A novel malonamide grafted polystyrene-divinyl benzene resin for extraction, pre-concentration and separation of actinides

Journal of Hazardous Materials

Volumn 161, Issue 2-3, 2009, Pages 1323-1329

  Ansari, S A ^a   Mohapatra, P K ^a   Manchanda, V K ^a  

^a BHABHA ATOMIC RESEARCH CENTRE   (India)

Author keywords

Actinide separation; Grafted resin; Pre concentration; Solid phase extraction

Indexed keywords

ABS RESINS; ACTINIDES; AMERICIUM; BENZENE; CONCENTRATION (PROCESS); DESORPTION; GRAFTING (CHEMICAL); ISOMERS; MICROSCOPIC EXAMINATION; NEUTRON DETECTORS; PHASE SEPARATION; PLUTONIUM; POLYSTYRENES; RESINS; SORPTION; TRANSURANIUM ELEMENTS; URANIUM; URANIUM COMPOUNDS; VEGETATION;

ACID SOLUTIONS; ACTINIDE IONS; BATCH STUDIES; CHEMICAL ANCHORING; CHROMATOGRAPHIC RESINS; DIVINYL BENZENES; GRAFTED POLYSTYRENES; GRAFTED RESIN; MERRIFIELD RESINS; OXALIC ACIDS; PRE-CONCENTRATION; SOLID PHASE EXTRACTION; SOLID-PHASE EXTRACTIONS; SORPTION EFFICIENCIES; TRIVALENT ACTINIDES; URANYL IONS;

EXTRACTION;

ACTINIDE; AMERICIUM; DIVINYLBENZENE; EDETIC ACID; MALONIC ACID; METAL ION; N,N' DIMETHYL N.N' DIBUTYL MALONAMIDE; OXALIC ACID; PLUTONIUM; POLYMER; POLYSTYRENE; RADIOISOTOPE; RESIN; THORIUM; UNCLASSIFIED DRUG; URANIUM;

ACTINIDE; CONCENTRATION (COMPOSITION); DESORPTION; EXTRACTION; RESIN; SCANNING ELECTRON MICROSCOPY; SEPARATION; URANIUM;

AQUEOUS SOLUTION; ARTICLE; CHEMICAL STRUCTURE; CHROMATOGRAPHY; INFRARED SPECTROSCOPY; POLLUTION; SCANNING ELECTRON MICROSCOPY; SOLID STATE; SYNTHESIS; ULTRAVIOLET SPECTROSCOPY;

ACTINOID SERIES ELEMENTS; AMERICIUM; CHEMISTRY, ANALYTICAL; IONS; MALONATES; MICROSCOPY, ELECTRON, SCANNING; MODELS, CHEMICAL; PLUTONIUM; POLYSTYRENES; SOLUTIONS; SPECTROPHOTOMETRY, ULTRAVIOLET; THORIUM; URANIUM; VINYL COMPOUNDS;

EID: 56249088603     PISSN: 03043894     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jhazmat.2008.04.093     Document Type: Article

References (29)

