Isoprene and C5 Olefins Production by Oxidative Dehydrogenation of Isopentane

Industrial and Engineering Chemistry Research

Volumn 47, Issue 21, 2008, Pages 8037-8042

  Valenzuela, Rita X ^b   Muñoz Asperilla, José M ^c   Corberán, Vicente Cortés ^a  

^a INSTITUTO DE CATÁLISIS Y PETROLEOQUÍMICA   (Spain)

^b CIEMAT   (Spain)

^c Rotating Equipment Department   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

BUTENES; CATALYSIS; HYDROCARBONS; OLEFINS; ORGANIC COMPOUNDS; OXYGEN; PETROCHEMICALS;

DIRECT CONVERSIONS; FEED COMPOSITIONS; ISOPENTANE; OLEFINS PRODUCTIONS; OXIDATIVE DEHYDROGENATIONS; OXIDE CATALYSTS; PETROCHEMICAL PROCESSES; REACTION CONDITIONS; REACTION PARAMETERS; RESIDENCE TIMES;

DEHYDROGENATION;

EID: 56749100721     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie800756p     Document Type: Article

References (31)

1. Mukhlenov, I. P.; Dobkina, E. I.; Deryuzhkina, V. I.; Soroko, V. E. Tekhnologiya Katalizatorov (Technology of Catalysts); Khimiya: Leningrad, 1979.
2. Kolesnikov, I. M., Kataliz i Proizvodstvo Katalizatorov (Catalysis and Manufacture of Catalysts); Tekhnika TUMA GRUPP: Moscow, 2004.
3. Saítman, W. Isoprene. In Kirk-Othmer Concise Encyclopedia of Chemical Technology; Grayson, M., Ed.; John Wiley and Sons: New York, 1985; pp 674-675.
4. (a) Gusman, T. Ya.; Serebryakov, B. R.; Dalin, M. A. Oxidative dehydrogenation of isoamylenes on bismuth molybdates. Khim. Tekh. Topi. Masel 1967, 12, 1.
5. (b) Lisova, N. N.; Shapolova, L. P.; Luk'yanenko, V. P. Effect of method of zinc-titanium catalyst preparation on its catalytic properties in oxidative dehydrogenation of isopentane. Neftepererab. Neftekhim. (Kiev) 1984, 27, 15.
6. (a) Kuznetzov, A. V. Oxidative dehydrogenation of isopentane on zeolite catalysts. Khim. Khim. Tekhnol. Polim. Org. Sint., 1973, 49, CA 82: 98416f.
7. (b) Okel'son, I. I.; Kuznetsov, A. V. Effect of cation nature on zeolite activity in the oxidative dehydrogenation of isopentane. Vpor. Kinetiki i Kataliza 1973, (1), 68.
8. 2: Nikonov, V. I.; Nikonova, M. M.; Adel'son. S. V.; Liakumovich, A. G.; Rozenoer, S. S. Preparation of isoprene by oxidative dehydrogenation of isopentane. Nov. Neftekhim. Prod. Protsessy 1971, 6, CA 81:38601g.
9. (b) For HC1: Adel'son, S. V.; Yudinson, R. N.; Lebedeva, N. I.; Paushkin, Y. M. Oxidative dehydrogenation of isopentane in the presence of hydrogen chloride. Khim. Prom. (Moscow) 1971, 47, 174.
10. 2: Sterligov, O. D.; Arinich, I. M; Dudukina, T. V. Oxidative dehydrogenation of isopentane in presence of bromine. Izv. Akad. Nauk SSSR. Ser. Khim. 1971, (12), 2833.
11. Sterligov, O. D.; Arinich, I. M.; Dudukina, T. V. Oxidative dehydrogenation of isopentane in presence of hydrobromic acid. Izv. Akad. Nauk SSSR, Ser. Khim. 1972, (1), 1959.
12. Cichowski, R. S. Catalytic oxidative dehydrogenation of hydrocarbon feedstocks, U.S. Patent 3, 758,609, 1973.
13. Cichowski, R. S. Oxidative dehydrogenation catalyst, U.S. Patent 3,862,910, 1975.
