Kinetics of the gas-phase reactions of OH radicals, NO3 radicals and O3 with three C7-carbonyls formed from the atmospheric reactions of myrcene, ocimene and terpinolene

Journal of Atmospheric Chemistry

Volumn 48, Issue 3, 2004, Pages 241-260

  Baker, Jillian ^a   Arey, Janet ^a   Atkinson, Roger ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

4 methylcyclohex 3 en 1 one; 4 methylenehex 5 enal; 4 methylhexa 3,5 dienal; Hydroxy radical; Kinetics; Nitrate radical; Ozone

Indexed keywords

CARBONYL DERIVATIVE; HYDROXYL RADICAL; MYRCENE; NITRATE; OZONE; TERPENOID; TERPINOLENE;

ATMOSPHERIC CHEMISTRY; CHEMICAL REACTION; HYDROXYL RADICAL; KINETICS; NITRATE;

ARTICLE; ATMOSPHERE; ATMOSPHERIC PRESSURE; CHEMICAL REACTION KINETICS; CHEMICAL STRUCTURE; CIRCADIAN RHYTHM; CONTROLLED STUDY; DEGRADATION; GAS; PHOTOLYSIS; PREDICTION; TROPOSPHERE;

EID: 5544315285     PISSN: 01677764     EISSN: None     Source Type: Journal    
DOI: 10.1023/B:JOCH.0000044420.94492.fa     Document Type: Article

References (29)

1. 3 with the monoterpene reaction products pinonaldehyde, caronaldehyde, and sabinaketone, J. Atmos. Chem. 31, 281-297.
2. 3 radical with organic compounds, J. Phys. Chem. Ref. Data 20, 459-507.
3. Atkinson, R., 1997: Gas-phase tropospheric chemistry of volatile organic compounds. 1. Alkanes and alkenes, J. Phys. Chem. Ref. Data 26, 215-290.
4. Atkinson, R., 2000: Atmospheric chemistry of VOCs and NOx, Atmos. Environ. 34, 2063-2101.
5. Atkinson, R. and Arey, J., 1998: Atmospheric chemistry of biogenic compounds, Acc. Chem. Res. 31, 574-583.
6. Atkinson, R. and Arey, J., 2003: Gas-phase tropospheric chemistry of biogenic volatile organic compounds: A review, Atmos. Environ. 37(Suppl. 2), S197-S219.
7. Atkinson, R. and Aschmann, S. M., 1993: Atmospheric chemistry of the monoterpene reaction products nopinone, camphenilone, and 4-acetyl-1-methylcyclohexene, J. Atmos. Chem. 16, 337-348.
8. 3 radicals and O3 with sabinene and camphene at 296 ± 2 K, Atmos. Environ. 24A, 2647-2654.
9. 3 with a series of terpenes, J. Geophys. Res. 97, 6065-6073.
10. Atkinson, R., Carter, W. P. L., Winer, A. M., and Pitts, J. N., Jr., 1981: An experimental protocol for the determination of OH radical rate constants with organics using methyl nitrite photolysis as an OH radical source, J. Air Pollut. Control Assoc. 31, 1090-1092.
11. Atkinson, R., Plum, C. N., Carter, W. P. L., Winer, A. M., and Pitts, J. N., Jr., 1984: Rate constants for the gas-phase reactions of nitrate radicals with a series of organics in air at 298 ± 1 K, J. Phys. Chem. 88, 1210-1215.
12. Bertele, E. and Schudel, P., 1967: Synthese von α- and β-sinensal, Helv. Chim. Acta 50, 2445-2456.
13. 3, and ozone, Environ. Sci. Technol. 33, 453-460.
14. Calvert, J. G., Atkinson, R., Kerr, J. A., Madronich, S., Moortgat, G. K., Wallington, T. J., and Yarwood, G., 2000: The Mechanisms of Atmospheric Oxidation of the Alkenes, Oxford University Press, New York, NY.
15. Fall, R., 1999: Biogenic emissions of volatile organic compounds from higher plants, in (ed.) C. N. Hewitt, Reactive Hydrocarbons in the Atmosphere, Academic Press, San Diego, CA.
16. Fuentes, J. D., Lerdau, M., Atkinson, R., Baldocchi, D., Bottenheim, J. W., Ciccioli, P., Lamb, B., Geron, C., Gu, L., Guenther, A., Sharkey, T. D., and Stockwell, W., 2000: Biogenic hydrocarbons in the atmospheric boundary layer: A review, Bull. Am. Meteor. Soc. 81, 1537-1575.
17. Glasius, M., Calogirou, A., Jensen, N. R., Hjorth, J., and Nielsen, C. J., 1997: Kinetic study of gas-phase reactions of pinonaldehyde and structurally related compounds, Int. J. Chem. Kinet. 29, 527-533.
18. Guenther, A., Geron, C., Pierce, T., Lamb, B., Harley, P., and Fall, R., 2000: Natural emissions of non-methane volatile organic compounds, carbon monoxide, and oxides of nitrogen from North America, Atmos. Environ. 34, 2205-2230.
19. Guenther, A., Hewitt, C. N., Erickson, D., Fall, R., Geron, C., Graedel, T., Harley, P., Klinger, L., Lerdau, M., McKay, W. A., Pierce, T., Scholes, B., Steinbrecher, R., Tallamraju, R., Taylor, J., and Zimmerman, P., 1995: A global model of natural volatile organic compound emissions, J. Geophys. Res. 100, 8873-8892.
20. 3 with a series of monoterpenes, J. Atmos. Chem. 18, 75-102.
21. 3 radicals, UV absorption cross sections, and vapor pressures, Environ. Sci. Technol. 31, 3166-3172.
22. IUPAC, 2003: Evaluated kinetic data, http://www.iupac-kinetic.ch.cam.ac.uk/
23. Kramp, F. and Paulson, S. E., 1998: On the uncertainties in the rate coefficients for OH reactions with hydrocarbons, and the rate coefficients of the 1,3,5-trimethylbenzene and m-xylene reactions with OH radicals in the gas phase, J. Phys. Chem. A 102, 2685-2690.
24. Kwok, E. S. C. and Atkinson, R., 1995: Estimation of hydroxyl radical reaction rate constants for gas-phase organic compounds using a structure-reactivity relationship: An update, Atmos. Environ. 29 1685-1695.
25. Logan, J., 1985: Tropospheric ozone: Seasonal behavior, trends, and anthropogenic influence, J. Geophys. Res. 90, 10463-10482.
26. Nozière, B., Spittler, M., Ruppert, L., Barnes, I., Becker, K. H., Pons, M., and Wirtz, K., 1999: Kinetics of the reactions of pinonaldehyde with OH radicals and with Cl atoms, Int. J. Chem. Kinet. 31, 291-301.
27. Prinn, R. G., Huang, J., Weiss, R. F., Cunnold, D. M., Fraser, P. J., Simmonds, P. G., McCulloch, A., Harth, C., Salameh, P., O'Doherty, S., Wang, R. H. J., Porter, L., and Miller, B. R., 2001: Evidence for substantial variations of atmospheric hydroxyl radicals in the past two decades, Science 292, 1882-1888.
28. 3-initiated reactions of myrcene and ocimene, J. Geophys. Res. 107 (D 12), 10.1029/2001JD001234, ACH 3-1 to 3-6.
29. 3-initiated reactions of a series of monoterpenes, J. Geophys. Res. 104 13869-13879.