1. Mester Z., Sturgeon R., and Pawliszyn J. Solid phase microextraction as a tool for trace element speciation. Spectrochim. Acta-Part B: At. Spectrosc. 56 (2001) 233-260
2. Merdivan M., Duz M.Z., and Hamamci C. Sorption behaviour of uranium(VI) with N,N-dibutyl-N′-benzoylthiourea Impregnated in amberlite XAD-16. Talanta 55 (2001) 639-645
3. Horwitz E.P. Extraction chromatography of actinides and fission products: principles and achievement of selectivity. Proceedings of the International Workshop on the Application of Extraction Chromatography in Radionuclide Measurements. IRMM, Geel 9-10, EUR 18974EN (1998) 27-37
4. Mohapatra P.K., Sriram S., Manchanda V.K., and Badheka L.P. Uptake of metal ions by extraction chromatography using dimethyl dibutyl tetradecyl-1,3-malonamide (DMDBTDMA) as the stationary phase. Sep. Sci. Technol. 35 (2000) 39-55
5. Liu P., Liu Y., and Su Z. Modification of poly-(hydroxyethyl acrylate)-grafted cross-linked poly(vinyl chloride) particles via surface-initiated atom-transfer radicals polymerization (SI-ATRP). Competitive adsorption of some heavy metal ions on modified polymers. Ind. Eng. Chem. Res. 45 (2006) 2255-2260
6. Moawed A., Zaid M.A.A., and El-Shahat M.F. Methylene blue grafted polyurethane foam as a chelating resin for pre-concentration and separation of Cd(II), Hg(II) and Ag(I) from waste water. Anal. Lett. 36 (2003) 405-422
7. Benicewicz B.C., Jarvinen G.D., Kathios D.J., and Jorgensen B.S. Open-celled polymeric foam monoliths for heavy metals. J. Radioanal. Nucl. Chem. 235 (1998) 31-35
8. Bourg S., Broudic J.C., Conocar O., Moreau J.J.E., Meyer D., and Man M.W.C. Tailoring of organically modified silicas for the solid-liquid extraction of actinides. Chem. Mater. 13 (2001) 491-499
9. Raju C.S.K., and Subramanian M.S. A novel solid phase extraction method for separation of actinides and lanthanides from high acidic streams. Sep. Purif. Technol. 55 (2007) 16-22
10. Raju C.S.K., and Subramanian M.S. Selective pre-concentration of U(VI) and Th(IV) in trace and macroscopic levels using malonamide grafted polymer from acidic matrices. Microchim. Acta 150 (2005) 297-304
11. Radi S., Ramdani A., Lekchiri Y., Morcellet M., Crini G., Janus L., and Martel B. J. Appl. Polym. Sci. 78 (2000) 2495
12. Bian K., and Cunningham M.F. Synthesis of polymeric microspheres from a Merrifield resin by surface-initiated nitroxide-mediated radical polymerisation. J. Polym. Sci., Part A: Polym. Chem. 43 (2005) 2145-2154
13. Thiollet G., and Musikas C. Synthesis and use of the amide extractants. Solvent Extr. Ion Exch. 7 (1989) 813-827
14. Ansari S.A., Pathak P.N., Husain M., Prasad A.K., Parmar V.S., and Manchanda V.K. Extraction chromatographic studies of metal ions using N,N,N′,N′-tetraoctyl diglycolamide (TODGA) as the stationary phase. Talanta 68 (2006) 1273-1280
15. Zhang A., Wei Y., Hoshi H., and Kumagai M. Synthesis of novel silica-based macroporous polymer containing TODGA chelating agent and its application in the chromatographic separation of Mo(VI) and Zr(IV) from diethylenetriamine pentacetic acid. Sep. Sci. Technol. 40 (2005) 811-827
16. Ansari S.A., Mohapatra P.K., and Manchanda V.K. Synthesis of N,N′-dimethyl-N,N′-dibutyl malonamide functionalized polymer and its sorption affinities towards U(VI) and Th(IV) ions. Talanta 73 (2007) 878-885
17. 229Th. J. Radioanal. Chem. 67 (1981) 95-99
18. Ryan J.L., and Wheelright E.J. Recovery and purification of plutonium by ion exchange. Ind. Eng. Chem. 51 (1959) 60-65
19. Ramanujam A., Nadakarni M.N., Ramakrishna V.V., and Patil S.K. Studies on HTTA extraction of tetravalent actinides. J. Radioanal. Chem. 42 (1978) 349-357
20. Murali M.S., and Mathur J.N. Use of mixture of TRPO and TBP for the partitioning of actinides from high-level waste solutions of PUREX origin and its comparison with CMPO and other phosphorus-based extractants. Solvent Extr. Ion Exch. 19 (2001) 61-77
21. Thakur P., Veeraraghavan R., Mohapatra P.K., Manchanda V.K., and Dash K.C. Extraction of ternary complexes of thorium(IV) with 3-phenyl-4-benzoyl-5-isoxazolone and neutral donors from nitric acid medium. Talanta 43 (1996) 1305-1312
22. Maheshwari M.A., and Subramanian M.S. Extraction chromatographic method for the separation of actinides and lanthanides using EDHBA grafted AXAD-16 polymer. Talanta 65 (2005) 735-742
23. Pathak P.N., Prabhu D.R., Rizvi G.H., Ruikar P.B., Kumbhare L.B., Mohapatra P.K., and Manchanda V.K. Pu-Th separation studies employing di(2-ethylhexyl) isobutyramide (D2EHIBA) as extractant from nitric acid medium. Radiochim. Acta 91 (2003) 1-6
24. 3 medium. Solvent Extr. Ion Exch. 22 (2004) 267-284
25. Prabhakaran D., and Subramanian M.S. Selective extraction of U(VI) over Th(IV) from acidic streams using di-bis(2-ethylhexyl) malonamide anchored chloromethylated polymeric matrix. Talanta 65 (2005) 179-184
26. Horwitz E.P., Chiarizia R., and Dietz M.L. A novel strontium selective extraction chromatographic resin. Solvent Extr. Ion Exch. 10 (1992) 313-336
27. Skoog D.A., Holler F.J., and Nieman T.A. Principles of Instrumental Analysis. fifth ed. (1998), Saunders College Publishing, Fort Worth p. 684
28. Raju C.S.K., and Subramanian M.S. DAPA grafted polymer: an efficient solid phase extractant for U(VI), Th(IV) and La(III) from acidic waste streams and environmental samples. Talanta 67 (2005) 81-89
29. Maheshwari M.A., and Subramanian M.S. Amide grafted Amberlite XAD-16 polymer for the selective and sequential separation of U(VI) and Th(IV) from acidic waste effluents. Solvent Extr. Ion Exch. 23 (2005) 249-263