974) 591-606
220. Brodnyan J.G., Gaskins F.H., Philippoff W., and Thelen E. The rheology of asphalt. III Dynamic mechanical properties of asphalt. Trans Soc Rheol IV (1960) 279-296
221. Dobson G.R. Rheological models for bitumens and asphalts. Proc. 5th Eurobitume Congress, Stockholm (1993) 240-244
222. Stastna J., Zanzotto L., and Berti J. How good are some rheological models of dynamic material functions of asphalt?. J Assoc Asphalt Paving Techn 66 (1997) 458-477
223. Stastna J., Zanzotto L., and Ho K. Fractional complex modulus manifested in asphalt. Rheol Acta 33 (1994) 344-354
224. Broome D.C. The measurement of the flow properties of bitumens. J Inst Pet Technol 25 (1939) 509-530
225. Romberg J.W., and Traxler R.N. Rheology of asphalt. J Coll Sci 2 (1947) 33-47
226. Sisko A.W. Determination and treatment of asphalt viscosity data. Highway Res Rec 67 (1965) 27-37
227. Cheung C.Y., and Cebon D.A. Experimental study of pure bitumens in tension, compression and shear. J Rheol 41 (1997) 45-73
228. Ossa E.A., Deshpande V.S., and Cebon D. Phenomenological model for monotonic and cyclic behavior of pure bitumen. J Mater Civ Eng 17 (2005) 188-197
229. Shenoy A.V., Saini D.R., and Nadkarni V.M. Rheograms for asphalts from single viscosity measurements. Rheol Acta 21 (1982) 333-339
230. Attané P.A., Soucemarianadin A., Turrel G., and Prud ́homme J.B. Non-linear behavior of asphalts in steady and transient state flow. Rheol Acta 23 (1984) 297-310
231. Walther C. Ueber die Auswertung von Viskositätsangaben. Erdöl und Teer 7 (1931) 382-384
232. Vinogradov G.V., Isayev I., Zolotarev V.A., and Verebskaya E.A. Rheological properties of road bitumens. Rheol Acta 16 (1977) 266-281
233. Maccarrone S., and Tiu C. Rheological properties of service weathered road bitumens. Rheol Acta 27 (1988) 311-319
234. Gokhman L.M. Etude des propriétés rhéologiques des types structuraux de bitume sous déformation statique ou dynamique. Bull Liaison Lab Ponts Chaussées, spécial V (1977) 59-67
235. Roscoe R. The viscosity of suspensions of rigid spheres. Br J Appl Phys 3 (1952) 267-269
236. Lesueur D. La rhéologie du bitume : principes et modification. Rhéologie 2 (2002) 1-30
237. Planche J.P., Lesueur D., Hines M.L., and King G.N. Evaluation of elastomer and plastomer modified bitumens using SHRP binder specifications. Proc. 1st Eurasphalt & Eurobitume Congress, Strasbourg (1996) paper E&E 5-121
238. Memon G.M., and Chollar B.H. Glass transition measurements of asphalts by DSC. J Therm Anal 49 (1997) 601-607
239. Brunsveld L., Folmer B.J.B., Meijer E.W., and Sijbesma R.P. Supramolecular polymers. Chem Rev 101 (2001) 4071-4097
240. Cordier P., Tournilhac F., Soulié-Ziakovic C., and Leibler L. Self-healing and thermoreversible rubber from supramolecular assembly. Nature 451 (2008) 977-980
241. Petsev D.N. Interactions and macroscopic properties of emulsions and microemulsions. In: Binks B.P. (Ed). Modern Aspects of Emulsion Science (1998), Royal Society of Chemistry Ed., Cambridge 329-366
242. Siegmann M.C. Manufacture of asphaltic bitumen. In: Pfeiffer J.P. (Ed). The Properties of Asphaltic Bitumen (1950), Elsevier, Amsterdam 121-154
243. Karlsson R., and Isacsson U. Laboratory studies of diffusion in bitumen using markers. J Mater Sci 38 (2003) 2835-2844
244. Karlsson R., Isacsson U., and Ekblad J. Rheological characterisation of bitumen diffusion. J Mater Sci 42 (2007) 101-108
245. Herrington P.R., Wu Y., and Forbes M.C. Rheological modification of bitumen with maleic anhydride and dicarboxylic acids. Fuel 78 (1999) 101-110
