Insight into the reduction of pyruvic acid to lactic acid over Cu{110}: The crucial role of intramolecular tunneling in direct hydrogenation

Journal of the American Chemical Society

Volumn 130, Issue 44, 2008, Pages 14483-14492

  Jones, Glenn ^a,b   Jenkins, Stephen J ^a  

^a UNIVERSITY OF CAMBRIDGE   (United Kingdom)

^b JOHNSON MATTHEY TECHNOLOGY CENTRE   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

ACIDS; BODY FLUIDS; CARBOXYLATION; COPPER; DENSITY FUNCTIONAL THEORY; DESORPTION; ELECTRONIC STRUCTURE; HYDROGEN; HYDROGENATION; LACTIC ACID; RATE CONSTANTS;

AMBIENT PRESSURES; BARRIER HEIGHTS; BIOLOGICALLY RELEVANT MOLECULES; CARBONYL REDUCTIONS; CARBOXYLATE GROUPS; DENSITY FUNCTIONAL THEORY CALCULATIONS; ELECTRON DENSITIES; EQUILIBRIUM THERMODYNAMICS; HYDROGEN EXCHANGES; KEY REACTIONS; LOW PRESSURES; METAL SURFACES; PRESSURE GAPS; PYRUVIC ACIDS; REACTION PROFILES; REPROTONATION;

ORGANIC ACIDS;

CARBONYL DERIVATIVE; COPPER; LACTIC ACID; PYRUVIC ACID;

ARTICLE; CHEMICAL REACTION; CHEMICAL STRUCTURE; DESORPTION; HYDROGENATION; HYPOBARISM; PROTON TRANSPORT; REDUCTION; SURFACE PROPERTY; TEMPERATURE DEPENDENCE; THERMODYNAMICS;

ADSORPTION; COPPER; HYDROGENATION; LACTIC ACID; MODELS, CHEMICAL; MODELS, MOLECULAR; OXIDATION-REDUCTION; PYRUVIC ACID; THERMODYNAMICS; VACUUM;

EID: 55549118620     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja077786m     Document Type: Article

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