Radiolytic formation of tribromine ion Br3- in aqueous solutions, a system for steady-state dosimetry

Radiation Physics and Chemistry

Volumn 78, Issue 2, 2009, Pages 106-111

  Mirdamadi Esfahani, Malaknaz ^a   Lampre, Isabelle ^a   Marignier, Jean Louis ^a   de Waele, Vincent ^a   Mostafavi, Mehran ^a  

^a UNIVERSITÉ PARIS SUD   (France)

Author keywords

Bromide ion; Oxidation yield; Steady state radiolysis

Indexed keywords

BROMINE; DOSIMETERS; DOSIMETRY; RADIATION CHEMISTRY; RADIOLYSIS; SOLUTIONS;

AQUEOUS SOLUTIONS; BROMIDE ION; HIGH CONCENTRATIONS; IRRADIATION DOSES; RADIOLYTIC FORMATIONS; STEADY-STATE RADIOLYSIS;

IONS;

BROMIDE ION;

AQUEOUS SOLUTION; ARTICLE; DOSIMETRY; GAMMA IRRADIATION; OXIDATION; RADIATION DOSE; RADIOLYSIS;

EID: 56349096364     PISSN: 0969806X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.radphyschem.2008.08.009     Document Type: Article

References (29)

1. - and OH radicals in concentrated HCl and NaCl aqueous solutions. Chem. Phys. Lett. 460 (2008) 461-465
2. - in aqueous solution. J. Phys. Chem. 97 (1993) 4101-4105
3. Beckwith R.C., Wang T.X., and Margerum D.W. Equilibrium and kinetics of bromine hydrolysis. Inorg. Chem. 35 (1996) 995-1000
4. - formation. J. Phys. Chem. 76 (1972) 1815-1818
5. Buxton G.V., Greenstock C.L., Helman W.P., and Ross A.B. Critical review of rate constant of hydrated electrons, hydrogen atoms and hydroxyl radicals in aqueous solution. J. Phys. Chem. Ref. Data 17 (1988) 513-886
6. Cercek B., Ebert M., Gilbert C.W., and Swallow A.J. Pulse radiolysis of aerated aqueous potassium bromide solutions. In: Ebert M., Keene J.P., Swallow A., and Baxendale J.H. (Eds). Pulse Radiolysis (1965), Academic Press, London 83-98
7. reducing in the radiation chemistry of aqueous solutions. Isr. J. Chem. 6 (1968) 421-436
8. - radicals in aqueous solution. Radiat. Phys. Chem. 32 (1988) 319-324
9. Draganic Z.D., and Draganic I.G. Studies on the formation of primary yields of hydroxyl radical and hydrated electron in the γ-radiolysis of water. J. Phys. Chem. 77 (1973) 765-772
10. - in aqueous solutions. Radiat. Phys. Chem. 34 (1989) 753-758
11. Elliot A.J., McCracken D.R., Buxton G.V., and Wood N.D. Estimation of rate constants for near-diffusion-controlled reactions in water at high temperatures. J. Chem. Soc. Faraday Trans. 86 (1990) 1539-1547
12. Hoigné J., Bader H., Haag W.R., and Staehelin J. Rate constants of reactions of ozone with organic and inorganic compounds in water-III. Inorganic compounds and radicals. Water Res. 19 (1985) 993-1004
13. LaVerne J.A., and Pimblott S.M. Diffusion-kinetic modelling of the cooperative effect of scavengers on the scavenged yield of the hydroxyl radical. J. Chem. Soc. Faraday Trans. 89 (1993) 3527-3532
14. Lind J., Shen X., Eriksen T.E., Merényi G., and Eberson L. One-electron reduction of N-bromosuccinimide. Rapid expulsion of a bromine atom. J. Am. Chem. Soc. 113 (1991) 4629-4633
15. Liu Q., Schurter L.M., Muller C.E., Aloisio S., Francisco J.S., and Margerum D.W. Kinetics and mechanisms of aqueous ozone reactions with bromide, sulfite, hydrogen sulfite, iodide, and nitrite ions. Inorg. Chem. 40 (2001) 4436-4442
16. - by OH radicals, studied by pulse radiolysis. J. Phys. Chem. 81 (1977) 1447-1448
17. - and H. J. Phys. Chem. 69 (1965) 1324-1335
18. Matheson M.S., Mulac W.A., Weeks J.L., and Rabani J. The pulse radiolysis of deaerated aqueous bromide solutions. J. Phys. Chem. 70 (1966) 2092-2099
19. Merényi G., and Lind J. Reaction mechanism of hydrogen abstraction by the bromine atom in water. J. Am. Chem. Soc. 116 (1994) 7872-7876
20. Rafi A., and Sutton H.C. Radiolysis of aerated solutions of potasium bromide. Trans. Faraday Soc. 61 (1965) 877-890
21. Scaiano J.C., Barra M., Krzywinski M., Sinta R., and Calabrese G. Laser flash photolysis determination of absolute rate constants for reactions of bromine atoms in solution. J. Am. Chem. Soc. 115 (1993) 8340-8344
22. 2O-saturated aqueous solutions. J. Phys. Chem. 85 (1981) 192-199
23. Schwarz H., and Gill P.S. Diffusion-limited solvated electron reactions in ethanol and water. J. Phys. Chem. 81 (1977) 22-25
24. Sutton H.C., Adams G.E., Boag J.W., and Michael B.D. Radical yields and kinetics in pulse radiolysis of potassium bromide. In: Ebert M., Keene J.P., Swallow A., and Baxendale J.H. (Eds). Pulse Radiolysis (1965), Academic Press, London 61-81
25. Treinin A., and Hayon E. Charge transfer spectra of halogen atoms in water. Correlation of the electronic transition energies of iodine, bromine, chlorine, hydroxyl, and hydrogen radicals with their electron affinities. J. Am. Chem. Soc. 97 (1975) 1716-1721
26. Wagner I., and Stehlow H. On the flash photolysis of bromide ions in aqueous solutions. Ber. Bunsenges. Phys. Chem. 91 (1987) 1317-1321
27. Wang T.X., Kelley M.D., Cooper J.N., Beckwith R.C., and Margerum D.W. Equilibrium, kinetic, and UV-spectral characteristics of aqueous bromine chloride, bromine, and chlorine species. Inorg. Chem. 33 (1994) 5872-5878
28. - radical ions. J. Phys. Chem. 75 (1971) 1738-1744
29. Zehavi D., and Rabani J. The oxidation of aqueous bromide ions by hydroxyl radicals. A pulse radiolytic investigation. J. Phys. Chem. 76 (1972) 312-319