246. Orange G., Dupuis D., Martin J.V., Farcas F., Such C., and Marcant B. Chemical modification of bitumen through polyphosphoric acid: properties-microstructure relationship. Proc. 3rd Eurasphalt & Eurobitume Congress, vol. 1, Vienna (2004) 733-745
247. Bonemazzi F., and Giavarini C. Shifting the bitumen structure from sol to gel. J Pet Sci Eng 22 (1999) 17-24
248. Baumgardner G.L., Masson J.F., Hardee J.R., Menapace A.M., and Williams A.G. Polyphosphoric acid modified asphalt: proposed mechanisms. J Assoc Asphalt Paving Technol 74 (2005) 283-305
249. Brahimi B., Ait-Kadi A., Ajji A., Jerome R., and Fayt R. Rheological properties of copolymer modified polyethylene/polystyrene blends. J Rheol 35 (1991) 1069-1091
250. Graebling D., Müller R., and Palierne J.F. Linear viscoelastic behavior of some incompatible polymer blends in the melt. Interpretation of data with a model of emulsion of viscoelastic liquids. Macromol. 26 (1993) 320-329
251. Cassagnau P., Espinasse I., and Michel A. Viscoelastic and elastic behavior of polypropylene and ethylene copolymer blends. J Appl Polym Sci 58 (1995) 1393-1399
252. Lesueur D., Gérard J.F., Claudy P., Létoffé J.M., Planche J.P., and Martin D. Polymer-modified asphalts as viscoelastic emulsions. J Rheol 42 (1998) 1059-1074
253. Palierne J.F. Linear rheology of viscoelastic emulsions with interfacial tension, Rheol Acta. Rheol Acta 30 (1990) 204-214 (see also Palierne J.-F., Erratum to linear rheology of viscoelastic emulsions with interfacial tension. Rheol Acta 1991;30;497)
254. Einstein, A., Eine neue Bestimmung der Moleküldimensionen, Ann. Physik 19 (1906) 289-306 (see also Einstein A., Berechtigung zu meiner Arbeit : Eine neue Bestimmung der Moleküldimensionen, Ann. Physik 24 (1911) 591-592).
255. Coussot P. Rheometry of Pastes, Suspensions and Granular Materials (2005), Wiley and Sons, New-York
256. Landau L., and Lifschitz E. Fluid Mechanics (1958), Pergamon Press, Oxford (England)
257. Fröhlich H., and Sack R. Theory of the rheological properties of dispersions. Proc R Soc (London) A185 (1946) 415-430
258. Goddard J.D., and Miller C. Nonlinear effect in the rheology of dilute suspensions. J Fluid Mech 28 (1967) 657-673
259. Roscoe R. On the rheology of a suspension of viscoelastic spheres in a viscous liquid. J Fluid Mech 28 (1967) 273-293
260. Taylor G.I. The viscosity of a fluid containing small drops of another fluid. Proc R Soc (London) A138 (1932) 41-48
261. Oldroyd J.G. The effect of interfacial stabilizing films on the elastic and viscous properties of emulsions. Proc R Soc (London) A232 (1955) 567-577
262. Lesueur D., Gérard J.F., Martin D., and Planche J.P. Evidence of a hard/soft relaxation in a polymer modified asphalt. C R Acad Sci IIb 325 (1997) 615-620
263. Shepherd P.B. Mineral fillers. In: Hoiberg A.J. (Ed). Bituminous Materials: Asphalts, Tars and Pitches vol. 1 (1964), Interscience Publishers, New York 347-373
264. Kandhal P.S., Linn C.Y., and Parker Jr. F. Characterization tests for mineral fillers related to performance of asphalt paving mixture. NCAT Report 98-2, National Center for Asphalt Technology: Auburn (AL) (1998)
265. Prowell B.D., Zhang J., and Brown E.R. Aggregate Properties and the Performance of Superpave-Designed Hot Mix Asphalt, NCHRP Report 539, Transportation Research Board: Washington (2005)
266. Mitchell J.G., and Lee A.R. The evaluation of fillers for tar and other bituminous surfaces. J Soc Chem Ind 58 (1939) 299-306
267. Rigden D.J. Mineral fillers in bituminous road surfacings: a study of filler/binder systems in relation to filler characteristics. J Soc Chem Ind 66 (1947) 299-309
268. Heukelom W., and Wijga P.W.O. Viscosity of dispersions as governed by concentration and rate of shear. Proc Assoc Asphalt Paving Techn 40 (1971) 418-435
