Modification of platinum surfaces by spontaneous deposition: Methanol oxidation electrocatalysis

International Journal of Hydrogen Energy

Volumn 33, Issue 23, 2008, Pages 7048-7061

  MacDonald, J P ^a   Gualtieri, B ^a   Runga, N ^a   Teliz, E ^a   Zinola, C F ^a  

^a UNIVERSIDAD DE LA REPÚBLICA   (Uruguay)

Author keywords

Electrocatalysis; Platinum; Ruthenium; Spontaneous deposition; Tin

Indexed keywords

ACIDS; ADSORBATES; ADSORPTION; ANODIC OXIDATION; CARBON MONOXIDE; CATALYSIS; CHEMICAL OXYGEN DEMAND; DISSOLUTION; ELECTRIC BATTERIES; ELECTROCATALYSIS; ELECTROCHEMISTRY; ELECTROLYSIS; FUEL CELLS; INFRARED SPECTROSCOPY; METAL RECOVERY; METALLIC COMPOUNDS; METHANOL; METHANOL FUELS; OXIDATION; PLATINUM; PLATINUM METALS; RUTHENIUM; SPECTROSCOPIC ANALYSIS; STRIPPING (DYES); TIN; TITANIUM COMPOUNDS;

ACID MEDIAS; ANODIC STRIPPING; DISSOLUTION PROCESSES; ELECTROCATALYTIC REACTIONS; IN SITU INFRARED SPECTROSCOPIES; METHANOL ADSORPTIONS; METHANOL FUEL CELLS; METHANOL OXIDATIONS; PLATINUM SURFACES; POLARIZATION CURVES; POLARIZED LIGHTS; POLYCRYSTALLINE SURFACES; POTENTIOSTATIC; PT(111); SPECTROSCOPIC TECHNIQUES; SPONTANEOUS DEPOSITION; SPONTANEOUS DEPOSITIONS; STEADY STATES; SURFACE DISTRIBUTIONS; TAFEL SLOPES;

PLATINUM ALLOYS;

EID: 56749107213     PISSN: 03603199     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ijhydene.2008.09.008     Document Type: Article

References (61)

