Three-compartment bipolar membrane electrodialysis for splitting of sodium formate into formic acid and sodium hydroxide: Role of diffusion of molecular acid

Journal of Membrane Science

Volumn 325, Issue 2, 2008, Pages 528-536

  Jaime Ferrer, J S ^a   Couallier, E ^a   Viers, Ph ^a   Durand, G ^a   Rakib, M ^a  

^a ECOLE CENTRALE PARIS   (France)

Author keywords

Bipolar membrane electrodialysis; Diffusion through anion exchange membrane; Diffusion through bipolar membrane; Formic acid; Hydroxide ion leakage through cation exchange membrane; Modelling; Salt splitting

Indexed keywords

ACIDS; CATALYST ACTIVITY; CONCENTRATION (PROCESS); DIFFUSION; ELECTRODIALYSIS; ION EXCHANGE; IONS; MEMBRANES; NEGATIVE IONS; ORGANIC ACIDS; POSITIVE IONS; SEMICONDUCTOR DOPING;

ACID CONCENTRATIONS; ACID DIFFUSIONS; BIPOLAR MEMBRANE ELECTRODIALYSIS; BIPOLAR MEMBRANE ELECTRODIALYSISES; BIPOLAR MEMBRANES; CURRENT EFFICIENCIES; EXCHANGE MEMBRANES; EXPERIMENTAL PARAMETERS; FLUX RATES; HYDROXIDE ION LEAKAGE THROUGH CATION-EXCHANGE MEMBRANE; LOW TEMPERATURES; MASS BALANCES; MODEL-BASED; MODELLING; MOLECULAR ACIDS; ROLE OF DIFFUSIONS; SALT SPLITTING; SODIUM FORMATES; SODIUM HYDROXIDE CONCENTRATIONS; SODIUM HYDROXIDE SOLUTIONS; SODIUM HYDROXIDES; VOLUME VARIATIONS;

FORMIC ACID;

FORMIC ACID; SODIUM; SODIUM HYDROXIDE;

ANION EXCHANGE; ARTICLE; BIPOLAR MEMBRANE; CATION EXCHANGE; DIFFUSION; ELECTRODIALYSIS; LOW TEMPERATURE; MEMBRANE; MEMBRANE BIOLOGY; MEMBRANE TRANSPORT; MOLECULAR DYNAMICS; MOLECULAR MODEL; PRIORITY JOURNAL; RELATIVE DENSITY; TEMPERATURE SENSITIVITY;

EID: 55749100130     PISSN: 03767388     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.memsci.2008.07.059     Document Type: Article

References (15)

1. Strathmann H. Ion-exchange Membrane Separation Processes (2004), Elsevier, Amsterdam
2. Thate S., Eigenberger G., and Rapp H.J. In: Kemperman A.J.B. (Ed). Handbook on Bipolar Membrane Technology (2000), Twente University Press, Enschede, The Netherlands
3. Huang C., Xu T., Zhang Y., Xue Y., and Chen G. Application of electrodialysis to the production of organic acids: state-of-the-art and recent developments. J. Membr. Sci. 288 (2007) 1-12
4. Tongwen X. Electrodialysis processes with bipolar membranes (EDBM) in environmental protection-a review. Resour. Conserv. Recycl. 37 (2002) 1-22
5. Kim Y.H., and Moon S.H. Lactic acid recovery from fermentation broth using one stage electrodialysis. J. Chem. Tech. Biotech. 76 (2001) 169-178
6. Trivedi G.S., Shah B.G., Adhikary S.K., Indusekhar V.K., and Rangarajan R. Studies on bipolar membranes. Part II. Conversion of sodium acetate to acetic acid and sodium hydroxide. React. Funct. Polym. 32 (1997) 209-215
7. Jaime Ferrer J.S., Laborie S., Durand G., and Rakib M. Formic acid regeneration by electromembrane processes. J. Membr. Sci. 280 (2006) 509-516
8. Narebska A., Kurantowicz M., and Staniszewski M. Separation of fermentation products by membrane techniques. IV. Electrodialytic conversion of carboxylates to carboxylic acids. Sep. Sci. Technol. 36 (2001) 443-455
9. Wodzki R., and Nowaczyk J. Membrane transport of organics. II. Permeation of some carboxylic acids through bipolar polymer membrane. J. Appl. Polym. Sci. 71 (1999) 2179-2190
10. Wodzki R., and Nowaczyk J. Membrane transport of organics. III. Permeation of some carboxylic acids through strongly basic polymer membrane. J. Appl. Polym. Sci. 80 (2001) 2705-2717
11. Yu L., Guo Q., Hao J., and Jiang W. Recovery of acetic acid from dilute wastewater by means of bipolar membrane electrodialysis. Desalination 129 (2000) 283-288
12. Koter S. Modeling of weak acid production by the EDB method. Sep. Purif. Technol. 57 (2007) 406-412
13. Jaime Ferrer J.S., Couallier E., Rakib M., and Durand G. Electrochemical determination of acidity level and dissociation of formic acid/water mixtures as solvent. Electrochim. Acta 52 (2007) 5773-5780
14. Gineste J.L., Pourcelly G., Lorrain Y., Persin F., and Gavach C. Analysis of factors limiting the use of bipolar membranes: a simplified model to determine trends. J. Membr. Sci. 112 (1996) 199-208
15. Lorrain Y., Pourcelly G., and Gavach C. Influence of cations on the proton leakage through anion-exchange membranes. J. Membr. Sci. 110 (1996) 181-190