269. Van der Poel C. On the rheology of concentrated dispersions. Rheol Acta 1 (1958) 198-205
270. Lesueur D., Dekker D.L., and Planche J.P. Comparison of carbon black from pyrolized tires to other fillers as asphalt rheology modifiers. Transp Res Rec 1515 (1995) 47-55
271. Fritschy G., and Papirer E. Dynamic-mechanical properties of a bitumen-silica composite. I. Relation with filler content and bitumen-silica interfacial area. Rheol Acta 18 (1979) 749-755
272. Shashidhar N., and Shenoy A. On using micromechanical models to describe dynamic mechanical behavior of asphalt mastics. Mech Mater 34 (2002) 657-669
273. Shashidhar N., Needham S.P., and Collar B.H. Prediction of the performance of mineral fillers in SMA. J Assoc Asphalt Paving Techn 68 (1999) 222-245
274. Tunnicliff D.G. Binding effect of mineral filler. Proc Assoc Asphalt Paving Techn 36 (1967) 114-154
275. Plancher H., Green E.L., and Petersen J.C. Reduction of oxidative hardening of asphalts by treatment with hydrated lime. Proc Assoc Asphalt Paving Techn 45 (1976) 1-19
276. Wortelboer J.P., Hoppen H.J., Ramond G., and Pastor M. Rheological properties of bitumen/filler mixtures. Proc. 1st Eurasphalt & Eurobitume Congress, Strasbourg (1996) paper E&E 4-079
277. Lesueur D., and Little D. Effect of hydrated lime on the rheology, fracture and ageing of bitumen. Transp Res Rec 1661 (1999) 93-100
278. Acevedo S., Ranaudo M.A., and Escobar G. Adsorption of asphaltenes and resins on organic and inorganic substrates and their correlation with precipitation problems in production well tubing. Fuel 74 (1995) 595-598
279. Craus J., Ishai I., and Por N. Selective sorption in filler-bitumen systems. J Mater Sci 14 (1979) 2195-2204
280. Sato A., and Nishimoto S. Effective reuse of coal ash as civil engineering material. Proc. World of Coal Ash Conference, Lexington (KY), April 11-15, paper 66 (2005)
281. Chen J.S., and Lin K.Y. Mechanism and behavior of bitumen strength reinforcement using fibers. J Mater Sci 40 (2005) 87-95
282. Delaporte B., Di Benedetto H., Chaverot P., and Gauthier G. Linear viscoelastic properties of bituminous materials: from binders to mixes. to appear in. J Assoc Asphalt Paving Technol (2008)
283. Lachihab A., and Sab K. Aggregate composites: a contact based modeling. Comput Mater Sci 33 (2005) 467-490
284. Thomson D.C. Rubber modifiers. In: Hoiberg A.J. (Ed). Bituminous Materials: Asphalts, Tars and Pitches vol. 1 (1964), Interscience Publishers, New York 375-414
285. Polacco G., Stastna J., Biondi D., Antonelli F., Vlachovicova Z., and Zanzotto L. Rheology of asphalts modified with glycidylmethacrylate functionalized polymers. J Colloid Interface Sci 280 (2004) 366-373
286. California Department of Transportation, Asphalt Rubber Usage Guide, Sacramento: Caltrans, 2003.
287. Rouse M.W. Production, identification and application of crumb-rubber modifiers for asphalt. In: Usmani A.M. (Ed). Asphalt Science and Technology (1997), Marcel Dekker, New York 385-442
288. Kim S., Loh S.W., Zhai H., and Bahia H. Advanced characterization of crumb-rubber modified asphalts, using protocols developed for complex binders. Transp Res Rec 1767 (2001) 15-24
289. Brûlé B., and Druon M. La microscopie de fluorescence appliquée à l'observation de bitumes thermoplastiques. Bull Liaison Lab Ponts Chaussées 79 (1975) 11-14
290. Kraus G. Modification of asphalt by block polymers of butadiene and styrene. Rubber Chem Technol 55 (1982) 1389-1402
291. Brion, Y. and B. Brûlé, Etude des Mélanges Bitumes-Polymères. Composition - Structure - Propriétés, Rapport PC-6, LCPC Eds, Paris (France), 1986.
