Gas-phase metathesis of 1-hexene over a WO3/SiO2 catalyst: Search for optimal reaction conditions

Applied Catalysis A: General

Volumn 351, Issue 2, 2008, Pages 137-147

  Lokhat, David ^a   Starzak, Maciej ^a   Stelmachowski, Marek ^b  

^a UNIVERSITY OF KWAZULU NATAL   (South Africa)

^b LODZ UNIVERSITY OF TECHNOLOGY   (Poland)

Author keywords

1 Hexene; Metathesis; Tungsten trioxide catalyst

Indexed keywords

CATALYSIS; HYDROGEN; SILICON COMPOUNDS; SURFACE TREATMENT; TUNGSTEN;

1-HEXENE; BED REACTORS; EXPERIMENTAL CONDITIONS; FEED COMPOSITIONS; FULL FACTORIALS; METATHESIS; NITROGEN PURGES; OPERATING CONDITIONS; OPTIMAL REACTION CONDITIONS; REACTION TEMPERATURES; SPACE TIMES; TRANSFER RESISTANCES; TUNGSTEN TRIOXIDE CATALYST;

CATALYST SELECTIVITY;

EID: 56349124210     PISSN: 0926860X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.apcata.2008.09.006     Document Type: Article

References (27)

1. Mol J.C. J. Mol. Catal. A: Chem. 213 (2004) 39-45
2. Rouhi M. Chem. Eng. News 80 51 (2002) 29-33
3. van Schalkwyk C., Spamer A., Moodley D.J., Dube T., Reynhardt J., and Botha J.M. Appl. Catal. A: Gen. 255 (2003) 121-131
4. Hagen J. Industrial Catalysis-A Practical Approach (1999), Wiley-VCH, Weinheim
5. Mol J.C. Catal. Today 51 (1999) 289-299
6. van Schalkwyk C., Spamer A., Moodley D.J., Dube T., Reynhardt J., Vosloo H.C.M., and Botha J.M. Appl. Catal. A: Gen. 255 (2003) 143-152
7. Gangwal S.K., Fathi-kalajahi J., and Wills G.B. Ind. Eng. Chem. Prod. Res. Dev. 16 (1977) 237-241
8. Moodley D.J., van Schalkwyk C., Spamer A., Botha J.M., and Datye A.K. Appl. Catal. A: Gen. 318 (2007) 155-159
9. Spamer A., Dube T., Moodley D.J., van Schalkwyk C., and Botha J.M. Appl. Catal. A: Gen. 255 (2003) 153-167
10. van Roosmalen A.J., and Mol J.C. J. Catal. 78 (1982) 17-23
11. Antony J. Design of Experiments for Engineers and Scientists (2003), Elsevier, Amsterdam
12. Bartholomew C.H. Appl. Catal. A: Gen. 212 (2001) 17-60
13. Basrur A.G., Patwardhan S.R., and Vyas S.N. J. Catal. 127 (1991) 86-95
14. Barton D.G., Soled S.L., and Iglesia E. Top. Catal. 6 (1998) 87-99
15. Bernholc J., Horsley J.A., Murrell L.L., Sherman L.G., and Soled S. J. Phys. Chem. 91 (1987) 1526-1530
16. Rodríguez-Ramos I., Guerrero-Ruiz A., Homs N., Ramírez de la Piscina P., and Fierro J.L.G. J. Mol. Catal. A: Gen. 95 (1995) 147-154
17. Banks R.L. Top. Curr. Chem. 25 (1972) 40-67
18. van Roosmalen A.J., Koster D., and Mol J.C. J. Phys. Chem. 84 (1980) 3075-3079
19. van Schalkwyk C., Spamer A., Moodley D.J., Dube T., and Botha J.M. Appl. Catal. A: Gen. 255 (2003) 133-142
20. Westhoff R., and Moulijn J.A. J. Catal. 46 (1977) 414-416
21. Luckner R.C., and Wills G.B. J. Catal. 28 (1973) 83-91
22. Venables D.S., and Brown M.E. Thermochim. Acta 291 (1997) 131
23. R.J. Gartside, M.I. Greene, A.M. Khonsari, L.L. Murrell, International Patent WO 02/100535 A1, ABB Lummus, 2002.
24. Spronk R., Dekker F.H.M., and Mol J.C. Appl. Catal. 70 (1991) 295-306
25. Walters F.H., Parker L.R., Morgan S.L., and Deming S.N. Sequential Simplex Optimization (1991), CRC Press, Baton Rouge
26. J. Botha, T.I. Dube, D.J. Moodley, A. Spamer, C. van Schalkwyk, International Patent WO 2004/016351 A1, Sasol Technology (Pty) Limited, 2004.
27. Dwyer C.L. In: Chiusoli G.P., and Maitlis P.M. (Eds). Metal-Catalysis in Industrial Organic Processes (2006), RSC Publishing, Cambridge 201-217