14. Colling, P. M.; Dean, J. C. Metal ferrites as catalysts for oxidative dehydrogenation of organic compounds, U.S. Patent 3,567,793, 1971.
15. Manning, H. E. Oxidative dehydrogenation utilizing manganese ferrite, U.S. Patent 3,671,606, 1972.
16. Manning, H. E. Chromium modified manganese ferrite oxidative dehydrogenation catalysts, U.S. Patent 4,026,920, 1977.
17. Walker, D. W.; Farha, F. E. Oxidative dehydrogenation catalyst, U.S. Patent 4,010,114, 1977.
18. Cichowski, R. S. Cobalt-, iron-, phosphorus- and oxygen-containing dehydrogenation catalysts, U.S. Patent 3,784,483, 1974.
19. Tsailingold, A. L.; Pilipenko, F. S.; Levin, V. A.; Vemova, T. P.; Stepanov, G. A.; Bashin, A. N.; Sivotkin, B. V.;, Kozin, V. V.; Basner, M. E. Mono- and diolefin hydrocarbons, Br. Patent 1,363,331, 1972.
20. Kung, H. H.; Chaar, M. A. Oxidative dehydrogenation of alkanes to unsaturated hydrocarbons, U.S. Patent 4,777,319, 1988.
21. 7. J. Catal. 1993, 140, 226.
22. Mamedov, E. A.; Cortés Corberán, V. Oxidative dehydrogenation of lower paraffins on vanadium-oxide-based catalysts: The present state and outlooks-A review. Appl. Catal., A 1995, 127, 1.
23. Centi, G.; Lopez-Nieto, J. M.; Pinelli, D.; Trifiro, F. Synthesis of phthalic and maleic anhydrides from n-pentane. 1. Kinetic analysis of the reaction network. Ind. Eng. Chem. Res. 1989, 28, 400.
24. Korili, S. A.; Ruiz, P.; Delmon, B. Oxidative dehydrogenation of n-pentane on magnesium vanadate catalysts. Catal. Today 1996, 32, 229.
25. Ozkan, U. S.; Harris, T. A.; Schilf, B. T. The partial oxidation of C-5 hydrocarbons over vanadia-based catalysts. Catal. Today 1997, 33, 57.
26. Cavani, F.; Colombo, A.; Trifiro, F.; Sananes-Schulz, M. T.; Volta, J. C; Hutchings, G. J. The effect of cobalt and iron dopants on the catalytic behavior of V/P/O catalysts in the selective oxidation of n-pentane to maleic and phthalic anhydrides. Catal. Lett. 1997, 43, 241.
27. Dietz, A. G.; Carlsson, A. F.; Schmidt, L. D. Partial oxidation of C-5 and C-6 alkanes over monolith catalysts at short contact times. J. Catal. 1998, 176, 459.
28. Iordanoglou, D. I.; Bodke, A. S.; Schmidt, L. D. Oxygenates and olefins from alkanes in a single-gauze reactor at short contact times. J. Catal. 1999, 187, 400.
29. Rizayev, R.G.; Talyshinskii, R. M.; Seifullareva, J. M.; Guseinova, E. M.; Panteleyeva, Yu. A.; Mamedov, E. A. Oxidative dehydrogenation of the C-4-C-5 paraffins over vanadium-containing oxide catalysts. In New Developments in Selective Oxidation II; Cortés Corberàn, V.; Vic Bellón, S., Eds.;studies in Surface Science Catalysis 82; Elsevier: Amsterdam, 1994; p 125.
30. Chaar, M.; Patel, D.; Kung, H. H. Selective oxidative dehydrogenation of propane over V-Mg-O catalysts. J. Catal. 1988, 109, 463.
31. Valenzuela, R. X.; Cortés Corberán, V. On the intrinsic activity of vanadium centres in the oxidative dehydrogenation of propane over V- Ca-O and V-Mg-O catalysts. Top. Catal. 2000, 11/12, 153.