292. Bouldin M.G., Collins J.H., and Berker A. Rheology and microstructure of polymer/asphalt blends. Rubber Chem Technol 64 (1990) 577-600
293. Hesp S.A.M., and Woodhams R.T. Stabilization mechanisms in polyolefin-asphalt emulsions. In: Wardlaw, and Shuler (Eds). Polymer-Modified Asphalt Binders (1992), ASTM Publications, Philadelphia 1-19
294. Bonemazzi F., Braga V., Corrieri R., Giavarini C., and Sartori F. Characteristics of polymers and polymer-modified binders. Transp Res Rec 1535 (1996) 36-47
295. Fawcett A.H., and McNally T. Blends of bitumen with various polyolefins. Polymer 41 (2000) 5315-5326
296. Tadros T.F., and Vincent B. Emulsion stability, in encyclopedia of emulsion science, vol. 1. In: Becher P. (Ed). Basic Theory (1983), Marcel Dekker, New York 129-285
297. Gazeau, S, Liants Bitumes-Copolymères d'Éthylène, Ph. D. Thesis: Univ. L. Pasteur Strasbourg (France), 1996.
298. Coran A.Y. Thermoplastic elastomers based on elastomer-thermoplastic blends dynamically vulcanized. In: Legge, Holden, and Schroeder (Eds). Thermoplastic elastomers (1987), Hanser Publishers, München 133-161
299. Hesp S.A.M., and Woodhams R.T. In: Wardlaw, and Shuler (Eds). Stabilization mechanisms in polyolefin-asphalt emulsions in Polymer-Modified Asphalt Binders (1992), ASTM Publications, Philadelphia 1-19
300. Laval C., and Quivoron C. Mise en évidence d'une corrélation entre le rapport hydrophile/lipophile des résines époxydes et leur compatibilité avec le bitume routier. C R Acad Sci IIc 256 (1973) 743-746
301. Van Beem E.J., and Brasser P. Bituminous binders of improved quality containing Cariflex thermoplastic rubber. J Inst Pet 59 (1973)
302. Laval, C. and B. Brûlé, Etude Expérimentale de la Compatibilité de Résines Epoxydes avec le Bitume. Application à la Prévision de Systèmes Compatibles, Rapport de Recherche LCPC 40, LCPC Eds, Paris (France), 1974.
303. In: Holmberg K., Jönsson B., Kronberg B., et al. (Eds). Surfactants and Polymers in Aqueous Solution. 2nd Ed. (2003), John Wiley and Sons, Chichester (England)
304. Brûlé B. Polymer-modified asphalt cements used in the road construction industry: basic principles. Transp Res Rec 1535 (1996) 48-53
305. Rodriguez F. Principles of Polymer Systems, 2nd Ed., Chemical Engineering Series (1982), McGraw-Hill, New York
306. Bouldin M.G., Collins J.H., and Berker A. Rheology and microstructure of polymer/asphalt blends. Rubber Chem Technol 64 (1990) 577-600
307. Arrambide J., and Duriez M. Liants Routiers et Enrobés (1959), Dunod, Paris
308. García-Morales M., Partal P., Navarro F.J., Martinez-Boza F.J., and Gallegos C. Process rheokinetics and microstructure of recycled EVA/LDPE-modified bitumen. Rheol Acta 45 (2006) 513-524
309. Dony, A., Liants Bitumes-Polymères. De la Fabrication à la Mise en Œuvre des Enrobés : Influence de la Nature du Bitume sur leurs Propriétés Mécaniques, leur Micromorphologie et leur Stabilité Thermique, Rapport CR-15, LCPC Eds, Paris (France), 1991
310. Fawcett A.H., McNally T., McNally G.M., Andrews F., and Clarke J. Blends of bitumen with polyethylenes. Polymer 40 (1999) 6337-6349
311. Sakellariou P. Phase separation and morphology in polymer modified colloids. Prog Org Coat 33 (1997) 183-189
312. De Hoog E.H.A., Kegel W.K., Van Blaaderen A., et al. Direct observation of crystallization and aggregation in a phase-separating colloid-polymer suspension. Phys Rev E 64 (2001) 021407
313. Champion, L., Etude des Comportements Rhéologique et Mécanique de Liants Routiers Purs ou Modifiés par un Polymère, Ph D. Thesis, INSA Lyon (France), 1999.
