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Two pseudoruthenocene complexes incorporating 1,2,4-diazaphospholides have been substantiated to be feasible ligands in the palladium-catalyzed Heck reaction. See: Yorke, J.; Wan, L.; Xia, A.; Zheng, W. Tetrahedron Lett. 2007, 48, 8843.
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Synthetic procedures, analytical and spectroscopic data for 2a, 2b, 3 and 5, crystallographic data for 2a, 3, and 5, and the mechanism for the formation of 3 are contained in the Supporting Information.
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Synthetic procedures, analytical and spectroscopic data for 2a, 2b, 3 and 5, crystallographic data for 2a, 3, and 5, and the mechanism for the formation of 3 are contained in the Supporting Information.
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21
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56649121147
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r = 886.26, monoclinic, space group C2/c, a - 18.82(6) Å, b = 12.99(4) Å, c = 20.37(7) Å, α = γ = 90.00°, β = 102.05(4)°].
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r = 886.26, monoclinic, space group C2/c, a - 18.82(6) Å, b = 12.99(4) Å, c = 20.37(7) Å, α = γ = 90.00°, β = 102.05(4)°].
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