A new organofunctionalized silica containing thioglycolic acid incorporated for divalent cations removal-A thermodyamic cation/basic center interaction

Colloids and Surfaces A: Physicochemical and Engineering Aspects

Volumn 332, Issue 2-3, 2009, Pages 144-149

  Silva, André L P ^a   Sousa, Kaline S ^b   Germano, Ana F S ^a   Oliveira, Vaeudo V ^a   Espínola, José G P ^a   Fonseca, Maria G ^a   Airoldi, Claudio ^b   Arakaki, Tomaz ^a   Arakaki, Luiza N H ^a  

^a FEDERAL UNIVERSITY OF PARAÍBA   (Brazil)

^b UNIVERSITY OF CAMPINAS   (Brazil)

Author keywords

Calorimetric titration; Cation removal; Silica immobilization; Thermodynamic data; Thioglycolic acid

Indexed keywords

ADSORPTION; COBALT; COLLOIDS; COMPLEXATION; COPPER; FLOW INTERACTIONS; GELATION; INFRARED SPECTROSCOPY; NICKEL; NICKEL ALLOYS; POSITIVE IONS; SILANES; SILICA; SILICA GEL; SOLUTIONS; SPECTROSCOPIC ANALYSIS; TITRATION; TRANSITION METALS; VOLUMETRIC ANALYSIS;

AQUEOUS SOLUTIONS; BATCH ADSORPTION PROCESSES; CALORIMETRIC TITRATION; CATION REMOVAL; COBALT CATIONS; DIVALENT CATIONS; DIVALENT COPPERS; ELEMENTAL ANALYSES; HETEROGENEOUS ROUTES; INORGANIC SUPPORTS; LANGMUIR EQUATIONS; MAXIMUM RETENTION CAPACITIES; ORGANIC MOIETIES; ORGANOFUNCTIONALIZED; SILYLATING AGENTS; STANDARD MOLAR GIBBS FREE ENERGIES; THERMODYNAMIC DATA; THERMOGRAVIMETRY; THIOGLYCOLIC ACID; THIOGLYCOLIC ACIDS; TRIMETHOXY SILANES;

OXIDES;

COBALT; COPPER; NICKEL; SILICON DIOXIDE; THIOGLYCOLIC ACID;

ADSORPTION; AQUEOUS SOLUTION; ARTICLE; BATCH PROCESS; CALORIMETRY; CARBON NUCLEAR MAGNETIC RESONANCE; CHEMICAL INTERACTION; COVALENT BOND; ENTHALPY; INFRARED SPECTROSCOPY; PRIORITY JOURNAL; THERMODYNAMICS; THERMOGRAVIMETRY; TITRIMETRY;

EID: 56649085098     PISSN: 09277757     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.colsurfa.2008.09.010     Document Type: Article

References (29)

