Reconsideration of theoretical basis of freundlich adsorption isotherm equation: I. The problem

Soil Science and Plant Nutrition

Volumn 42, Issue 1, 1996, Pages 41-49

  Nakahara, Osamu ^a  

^a KYUSHU UNIVERSITY   (Japan)

Author keywords

Cation adsorption on andisols; Freundlich isotherm; Heavy metal adsorption; Phosphate adsorption; Surface complexation models

Indexed keywords

EID: 5544231853     PISSN: 00380768     EISSN: 17470765     Source Type: Journal    
DOI: 10.1080/00380768.1996.10414687     Document Type: Article

References (27)

1. Charlet, L. and Sposito, G. 1987: Monovalent ion adsorption by an Oxisol. Soil Sci. Soc. Am. J., 51, 1155-1160
2. Davis, L.E. 1950: Ionic exchange and statistical thermodynamics. I. Equilibria in simple exchange systems. J. Colloid Sci., 5, 71-79
3. Ericksson, E. 1952: Cation-exchange equilibria on clay minerals. Soil Sci., 74, 103-113
4. Gaines, G.L. and Thomas, H.C. 1953: Adsorption studies on clay minerals II. A formulation of the thermodynamics of exchange-adsorption. J. Chem. Phys., 21, 714-718
5. Gapon, E.N. 1933: On the theory of exchange adsorption in soils. J. Gen. Chem. U.S.S.R., 3, 144-152 (in Russian)
6. Halsey, G. and Taylor, H.S. 1947: The adsorption of hydrogen on tungsten powders. J. Chem. Phys., 15, 624-630
7. Hendricks, S.B. and Fry, W.H. 1930: The results of X-ray and mineralogical examination of soil colloids. Soil Sci., 29, 457-476
8. Hill, T.L. 1949: Statistical mechanics of adsorption. VI. Localized unimolecular adsorption on a heterogeneous surface. J. Chem. Phys., 17, 762-771
9. Jaroneic, M. 1983: Physical adsorption on heterogeneous solids. Adv. Colloid Interface Sci, 18, 149-225
10. Kinniburgh, D.G., Barker, J.A., and Whitfield, M. 1983: A comparison of some simple adsorption isotherms for describing divalent cation adsorption by ferrihydrite. J. Colloid Interface Sci., 95, 370-384
11. Marshall, C.E. 1935: Layer lattices and the base exchange clays. Z. Kristallogr. Mineral., 91, 433-449
12. Nakahara, O. 1994: Two simple isotherms describing cation adsorption on Andisols. Soil Sci. Plant Nutr., 40, 83-94
13. Nakahara, O. and Wada, S.-I. 1994: Ca2+ and Mg2+ adsorption by an allophanic and a humic Andisol. Geoderma, 61, 203-212
14. Nakahara, O. and Wada, S.-I. 1995a: Surface complexation model of cation adsorption on humic soils. 1. K+ and Ca2+ adsorption. Soil Sci. Plant Nutr., 41, 659-669
15. Nakahara, O. and Wada, S.-I. 1995b: Surface complexation model of cation adsorption on humic soils. 2. K+-Ca2+ exchange. Soil Sci. Plant Nutr., 41, 671-679
16. Parfitt, R.L. 1989: Phosphate reactions with natural allophane, ferrihydrite and goethite. J. Soil Sci., 40, 359-369
17. Sips, R. 1948: On the structure of a catalyst surface. J. Chem. Phys., 16, 490-495
18. Sips, R. 1950: On the structure of a catalyst surface. II. J. Chem. Phys., 18, 1024-1026
19. Sposito, G. 1980a: Cation exchange in soils: An historical and theoretical perspective. In Chemistry in the Soil Environment, ASA Special Publication Number 40, p. 13-30. American Society of America, Madison
20. Sposito, G. 1980b: Derivation of the Freundlich equation for ion exchange reactions in soils. Soil Sci. Soc. Am. J., 44, 652-654
21. Sposito, G. 1984: The Surface Chemistry of Soils, p. 154-197. Oxford Univ. Press, New York
22. Thompson, H.S. 1850: On the absorbent power of soils. R. Agric. Soc. Engl. J., 11, 68-74
23. VanRaij, B. and Peech, M. 1972: Electrochemical properties of some Oxisols and Alfisols of the tropics. Soil Sci. Soc. Am. J., 36, 587-593
24. Wada, S.-I. 1984: pH-and ionic concentration-dependence of monovalent cation retention by clays and clay minerals expected in soils. Soil Sci. Plant Nutr., 29, 561-564
25. Wada, S.-I. and Kawabata, K. 1991: Ion adsorption on variable charge materials and thermodynamics of ion exchange. Soil Sci. Plant Nutr., 37, 191-200
26. Westall, J.C. 1987: Adsorption mechanisms in aquatic surface chemistry. In Aquatic Surface Chemistry, Ed. W. Stumm, p. 3-32. John Wiley & Sons, New York
27. Zachara, J.M., Smith, S.C., McKinley, J.P., and Resch, C.T. 1993: Cadmium sorption on specimen and soil smectites in sodium and calcium electrolyte. Soil Sci. Soc. Am. J., 57, 1491-1501