1. Herrero E., Buller L.J., and Abruña H.D. Underpotential deposition at single crystal surfaces of Ag, Au, Pt and other materials. Chem Rev 101 (2001) 1897-1930
2. García M.F., Sieben J.M., Pilla A.S., Duarte M.E., and Mayer C.E. Methanol/air fuel cells: catalytic aspects and experimental diagnostics. Int J Hydrogen Energy 33 13 (2008) 3517-3521
3. Jha N., Reddy A.L.M., Shaijumon M.M., Rajalakshmi N., and Ramaprabhu S. Pt-Ru/multi-walled carbon nanotubes as electrocatalysts for direct methanol fuel cell. Int J Hydrogen Energy 33 1 (2008) 427-433
4. Bonesi A., Garaventa G., Triaca W.E., and Castro Luna A.M. Synthesis and characterization of new electrocatalysts for ethanol oxidation. Int J Hydrogen Energy 33 13 (2008) 3499-3501
5. Herrero E., Franaszczuk K., and Wieckowski A. Electrochemistry of methanol at low index crystal planes of platinum: an integrated voltammetric and chronoamperometric study. J Phys Chem 98 (1994) 5074-5083
6. Xia X.H., Liess H.-D., and Iwasita T. Early stages in the oxidation of ethanol at low index single crystal platinum electrodes. J Electroanal Chem 437 1-2 (1997) 233-240
7. Cleghorn S.J.C., Ren X., Springer T.E., Wilson M.S., Zawodzinski C., Zawodzinski T.A., et al. Pem fuel cells for transportation and stationary power generation applications. Int J Hydrogen Energy 22 12 (1997) 1137-1144
8. Batista E.A., Malpass G.R.P., Motheo A.J., and Iwasita T. New mechanistic aspects of methanol oxidation. J Electroanal Chem 571 2 (2004) 273-282
9. Gasteiger H.A., Marković N., Ross Jr. P.N., and Cairns E.J. Electro-oxidation of small organic molecules on well-characterized Pt-Ru alloys. Electrochim Acta 39 11-12 (1994) 1825-1832
10. Herrero E., Franaszczuk K., and Wiecskowski A. A voltammetric identification of the surface redox couple effective in methanol oxidation on a ruthenium-covered platinum (110) electrode. J Electroanal Chem 361 1-2 (1993) 269-273
11. Chrzanowski W., and Wieckowski A. Surface structure effects in platinum/ruthenium methanol oxidation electrocatalysis. Langmuir 14 (1998) 1967
12. Gurau B., Viswanathan R., Liu R., Lafrenz T.J., Ley K.L., Smotkin E.S., et al. Structural and electrochemical characterization of binary, ternary, and quaternary platinum alloy catalysts for methanol electro-oxidation. J Phys Chem B 102 (1998) 9997-10003
13. Gerischer H., Kolb D.M., and Sass J.K. The study of solid surfaces by electrochemical methods. Adv Phys 27 (1978) 437-498
14. Friedrich K.A., Geyzers K.P., Dickinson A.J., and Stimming U. Fundamental aspects in electrocatalysis: from the reactivity of single-crystals to fuel cell electrocatalysts. J Electroanal Chem 524-525 (2002) 261-272
15. Rhee C.K., Wakisaka M., Tolmachev Y.V., Johnston C.M., Haasch R., Attenkofer K., et al. Osmium nanoislands spontaneously deposited on a Pt(111) electrode: an XPS, STM and GIF-XAS study. J Electroanal Chem 554-555 (2003) 367-378
16. Crown A., and Wieckowski A. Structure and reactivity of ruthenium- and osmium-modified Pt(100) and Pt(110) single crystal substrates. Phys Chem Chem Phys 3 (2001) 3290
17. Frelink T., Visscher W., and van Veen J.A.R. Measurement of the Ru surface content of electrocodeposited PtRu electrodes with the electrochemical quartz crystal microbalance: implications for methanol and CO electrooxidation. Langmuir 12 15 (2006) 3702-3708
18. Liu R., Iddir H., Fan Q., Hou G., Bo A., Ley K.L., et al. Potential-dependent infrared absorption spectroscopy of adsorbed CO and X-ray photoelectron spectroscopy of arc-melted single-phase Pt, PtRu, PtOs, PtRuOs, and Ru electrodes. J Phys Chem B 104 (2000) 3518-3531