1. El-Nahhal I.M., and El-Ashgar N.M. A review on polysiloxane-immobilized ligand systems: Synthesis, characterization and applications. J. Organometal. Chem. 692 (2007) 2861-2886
2. Jal P.K., Patel S., and Mishra B.K. Chemical modification of silica surface by immobilization of functional groups for extractive concentration of metal ions. Talanta 62 (2004) 1005-1028
3. Ruiz V.S.O., Petrucelli G.C., and Airoldi C. Inorganic-organic hybrids derived from lamellar acidic kenyiate immobilizations for cation removal at the solid/liquid interface. J. Mater. Chem. 16 6 (2006) 2338-2346
4. Xi F., and Wu J. Preparation of macroporous chitosan layer coated on silica gel and its application to affinity chromatography for trypsin inhibitor purification. React. Funct. Polym. 66 (2006) 682-688
5. Silva Filho E.C., Melo J.C.P., and Airoldi C. Preparation of ethylenediamine-anchored cellulose and determination of thermochemical data for the interaction between cations and basic centers at the solid/liquid interface. Carbohydr. Res. 341 11 (2006) 2842-2850
6. Nguyen V., Yoshida W., and Cohen Y. Graft polymerization of vinylacetate onto silica. J. Appl. Polym. Sci. 87 (2003) 300-310
7. 2 with N-, S-containing ligands for Pb(II) and Cd(II) adsorption. Colloid. Surf. A: Physicochem. Eng. Aspects 320 (2008) 25-35
8. Arakaki L.N.H., Espínola J.G.P., da Fonseca M.G., de Oliveira S.F., de Sousa A.N., Arakaki T., and Airoldi C. Thioglycolic acid grafted onto sílica gel and its properties in relation to extracting cations from ethanolic solution determined by calorimetric technique. J. Colloid. Interface Sci. 273 (2004) 211-217
9. Augusto Filha V.L.S., Wanderley A.F., de Sousa K.S., Espínola J.G.P., da Fonseca M.G., Arakaki T., and Arakaki L.N.H. Thermodynamic properties of divalent cations complexed by ethylenesulfide immobilized on silica gel. Colloid. Surf. A: Physicochem. Eng. Aspects 279 (2006) 64-68
10. Kara H., Ayyildiz H.F., and Topkafa M. Use of aminoprophyl silica-immobilized humic acid for Cu(II) ions removal from aqueous solutions by using a continuously monitored solid phase extraction technique in a column arrangement. Colloid. Surf. A: Physicochem. Eng. Aspects 312 1 (2008) 62-72
11. Blitz I.P., Blitz J.P., Gun'ko V.M., and Sheeran D.J. Functionalized silicas: structural characteristics and adsorption of Cu(II) and Pb(II). Colloid. Surf. A: Physicochem. Eng. Aspects 307 (2007) 83-92
12. Sales J.A.A., and Airoldi C. Calorimetric investigation of metal ions adsorption on 3-glycidoxypropyltrimethylsiloxane + propane-1,3-diamine immobilized on silica gel. Thermochim. Acta 427 (2005) 77-83
13. Price P.M., Clark J.H., and Macquarrie D.J. Modified silicas for clean technology. J. Chem. Soc., Dalton Trans. (2000) 101-110
14. Adam F., and Andas J. Amino benzoic acid modified silica-an improved catalyst for the mono-substituted product in the benzylation of toluene with benzyl chloride. J. Colloid. Interface Sci. 311 (2007) 135-143
15. Dirkland J.J. Development of some stationary phases for reversed-phase high-performance liquid chromatography. J. Chromatogr. A 1060 (2004) 9-21
16. 2 content on the chromatographic performance and high pH of C18 titanized phases. J. Chromatogr. A 114 1 (2006) 45-52
17. Silva C.R., Jardim J.C.S.F., Collins C.H., and Airoldi C. New stationary phases based on silica for high performance liquid chromatography. Quim. Nova 27 2 (2004) 270-276
18. Davis S.S. Biomedical applications of nanotechnology-implications for drug targeting and gene therapy. Trends Biotechnol. 15 (1997) 217-224
19. Kim J., Grate J.W., and Wang P. Nanostructures for enzyme stabilization. Chem. Eng. Sci. 61 (2006) 1017-1026
20. Ahuja T., Mir I.A., Kumar D., and Rajesh. Biomolecular immobilization on conducting polymers for biosensing applications. Biomaterials 28 (2007) 791-805
21. Airoldi C. The weighty potentiality of nitrogenated basic centers in inorganic polymers and biopolymers for cation removal. Quim. Nova 31 1 (2008) 144-153
22. Štandeker S., et al. Adsorption of toxic organic compounds from water with hydrophobic silica aerogels. J. Colloid. Interface Sci. 310 (2007) 362-368
23. Airoldi C., and Arakaki L.N.H. Two independent routes to synthesize identical silicas by grafting ethylenimine or 2-aminoethanethiol, their cation adsorbing abilities, and thermodynamic data. J. Colloid. Interface Sci. 249 (2002) 1-7
24. Arakaki L.N.H., Alves A.P.M., da Silva Filho E.C., da Fosneca M.G., de Oliveira S.F., Espínola J.G.P., and Airoldi C. Sequestration of Cu(II), Ni(II), and Co(II) by ethyleneimine immobilized on silica. Thermochim. Acta 453 (2007) 72-74
25. Fonseca M.G., Oliveira M.M., and Arakaki L.N.H. Removal of cadmium, zinc, manganese and chromium cations from aqueous solutions by a clay mineral. J. Hazard. Mater. B137 1 (2006) 288-292
26. de Sousa K.S., Augusto Filha V.L.S., Pinto V.H.A., da Fonseca M.G., Espínola J.G.P., and Arakaki L.N.H. Chemisorption of divalent cations on a silica gel surface modifield with thioglycolic acid-pH influence and ionic strength. Quim. Nova 30 (2007) 528-534
27. Adamsons A.W. Physical Chemistry of Surfaces. fifth ed. (1990), John Wiley & Sons, New York
28. Sales J.A.A., Petrucelli G.C., Oliveira F.J.V.E., and Airoldi C. Mesoporous silica originating from a gaseous ammonia epoxide ring opening and the thermodynamic data on some divalent cation adsorptions. J. Colloid. Interface Sci. 315 (2007) 426-433
29. Marcus Y. Ion Solvation (1985), John Wiley & Sons Ltd, Great Britain