Facilitated oxygen transport through a Nafion membrane containing cobaltporphyrin as a fixed oxygen carrier

Polymer

Volumn 49, Issue 26, 2008, Pages 5659-5664

  Shoji, Masami ^a   Oyaizu, Kenichi ^a   Nishide, Hiroyuki ^a  

^a WASEDA UNIVERSITY   (Japan)

Author keywords

Facilitated transport; Nafion membrane; Oxygen separation

Indexed keywords

ELECTROLYTIC REDUCTION; GLASS MEMBRANE ELECTRODES; MEMBRANES;

ELECTROCHEMICAL REDUCTIONS; FACILITATED TRANSPORT; GLASSY CARBON ELECTRODES; HYDROPHOBIC DOMAINS; MICROPHASE-SEPARATED STRUCTURE; NAFION MEMBRANE; NITROGEN PERMEABILITY; OXYGEN SEPARATION;

OXYGEN;

CARRIER; COPOLYMER; HYDROPHOBIC PROPERTY; MEMBRANE; OXYGEN; PHASE SEPARATION;

EID: 56349150865     PISSN: 00323861     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.polymer.2008.10.016     Document Type: Article

References (24)

1. Vielstich W., Lamm A., and Gasteiger H.A. Handbook of fuel cells (2003), John Wiley & Sons, Chichester, UK
2. Inukai J., Miyatake K., Takada K., Watanabe M., Hyakutake T., Nishide H., et al. Angew Chem Int Ed 47 (2008) 2792-2795
3. Lauzze K.C., and Chmielewski D.J. Ind Eng Chem Res 45 (2006) 4661-4670
4. Jaouen F., Lindbergh G., and Wiezell K. J Electrochem Soc 150 12 (2003) A1711-A1717
5. Passos R.R., Paganin V.A., and Ticianelli E.A. Electrochim Acta 51 (2006) 5239-5245
6. Chen Z., Holmberg B., Li W., Wang X., Deng W., Munoz R., et al. Chem Mater 18 (2006) 5669-5675
7. Steiger B., and Anson F.C. Inorg Chem 34 (1995) 3355-3357
8. Maldotti A., Andreotti L., Molinari A., Borisov S., and Vasil'ev V. Chem-Eur J 7 (2001) 3564-3571
9. Rhee C.H., Kim H.K., Chang H., and Lee J.S. Chem Mater 17 (2005) 1691-1697
10. Abe T., Fujita T., Sekimoto K., Tajiri A., and Kaneko M. J Mol Catal A Chem 201 (2003) 55-62
11. Nishide H., and Tsuchida E. Polymer complex membranes for gas separation. In: Toshima N. (Ed). Polymer for gas separator (1992), VCH Publishers, New York 183-219
12. Wöhrle D., and Pomogailo A.D. Metal complexes and metals in macromolecules (2003), Wiley-VCH, Berlin
13. Nishide H., Ohyanagi M., Okada O., and Tsuchida E. Macromolecules 19 (1986) 494-496
14. Nishide H., Kawakami H., Toda S., Tsuchida E., and Kamiya Y. Macromolecules 24 (1991) 5851-5855
15. Nishide H., Tsukahara Y., and Tsuchida E. J Phys Chem B 102 (1998) 8766-8770
16. Shentu B., and Nishide H. Ind Eng Chem Res 42 (2003) 5954-5958
17. Kadish K.M., Araullo-McAdams C., Han B.C., and Franzen M.M. J Am Chem Soc 112 (1990) 8364-8368
18. Xue T., Trent J.S., and Osseo-Asare K. J Membr Sci 45 (1989) 261-271
19. Shinohara H., Shibata H., Wöhrle D., and Nishide H. Macromol Rapid Commun 26 (2005) 467-470
20. Yeager E. J Mol Catal 38 (1986) 5-25
21. The CoP-loaded Nafion membrane was incompatible to the pretreatment process, because all prepared membranes changed in size drastically during the process, and exfoliated from the gold plate for the proton conductivity measurement. To uniform the conditions for the membrane preparation, all measurements were performed using the membrane prepared without the pretreatment process. However, the observed qualitative trends (Fig. 2) sufficed to provide insights into the effect of CoP, based on the control experiments which showed the coincidence of the proton conductivity of the pristine membrane after the pretreatment process with that of the literature data.
22. Sakai T., Takenaka H., and Torikai E. J Electrochem Soc 133 (1986) 88-92
23. Shinohara H., Arai T., and Nishide H. Macromol Symp 186 (2000) 135-139
24. Antolini E., Passos R.R., and Ticianelli E.A. Electrochim Acta 48 (2002) 263-270