19. Hubbard A.T., Stickney J.L., Rosasco S.D., Soriaga M.P., and Song D. Electrodeposition on a well-defined surface: silver on Pt(111)(√7 × √7)R19.1°-I. J Electroanal Chem 150 (1983) 165-180
20. Thiel P.A., and Madey T.E. The interaction of water with solid surfaces: fundamental aspects. Surf Sci Rep 7 (1987) 211-385
21. Marković N.M., and Ross Jr. P.N. Surface science studies of model fuel cell electrocatalysts. Surf Sci 45 (2002) 117-229
22. Kolb D.M. In: Gerisher H., and Tobias C.W. (Eds). Advances in electrochemistry and electrochemical engineering vol. 11 (1978), Wiley-Interscience 125
23. McBreen J., and Mukerjee S. In situ X-ray absorption studies of a Pt-Ru electrocatalyst. J Electrochem Soc 142 (1995) 3399
24. Adzić R.R. In: Gerisher H., and Tobias C.W. (Eds). Advances in electrochemistry and electrochemical engineering vol. 13 (1984), Wiley-Interscience
25. Lin W.F., Zei M.S., Eiswirth M., Ertl G., Iwasita T., and Vielstich W. Electrocatalytic activity of Ru-modified Pt(111) electrodes toward CO oxidation. J Phys Chem B 103 (1999) 6957-6967
26. Petrii O.A., Podlovchenko B.I., Frumkin A.N., and Lal H. The behaviour of platinized-platinum and platinum-ruthenium electrodes in methanol solutions. J Electroanal Chem 10 4 (1965) 253-269
27. Bockris J.O.M., and Wroblowa H. Electrocatalysis. J Electroanal Chem 7 (1964) 428-451
28. Watanabe M., and Motoo S. Electrocatalysis by ad-atoms: part II and III. J Electroanal Chem 60 3 (1975) 268-283
29. Petrii O.A., and Kalinin V.D. Electrocatalytic properties of electrodeposited osmium. Russ J Electrochem 35 6 (1999) 627-634
30. Janssen M.M.P., and Moolhuysen J. Binary systems of platinum and a second metal as oxidation catalysts for methanol fuel cells. Electrochim Acta 21 11 (1976) 869-878
31. Davies J.C., Hayden B.E., Pegg D.J., and Rendall M.E. The electro-oxidation of carbon monoxide on ruthenium modified Pt(111). Surf Sci 496 1-2 (2002) 110-120
32. Waszczuk P., Solla-Gullón J., Kim H.S., Tong Y.Y., Montiel V., Aldaz A., et al. Methanol electrooxidation on platinum/ruthenium nanoparticle catalysts. J Catal 203 (2001) 1-6
33. Kolb D.M. An atomistic view of electrochemistry. Surf Sci 500 1-3 (2002) 722-740
34. Iwasita T., Hoster H., John-Anacker A., Lin W.F., and Vielstich W. Methanol oxidation on PtRu electrodes. Influence of surface structure and Pt-Ru atom distribution. Langmuir 16 2 (2000) 522-529
35. Waszczuk P., Barnard T., Rice C., Masel R.I., and Wieckowski A. Novel nanoparticle catalyst for electrooxidation of formic acid. Electrochem Commun 4 (2002) 599-603
36. Bonilla S.H., Zinola C.F., Rodríguez J., Díaz V., Ohanian M., Martínez S., et al. Catalytic effects of ruthenium and osmium spontaneous deposition on platinum surfaces toward methanol oxidation. J Colloid Interface Sci 288 2 (2005) 377-386
37. Spinacé E.V., Neto A.O., and Linardi M. Electro-oxidation of methanol and ethanol using PtRu/C electrocatalysts prepared by spontaneous deposition of platinum on carbon-supported ruthenium nanoparticles. J Power Sources 129 2 (2004) 121-126
38. Colom F., and González-Tejera M.J. Electro-oxidation of ethylene glycol on PtRu/C and PtSn/C electrocatalysts prepared by alcohol-reduction process. J Appl Electrochem 35 2 (2005) 193-198
39. Massong H., Tillmann S., Langkau T., Abd El Meguid E.A., and Baltruschat H. On the influence of tin and bismuth UPD on Pt(111) and Pt(332) on the oxidation of CO. Electrochim Acta 44 8-9 (1998) 1379-1388
40. Stamenkovic V.R., Arenz M., Lucas C.A., Gallagher M.E., Ross P.N., and Marković N.M. Surface chemistry on bimetallic alloy surfaces: adsorption of anions and oxidation of CO on Pt3Sn(111). J Am Chem Soc 125 (2003) 2736
