Separation and concentration of cobalt from ammoniacal solutions containing cobalt and nickel by emulsion liquid membranes using 5,7-dibromo-8-hydroxyquinoline (DBHQ)

Journal of Membrane Science

Volumn 325, Issue 2, 2008, Pages 712-718

  Kumbasar, R A ^a   Şahin, I ^a  

^a SAKARYA UNIVERSITY   (Turkey)

Author keywords

5,7 dibromo 8 hydroxyquinoline (DBHQ); Ammoniacal solution; Cobalt nickel separation; Emulsion liquid membrane

Indexed keywords

ACIDS; COBALT; COBALT COMPOUNDS; CONCENTRATION (PROCESS); EMULSIFICATION; HYDROCHLORIC ACID; ISOMERS; LIQUID MEMBRANES; MEMBRANES; METAL ANALYSIS; NICKEL; NICKEL ALLOYS; PETROLEUM PRODUCTS; SEPARATION; STRIPPING (DYES); SURFACE ACTIVE AGENTS; TRANSITION METALS;

5,7-DIBROMO-8-HYDROXYQUINOLINE (DBHQ); AMMONIACAL SOLUTION; COMPLEXING AGENTS; EMULSION LIQUID MEMBRANE; EMULSION LIQUID MEMBRANES; EXTRACTANT; EXTRACTANT CONCENTRATIONS; FEED SOLUTIONS; HYDROXYQUINOLINE; INITIAL FEED CONCENTRATIONS; MEMBRANE COMPOSITIONS; MEMBRANE SOLUTIONS; MIXING SPEEDS; NICKEL CONCENTRATIONS; OPTIMUM CONDITIONS; PHASE RATIOS; SEPARATION AND CONCENTRATIONS; SEPARATION FACTORS; SPAN 80; STRIPPING SOLUTIONS; SURFACTANT CONCENTRATIONS; TRIBUTYL PHOSPHATES;

SOLUTIONS;

BROXYQUINOLINE; COBALT; EDETIC ACID; ION; NICKEL;

ANALYTIC METHOD; ARTICLE; CONCENTRATION (PARAMETERS); EMULSION; EXPERIMENTAL STUDY; LIQUID MEMBRANE; PH; PRIORITY JOURNAL;

EID: 55549096694     PISSN: 03767388     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.memsci.2008.08.044     Document Type: Article

References (33)

