Studies on thermal and flame retardant behaviour of mixtures of bis(m-aminophenyl)methylphosphine oxide based benzoxazine and glycidylether or benzoxazine of Bisphenol A

Polymer Degradation and Stability

Volumn 93, Issue 12, 2008, Pages 2158-2165

  Sponton M ^a   Ronda, J C ^a   Galia M ^a   Cadiz V ^a  

^a UNIVERSITAT ROVIRA I VIRGILI   (Spain)

Author keywords

Benzoxazine; Epoxy; Flame retardant; Heteroatom containing polymers

Indexed keywords

ABS RESINS; EPOXY RESINS; FIRE FIGHTING EQUIPMENT; FLAMMABILITY; GRAVIMETRIC ANALYSIS; MONOMERS; OXYGEN; PHENOLS; PHOSPHORUS; THERMOGRAVIMETRIC ANALYSIS;

BENZOXAZINE; BENZOXAZINE MONOMERS; BISPHENOL; DYNAMIC MECHANICALS; EPOXY; EPOXY SYSTEMS; HETEROATOM-CONTAINING POLYMERS; LIMITING OXYGEN INDICES; MOLAR RATIOS; PHOSPHORUS CONTENTS;

DYNAMIC MECHANICAL ANALYSIS;

EID: 56249087531     PISSN: 01413910     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.polymdegradstab.2008.08.004     Document Type: Article

References (21)

1. Ghosh N.N., Kiskan B., and Yagci Y. Polybenzoxazines - new high performance thermosetting resins: synthesis and properties. Prog Polym Sci 32 (2007) 1344-1391
2. Ning X., and Ishida H. Phenolic materials via ring-opening polymerization of benzoxazines: effect of molecular structure on mechanical and dynamic mechanical properties. J Polym Sci Part A Polym Chem Ed 32 (1994) 1121-1129
3. Lu S.-Y., and Hamerton I. Recent developments in the chemistry of halogen-free flame retardant polymers. Prog Polym Sci 27 (2002) 1661-1712
4. Shen S.B., and Ishida H. Synthesis and characterization of polyfunctional napthoxazines and related polymers. J Appl Polym Sci 61 (1996) 1595-1605
5. Takeichi T., Kano T., and Agag T. Synthesis and thermal cure of high molecular weight polybenzoxazine precursors and the properties of the thermosets. Polymer 46 (2005) 12172-12180
6. Men W., and Lu Z. Synthesis and characterization of 4,4-diaminodiphenyl methane-based benzoxazines and their polymers. J Appl Polym Sci 106 (2007) 2769-2774
7. Men W., and Lu Z. Synthesis of a novel benzoxazine precursor containing phenol hydroxyl group and its polymer. J Appl Polym Sci 109 (2008) 2218-2223
8. Subrayan R.P., and Jones F.N. Condensation of substituted phenols with hexakis (methoxymethyl)melamine: synthesis, characterization, and properties of substituted 2,4,6-tris(3,4-dihydro-1,3-(2H)-benzoxazin-3yl)-s-triazine derivatives. Chem Mater 10 (1998) 3506-3512
9. Lin C.H., Chang S.L., Hsieh C.W., and Lee H.H. Aromatic diamine-based benzoxazines and their high performance thermoset. Polymer 49 (2008) 1220-1229
10. Sponton M, Larrechi MS, Ronda JC, Galià M, Cádiz V. Synthesis of bis(m-aminophenyl)methylphosphine oxide based benzoxazine and study of thermal cross linking. J Polym Sci Part A Polym Chem, in press. doi:10.1002/pola.
11. Agag T., and Takeichi T. Synthesis, characterization and clay-reinforcement of epoxy cured benzoxazine. High Perform Polym 14 (2002) 115-132
12. Ishida H., and Allen D.J. Mechanical characterization of copolymers based on benzoxazine and epoxy. Polymer 37 (1996) 4487-4495
13. Kimura H., Matsumoto A., Hasegawa K., Ohtsuka K., and Fukuda A. Epoxy resin cured by Bisphenol A based benzoxazine. J Appl Polym Sci 68 (1998) 1903-1910
14. Jain R., Narula A.K., and Choudhary V. Studies on curing and thermal behavior of diglycidyl ether of Bisphenol-A and benzoxazine mixtures. J Appl Polym Sci 106 (2007) 3327-3334
15. Kimura H., Matsumoto A., and Ohtsuka K. Studies on new type of phenolic resin - curing reaction of Bisphenol-A-based benzoxazine with epoxy resin using latent curing agent and the properties of the cured resin. J Appl Polym Sci 109 (2008) 1248-1256
16. Ishida H., and Rodríguez Y. Polymer curing kinetics of the new benzoxazine-based phenolic resin by differential scanning calorimetry. Polymer 36 (1995) 3151-3158
17. Varma I.K., and Gupta U. Curing of epoxy resin with phosphorylated diamine. J. Macromol Sci Chem A23 (1986) 19-36
18. Ishida H., and Low H.I. A study on the volumetric expansion of benzoxazine-based phenolic resin. Macromolecules 30 (1997) 1099-1106
19. Andreu R., Reina J.A., and Ronda J.C. Studies on the thermal polymerization of substituted benzoxazine monomers: electronic effects. J Polym Sci Part A Polym Chem 46 (2008) 3353-3366
20. Tobolsky A.V., Carlson D.W., and Indictor N.J. Rubber elasticity and chain configuration. J Polym Sci 54 (1961) 175-192
21. Van Krevelen D.W. Basic aspects of flame resistance of polymeric materials. Polymer 16 (1975) 615-620