41. Crown A., de Moraes I., and Wieckowski A. Scanning tunneling microscopy investigations of ruthenium- and osmium-modified Pt(100) and Pt(110) single crystal substrates. Phys Chem Chem Phys 3 (2001) 3290-3296
42. Rodríguez F., Morante T., and Cabrera C.R. Sequential and simultaneous electrodeposition of Pt-Ru electrocatalysts on a HOPG substrate and the electro-oxidation of methanol in aqueous sulfuric acid. J Electroanal Chem 571 1 (2004) 15-26
43. Li Y., and Koel B.E. Structural studies of Sn/Pt(100) surfaces: conditions for alloy formation. Surf Sci 330 2 (1995) 193-206
44. Gallis C., Legrand B., and Tréglia G. On the "exotic" behaviour of the Pt-Sn system. Surf Sci 377-379 (1997) 1033-1037
45. Santos M.C., and Bulhões L.O.S. The underpotential deposition of Sn on Pt in acid media. Cyclic voltammetric and electrochemical quartz crystal microbalance studies. Electrochim Acta 48 18 (2003) 2607-2614
46. Gorstema F.P., and Cobble J.W. The chemistry of ruthenium. I. Ruthenyl and the nature of Ru(IV) in perchloric acid solutions. J Am Chem Soc 83 (1961) 4317
47. Morimoto Y., and Yeager E.B. CO oxidation on smooth and high area Pt, Pt-Ru and Pt-Sn electrodes. J Electroanal Chem 441 1-2 (1998) 77-81
48. Morimoto Y., and Yeager E.B. Comparison of methanol oxidations on Pt, Pt vertical bar Ru and Pt vertical bar Sn electrodes. J Electroanal Chem 444 1 (1998) 95-100
49. Abd El Meguid E.A., Berenz P., and Baltruschat H. Step decoration at Pt single crystal electrodes: role of the anion. J Electroanal Chem 467 1-2 (1997) 50-59
50. Clavilier J., Faure R., Guinet G., and Durand R. Preparation of monocrystalline Pt microelectrodes and electrochemical study of the plane surfaces. J Electroanal Chem 107 1 (1979) 205-209
51. Stalnionis G., Tamašauskaité-Tamašiunaité L., Pautieniené V., Sudavičius A., and Jusys Z. Modification of a Pt surface by spontaneous Sn deposition for electrocatalytic applications. J Solid State Electrochem 8 11 (2004) 892-899
52. Zinola C.F., Rodríguez J., and Obal G. Kinetics of molecular oxygen electroreduction on platinum modified by tin underpotential deposition. J Appl Electrochem 31 12 (2001) 1293-1300
53. Xia X.H. New insights into the influence of upd Sn on the oxidation of formic acid on platinum in acidic solution. Electrochim Acta 45 7 (1999) 1057-1066
54. Martínez S., and Zinola C.F. Surface metal modifiers for methanol electrooxidation on platinum, silver and mercury. J Solid State Electrochem 11 7 (2007) 947-957
55. Ohanian M., and Zinola C.F. The anode efficiency in methanol direct fuel cells-a chronoamperometric approach. J Power Sources 168 1 (2007) 307-322
56. Watanabe M., and Motoo S. Electrocatalysis by ad-atoms: part I. J Electroanal Chem 60 (1975) 259-267
57. Reddington E., Sapienza A., Gurau B., Viswanathan R., Sarangapani S., Smotkin E.S., et al. Combinatorial electrochemistry: a highly parallel, optical screening method for discovery of better electrocatalysts. Science 280 5370 (1998) 1735-1737
58. Inada R., Shimazu K., and Kita H. Analysis of time-dependent kinetics for the oxidation of methanol on a platinum electrode and reaction mechanism. J Electroanal Chem 277 1-2 (1990) 315-326
59. Kauranen P.S., Skou E., and Munk J. Kinetics of methanol oxidation on carbon-supported Pt and Pt + Ru catalysts. J Electroanal Chem 404 1 (1996) 1-13
60. Frelink T., Visscher W., Cox A.P., and van Veen J.A.R. Ellipsometry and DEMS study of the electrooxidation of methanol at Pt and Ru- and Sn-promoted Pt. Electrochim Acta 40 10 (1995) 1537-1543
61. von Schenck H., Janin E., Tjernberg O., Svensson M., and Göthelid M. CO bonding on tin modified Pt(110)-(1 × 2). Surf Sci 526 1-2 (2003) 184-192