1. Alguacil F.J., and Cerba A. Separation of cobalt and nickel from acidic sulfate solutions using mixtures of di(2-ethylhexyl)phosphoric acid (DP-8R) and hydroxyoxime (ACORGA M5640). J. Chem. Technol. Biotechnol. 79 (2004) 455-460
2. Flett D.S. Cobalt-nickel separation in hydrometallurgy: a review. Chem. Sustain. Dev. 12 (2004) 81-91
3. León G., and Guzmán M.A. Kinetic study of the effect of carrier and stripping agent concentrations on the facilitated transport of cobalt through bulk liquid membranes. Desalination 184 (2005) 79-87
4. Gómez-Lahoz C., García-Herruzo F., Rodríguez-Maroto J.M., and Rodríguez J.J. Cobalt (II) removal from water by chemical reduction with sodium borohydride. Water Res. 27 6 (1993) 985-992
5. Netzer A., and Hughes D.E. Adsorption of copper, lead and cobalt by activated carbon. Water Res. 18 8 (1984) 927-933
6. Rivera-Utrilla J., and Ferro-Garcia M.A. Study of cobalt adsorption from aqueous solution on activated carbons from almond shells. Carbon 25 5 (1987) 645-652
7. Travieso L., Pellón A., Benítez F., Sánchez E., Borja R., O'Farrill N., and Weiland P. BIOALGA reactor: preliminary studies for heavy metals removal. Biochem. Eng. J. 12 2 (2002) 87-91
8. Kim J.S., and Kaene M.A. The removal of iron and cobalt from aqueous solutions by ion exchange with Na-Y zeolite: batch, semi-batch and continuous operation. J. Chem. Technol. Biotecnol. 77 6 (2002) 633-640
9. Kara M., Yüzer H., Sabah E., and Celik M.S. Adsorption of cobalt from aqueous solutions onto sepiolite. Water Res. 37 1 (2003) 224-232
10. Zvezdov A., and Ishigure K. The effect of corrosion particles present in water solutions on the behaviour of strong acid cation-exchange resins during the process of cobalt removal. Desalination 154 2 (2003) 153-160
11. Mendes F.D., and Martins A.H. Selective sorption of nickel and cobalt from sulphate solutions using chelating resins. Int. J. Min. Process. 74 1-4 (2004) 359-371
12. Haura A.M., and Ramachandhran V. RO performance analysis of cellulose acetate and TFC polyamide membrane systems for separation of trace contaminants. Desalination 104 3 (1996) 175-183
13. Thompson J.A., and Jarvinen G. Using watersoluble polymers to remove dissolved metal ions. Filtration Sep. 36 5 (1999) 28-32
14. Atamanenko I.D., Kryvoruchko A.P., Yurlova L.Y., and Kornilovich B.Y. Concentration of heavy metal by pressure-driven membrane methods. Desalination 158 1-3 (2003) 151-156
15. Kryvoruchko A.P., Atamanenko I.D., and Yurlova L.Y. Concentration/purification of Co(II) ions by reverse osmosis and ultrafiltration combined with sorption on clay mineral montmorillonite and cation-exchange resin KU-2-8n. J. Membr. Sci. 228 1 (2004) 77-81
16. Strzelbicki J., and Charewicz W.A. Effect of some operating variables on cobalt (II) transport across a bulk liquid membrane. Hydrometallurgy 13 1 (1984) 89-102
17. Chaudry M.A., Malik M.T., and Ali A. Transport of Co (II) ions through di(2-ethylhexyl) phosphoric acid-CCl4 supported liquid membrane. Sep. Sci. Technol. 25 11-12 (1990) 1161-1174
18. Mohapatra R., Kanungo S.B., and Sarma P.V.R.B. Kinetics of the transport of Co (II) from aqueous sulphate solution through a supported liquid membrane containing di(2-ethylhexyl) phosphoric acid in kerosene. Sep. Sci. Technol. 27 6 (1992) 765-781
19. León G., and Guzmán M.A. Facilitated transport of cobalt through bulk liquid membranes containing diethylhexyl phosphoric acid. Desalination 162 1-3 (2004) 211-215
20. Alguacil F.J., and Alonso M. Separation of zinc(II) from cobalt(II) solutions using supported liquid membrane with DP-8R (di(2-ethylhexyl) phosphoric acid) as a carrier. Sep. Purif. Technol. 41 2 (2005) 179-184
21. Sastre A.M., Kumar A., Shukla J.P., and Singh R.K. Improved techniques in liquid membraneseparations: an overview. Sep. Purif. Method. 27 2 (1998) 213-298
22. R.A. Kumbasar, S. Kasap, Selective separation of nickel from cobalt in ammoniacal solutions by emulsion type liquid membranes using 8-hydroxyquinoline (8-HQ) as mobile carrier, Hydrometallurgy, doi:10.1016/j.hydromet.2008.05.002.
23. Mackenzie J.M.W., and Virnig M.J. Extraction of nickel from ammoniacal leach solutions: extractant and solution chemistry issues. Proceedings of the ALTA 1998 Nickel/Cobalt Pressure Leaching and Hydrometallurgy Forum. ALTA Metallurgical Services Melbourne, Perth, Australia (1998)
24. Price M.J., and Reid J.G. Separation and recovery of nickel and cobalt in ammoniacal systems-process development. In: Logsdail D.H., and Slater M.J. (Eds). Solvent Extraction in the Process Industries (Proceedings of ISEC'93), vol. 1 (1993), SCI/Elsevier, London 159
25. Skoog D.A., West D.M., and Holler F.J. Analytical Chemistry. sixth ed. (1994), Saunders College Publishing p. 242
26. Alguacil F.J., and Cobo A. Solvent extraction equilibrium of nickel with LIX 54. Hydrometallurgy 48 (1998) 291-299
27. Kolhinen T., and Jalkanen H. Thermodynamic modelling of ammoniacal nickel sulphate solutions. Scand. J. Metall. 34 6 (2005) 334-339
28. ®. Hydrometallurgy 81 (2006) 67-73
29. Kumbasar R.A., and Tutkun O. Separation and concentration of gallium from acidic leach solutions containing various metal ions by emulsion type of liquid membranes using TOPO as mobile carrier. Hydrometallurgy 75 1-4 (2004) 111-121
30. Othman N., Mat H., and Goto M. Separation of silver from photographic wastes by emulsion liquid membrane system. J. Membr. Sci. 282 1-2 (2006) 171-177
31. Reis M.T.A., and Carvalho J.M.R. Modelling of zinc extraction from sulphate solutions with bis (2-ethylhexyl) thiophosphoric acid by emulsion liquid membranes. J. Membr. Sci. 237 (2004) 97-107
32. Gasser M.S., El-Hefny N.E., and Daoud J.A. Extraction of Co(II) from aqueous solution using emulsion liquid membrane. J. Hazard. Mater. 151 2-3 (2008) 610-615
33. Sengupta B., Sengupta R., and Subrahmanyam N. Process intensification of copper extraction using emulsion liquid membranes: experimental search for optimal conditions. Hydrometallurgy 84 1-2 (2006) 43-53