314. Fetters L.J., Lohse D.J., Richter D., Witten T.A., and Zirkel A. Connection between polymer molecular weight, density, chain dimensions and melt viscoelastic properties. Macromol. 27 (1994) 4639-4647
315. Baumgärtel M., and Willenbacher N. The relaxation of concentrated polymer solutions. Rheol Acta 35 (1996) 168-185
316. Létoffé J.M., Champion-Lapalu L., Martin D., Planche J.P., Gérard J.F., and Claudy P. Analyse thermique de bitumes routiers modifiés par des polymères. Bull Liaison Lab Ponts Chaussées 229 (2000) 13-20
317. Graessley W.W., and Edwards S.F. Entanglement interactions in polymers and the chain contour concentration. Polymer 22 (1981) 1329-1334
318. Hadrzynski F., and Such C. Modélisation du comportement rhéologique des bitumes polymères. Le modèle autocohérent. Bull Liaison Lab Ponts Chaussées 214 (1998) 3-18
319. Isacsson U., and Lu X. Characterization of bitumens modified with SEBS, EVA and EBA polymers. J Mater Sci 34 (1999) 3737-3745
320. Durand, A., Relations Entre la Composition des Bitumes et leurs Propriétés Physico-Chimiques - Application à la Formulation de Liants Modifiés Bitume/EVA, Ph. D. Thesis, Univ. Rouen (France), 1997.
321. Langhammer G., and Nestler L. Grenzflächenspannung zwischen entmischten Polymerlösungen. Makrom Chem 88 (1965) 179-187
322. Broseta D., Leibler L., Ould Kaddour L., and Strazielle C. A theoretical and experimental study of interfacial tension of immiscible polymer blends in solution. J Chem Phys 87 (1987) 7248-7256
323. Ponniah J.E., Cullen R.A., and Hesp S.A.M. Fracture energy specifications for modified asphalts, ACS Div. Fuel Chem 41 (1996) 1317-1321
324. Hesp S.A.M., Haijun C., and Darren T. Low-temperature performance testing of polymer-modified asphalt concrete. Proc. 2nd Eurasphalt and Eurobitume Congress 1, Barcelona (2000) 320-326
325. Anderson D.A., Marasteanu M.O., Champion-Lapalu L., Martin D., Planche J.P., and Le Hir Y. Low-temperature thermal cracking of asphalt binders as ranked by strength and fracture properties. Proc. 2nd Eurasphalt and Eurobitume Congress 1, Barcelona (2000) 7-15
326. Guglielminetti E. La guerre contre la poussière. La Nature 1602 (1904) 151-154
327. Brosseaud Y., and Saint-Jacques M. Coloured bituminous wearing courses in France, overview of uses. Proc. 3rd Eurasphalt & Eurobitume Congress, vol. 1, Vienna (2004) 43-53 paper 289
328. Martinez-Boza F., Partal P., Conde B., and Gallegos C. Influence of temperature and composition on the linear viscoelastic properties of synthetic binders. Energy Fuels 14 (2000) 131-137
329. Ballié M., and Delcroix T. Innovative plant-based binder for road mixes and pavement surfacings. Proc. 23rd PIARC (World Road Association) meeting, Paris (2007)
330. Partal P., Martinez-Boza F., Conde B., and Gallegos C. Rheological characterisation of synthetic binders and unmodified bitumens. Fuel 78 (1999) 1-10
331. Martinez-Boza F., Partal P., Navarro F.J., and Gallegos C. Rheology and microstructure of asphalt binders. Rheol Acta 40 (2001) 135-141
332. Martinez-Boza F., Partal P., Conde B., and Gallegos C. Steady-state flow behaviour of synthetic binders. Fuel 80 (2001) 357-365