Variation of MCPA, metribuzine, methyltriazine-amine and glyphosate degradation, sorption, mineralization and leaching in different soil horizons

Environmental Pollution

Volumn 156, Issue 3, 2008, Pages 794-802

  Jacobsen, Carsten S ^a,b   van der Keur, Peter ^a   Iversen, Bo V ^c   Rosenberg, Per ^a   Barlebo, Heidi C ^a   Torp, Søren ^c   Vosgerau, Henrik ^a   Juhler, René K ^a   Ernstsen, Vibeke ^a   Rasmussen, Jim ^a   Brinch, Ulla Catrine ^a   Jacobsen, Ole Hørbye ^c  

^a GEOLOGICAL SURVEY OF DENMARK AND GREENLAND   (Denmark)

^b UNIVERSITY OF COPENHAGEN   (Denmark)

^c DANISH INSTITUTE OF AGRICULTURAL SCIENCES   (Denmark)

Author keywords

Groundwater contamination; Herbicides; MACRO modeling; Spatial variation; Vadose zone

Indexed keywords

AMINES; CLAY MINERALS; CONCENTRATION (PROCESS); CONTAMINATION; GROUNDWATER; GROUNDWATER POLLUTION; HYDROGEOLOGY; LEACHING; MINERALOGY; ORGANIC COMPOUNDS; PEST CONTROL; PESTICIDES; SOIL POLLUTION; SOILS; SORPTION; UNDERGROUND RESERVOIRS; WEED CONTROL;

AVERAGE CONCENTRATIONS; DRILLED HOLES; GLYPHOSATE; GLYPHOSATE DEGRADATIONS; GROUNDWATER CONTAMINATION; ORGANIC MATTERS; OUTWASH PLAINS; PHENOXYACETIC ACID HERBICIDES; SOIL HORIZONS; SOIL PH; SOIL SAMPLES; SPATIAL VARIATION; VADOSE ZONE; VADOSE ZONES;

HERBICIDES;

2 (4 CHLORO 2 METHYLPHENOXY)ACETIC ACID; GLYPHOSATE; METHYLTRIAZINE AMINE; METRIBUZIN; SOIL WATER; TRIAZINE DERIVATIVE; UNCLASSIFIED DRUG;

CONCENTRATION (COMPOSITION); DEGRADATION; GROUNDWATER POLLUTION; HERBICIDE; LEACHING; MINERALIZATION; POLLUTANT TRANSPORT; SOIL HORIZON; SORPTION; SPATIAL VARIATION; TOPSOIL; VADOSE ZONE;

ARTICLE; CLAY; CONCENTRATION (PARAMETERS); DEGRADATION; DETOXIFICATION; HYDRAULIC CONDUCTIVITY; LEACHING; MINERALIZATION; PH MEASUREMENT; SOIL ANALYSIS; SOIL POLLUTION;

2-METHYL-4-CHLOROPHENOXYACETIC ACID; ADSORPTION; ALUMINUM SILICATES; BIODEGRADATION, ENVIRONMENTAL; DENMARK; ENVIRONMENTAL MONITORING; GLYCINE; HERBICIDES; HYDROGEN-ION CONCENTRATION; MODELS, STATISTICAL; PARTICLE SIZE; PARTICULATE MATTER; RIVERS; SOIL; SOIL POLLUTANTS; TRIAZINES; WATER POLLUTANTS, CHEMICAL;

DENMARK; EURASIA; EUROPE; NORTHERN EUROPE; SCANDINAVIA;

EID: 55649103201     PISSN: 02697491     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.envpol.2008.06.002     Document Type: Article

References (25)

