On the biocatalytic cleavage of silicon-oxygen bonds: A substrate structural approach to investigating the cleavage of protecting group silyl ethers by serine-triad hydrolases

Journal of Molecular Catalysis B: Enzymatic

Volumn 56, Issue 1, 2009, Pages 24-28

  Maraite, Andy ^a   Ansorge Schumacher, Marion B ^a   Ganchegui, Benjamin ^a   Leitner, Walter ^a   Grogan, Gideon ^b  

^a RWTH AACHEN UNIVERSITY   (Germany)

^b UNIVERSITY OF YORK   (United Kingdom)

Author keywords

Enzymes; Protecting groups; Serine hydrolases; Silylethers; Tertiary acids

Indexed keywords

ACIDS; AMINO ACIDS; CARBOXYLATION; CATALYSTS; ENZYMES; ETHERS; FUNCTIONAL ELECTRIC STIMULATION; HYDROLYSIS; ORGANIC COMPOUNDS; OXYGEN; PROTEINS; SILANES; SILICON; SILICON COMPOUNDS;

CATALYSE; ETHER BONDS; HYDROLASES; ISOSTERIC; OXYGEN BONDS; PROTEASE ENZYMES; PROTECTING GROUPS; SERINE HYDROLASES; SILICATEIN; SILYLETHERS; STERIC EFFECTS; STERICALLY DEMANDING; TERTIARY ACIDS; TRIMETHYLETHOXYSILANE; TRIMETHYLSILYL;

SUBSTRATES;

BUFFER; CATHEPSIN; CHYMOTRYPSIN; HYDROLASE; OXYGEN; SERINE; SILANE DERIVATIVE; SILICON; TRYPSIN;

ARTICLE; BIOCATALYST; CHEMICAL BOND; ENZYME ACTIVITY; ENZYME MECHANISM; HYDROLYSIS; NONHUMAN; TEMPERATURE;

EID: 56049114233     PISSN: 13811177     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.molcatb.2008.04.006     Document Type: Article

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