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Crystal Structure analysis of 1 (Oxford Excalibur 2 diffractometer, The structural solution and refinement was performed using the programs SHELXS-86 and SHELXL-97.[30,31] C56H 60Mo4O16Zn10, M=2026.50, tetragonal, space group P4, a=18.0444(1, c=10.0674(2) Å, V=3277.95(7) Å3, Z=2, ρcalcd=2.053 gcm-3, T=105(2) K, F(000)=1984, μ(MoKα)=4.381 mm-1, 26852 reflections measured, 7596 unique (Rint= 0.0532, 389 parameters, R1=0.0440 (all data, wR2=0.0369 (all data, GOF=0.768. CCDC-694697 (1) contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via
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2=0.0369 (all data), GOF=0.768. CCDC-694697 (1) contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/ data_request/cif.
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6 core of 1 is found as a structural motif in the solid-state structure of the alloy.
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