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Volumn 41, Issue 20, 2008, Pages 7752-7754

Anomalous stiff backbones of helical poly(phenyl isocyanide) derivatives

Author keywords

[No Author keywords available]

Indexed keywords

ABS RESINS; CURVE FITTING; CYANIDES; ESTERS; MONOMERS; ORGANIC COMPOUNDS;

EID: 55649118471     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma8015954     Document Type: Article
Times cited : (38)

References (52)
  • 38
    • 55649108342 scopus 로고    scopus 로고
    • Although a number of rodlike helical polymers have been prepared, only a limited number of q values have been determined for helical polymers. The reported high q values for synthetic helical polymers are 13.5 nm (poly(N-propargylamide, 7b 20-40 nm (poly(n-hexyl isocyanate, 13 42 nm (poly(N-(1-phenylethyl)-N′-methylcarbodiimide, 14 76 nm (polyisocyanopeptides),6b 103 nm (poly(((R)-3,7-dimethyloctyl, S)-3-methylpentyl)-silylene, 15 and 135 nm (poly(4-ethynylbenzoyl-L-alanine n-decyl ester).8d
    • 8d
  • 51
    • 55649093665 scopus 로고    scopus 로고
    • Polyisocyanides including poly-1 adsorbed strongly on the SEC columns in THF and chloroform, and therefore, TBAB was used as an additive in the THF as the eluent.
    • Polyisocyanides including poly-1 adsorbed strongly on the SEC columns in THF and chloroform, and therefore, TBAB was used as an additive in the THF as the eluent.
  • 52
    • 55649104046 scopus 로고    scopus 로고
    • 11 also showed a large q value (175 nm), indicating that the excess of one-helical sense of poly-1 may not influence its main-chain stiffness, although the reason for the apparent difference in their q values of the poly-1s is not clear at present.
    • 11 also showed a large q value (175 nm), indicating that the excess of one-helical sense of poly-1 may not influence its main-chain stiffness, although the reason for the apparent difference in their q values of the poly-1s is not clear at present.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.