1. Bælum J., Henriksen T., Hansen H.C.B., and Jacobsen C.S. Degradation of 4-chloro-2-methyl-phenoxyacetic acid in top- and subsoil is quantitatively linked to the class III tfdA gene. Applied and Environmental Microbiology 72 (2006) 1476-1486
2. Beulke S., Renaud F., and Brown C.D. Development of Guidance on Parameter Estimation for the Preferential Flow Model MACRO 4.2. DEFRA Project PL0538 (2002), Report to the Department for Environment, Food & Rural Affairs. Cranfield University, Silsoe, UK
3. Bossi R., Vejrup K., and Jacobsen C.S. Determination of sulfonylurea degradation products in soil by liquid chromatography-ultraviolet detection followed by confirmatory liquid chromatography-tandem mass spectrometry. Journal of Chromatography A 855 (1999) 575-582
4. Brooks R.H., and Corey A.T. Hydraulic Properties of Porous Media. Hydrology Paper No.3 (1964), Colorado State University, Fort Collins, Colorado 27pp.
5. Coquet Y., and Barriuso E. Spatial variability of pesticide adsorption within the topsoil of a small agricultural catchment. Agronomie 22 (2002) 389-398
6. Coquet Y. Sorption of pesticides atrazine, isoproturon, and metamitron in the vadose zone. Vadose Zone Journal 2 (2003) 40-51
7. Dubus I.G., and Brown C.D. Sensitivity and first-step uncertainty analyses for the preferential flow model MACRO. Journal of Environmental Quality 31 (2002) 227-240
8. Dubus I.G., Brown C.D., and Beulke S. Sensitivity Analyses for Leaching Models used for Pesticide Registration in Europe. MAFF Project PL0532. SSLRC Project JF3741E (2000), Soil Survey and Land Research Centre. Cranfield University, UK
9. Espensen K.H. Multivariate Data Analysis - in Practice. fifth ed. (2002), Camo Process AS, Oslo, Norway
10. Felding G. Pesticide adsorption as a function of depth below surface. Pesticide Science 50 (1997) 64-66
11. FOCUS, 2000. Report of the FOCUS Groundwater Scenarios Workgroup. EC Document Reference. Sanco/321/2000.
12. Fredslund, L., Vinther, F.P., Brinch, U.C., Elsgaard, L., Rosenberg, P., Jacobsen, C.S. Field scale variation in the mineralization and sorption of MCPA in a sandy soil. Journal Environmental Quality, in press.
13. Gee G.W., and Bauder J.W. Particle-size analysis. Agron. Monogr. 9. In: Klute A. (Ed). Methods of Soil Analysis. Part 1. second ed. (1986), ASA and SSSA, Madison, WI 383-409
14. van Genuchten M.Th., Leij F.J., and Yates S.R. The RETC Code for Quantifying the Hydraulic Functions of Unsaturated Soils. EPA/600/2-91/065 (1991), U.S. Salinity Laboratory, USDA-ARS, Riverside, USA
15. Godskesen B., Holm P., Jacobsen O.S., and Jacobsen C.S. Ageing of triazine amine in soil and subsoil. Environmental Chemistry and Toxicology 24 (2005) 510-516
16. Haberhauer G., Pfeiffer L., Gerzabek M.H., Kirchmann H., Aquino A.J.A., Tunega D., and Lischka H. Response of sorption processes of MCPA to the amount and origin of organic matter in a long-term field experiment. European Journal of Soil Science 52 (2001) 279-286
17. 14C MCPA in soil - influence of concentration, temperature and moisture-content on degradation. Weed Research 27 (1987) 287-296
18. Houmark-Nielsen M., and Kjær K.H. Southwest Scandinavia, 40-15 kyr BP: palaeogeography and environmental change. Journal of Quaternary Science 18 (2003) 769-786
19. Jarvis N.J. Simulation of soil water dynamics and herbicide persistence in a silt loam soil using the MACRO model. Ecological Modelling 81 (1995) 97-109
20. Jarvis N. The MACRO Model (Version 4.3). Technical Description (2002). http://www.mv.slu.se/bgf/Macrohtm/info.htm Available from:
21. Jacobsen C.S., Shapir N., Christensen L.O., Jensen E.H., Juhler R.K., Streibig J.C., Mandelbaum R., and Helweg A. Bioavailability of triazine herbicides in a sandy soil profile. Biology and Fertility of Soils 33 (2001) 501-506
22. Kjær J., Olsen P., Henriksen T., and Ullum M. Leaching of metribuzin metabolites and the associated contamination of a sandy Danish aquifer. Environmental Science and Technology 39 (2005) 8374-8381
23. Klute A., and Dirksen C. Hydraulic conductivity and diffusivity: laboratory methods. In: Klute A. (Ed). Methods of Soil Analysis, Part 1. Physical and Mineralogical Methods (1986), American Society of Agronomy-Soil Science Society of America 687-734
24. Mortensen S.K., and Jacobsen C.S. Influence of frozen storage on herbicide degradation capacity in surface and subsurface sandy soils. Environmental Science and Technology 38 (2004) 6625-6632
25. Organisation for Economic Co-Operation and Development, 1997. OECD Guidelines for Testing of Chemicals. Proposal for Updating Guideline 106. Adsorption/desorption using a Batch Equilibrium Method. Revised draft document, October 1997. Environ. Health and Safety Div., OECD Environ., Directorate, Paris.